A Fully Reversible Water Electrolyzer Cell Made Up from FeCoNi (Oxy)hydroxide Atomic Layers

Zhang, Qingran; Bedford, Nicholas M.; Pan, Jian; Lu, Xunyu; Amal, Rose

doi:10.1002/aenm.201901312

Title: A Fully Reversible Water Electrolyzer Cell Made Up from FeCoNi (Oxy)hydroxide Atomic Layers

Journal Article · Mon Jun 24 00:00:00 EDT 2019 · Advanced Energy Materials

DOI:https://doi.org/10.1002/aenm.201901312· OSTI ID:1529020

^[1]; Bedford, Nicholas M. ^[1]; Pan, Jian ^[1]; Lu, Xunyu ^[1];

^[1]

Particles and Catalysis Research Group School of Chemical Engineering The University of New South Wales Sydney NSW 2052 Australia

Abstract Renewable electricity powered water electrolysis is a promising solution for the conversion and storage of the intermittent renewable energy resources in the form of hydrogen. Herein, atomically thin FeCoNi ternary (oxy)hydroxide nanosheets (FeCoNi‐ATNs) are developed as efficient and robust bifunctional electrocatalysts for the oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) in 1 m KOH solution (pH = 14). The electrocatalyst shows remarkably high apparent catalytic performance (400 mA cm ⁻² at 350 mV for OER and 240 mV for HER) and mass activities at modest overpotentials (1931 A g ⁻¹ at 330 mV for OER; 1819 A g ⁻¹ at 200 mV for HER). Moreover, the OER and HER performance of FeCoNi–ATNs are fully reversible and electrochemically switchable, due to the interconversion attribute of two catalytic states for OER and HER. Using the dual functional properties of this catalyst, a fully reversible water electrolyzer cell is fabricated, exhibiting a robust reversibility between two half reactions in water electrolysis under a high current density (100 mA cm ⁻¹ ), which can effectively overcome the stability issues caused by electrode depolarization during frequent power interruptions, an inevitable phenomenon commonly brought about by the usage of intermittent renewable energy supplies.

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Sponsoring Organization:: USDOE

OSTI ID:: 1529020

Journal Information:: Advanced Energy Materials, Journal Name: Advanced Energy Materials Vol. 9 Journal Issue: 29; ISSN 1614-6832

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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References (66)

Benchmarking Hydrogen Evolving Reaction and Oxygen Evolving Reaction Electrocatalysts for Solar Water Splitting Devices McCrory, Charles C. L.; Jung, Suho; Ferrer, Ivonne M. Journal of the American Chemical Society, Vol. 137, Issue 13 https://doi.org/10.1021/ja510442p	journal	March 2015
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT Ravel, B.; Newville, M. Journal of Synchrotron Radiation, Vol. 12, Issue 4 https://doi.org/10.1107/S0909049505012719	journal	June 2005
In situ Cobalt–Cobalt Oxide/N-Doped Carbon Hybrids As Superior Bifunctional Electrocatalysts for Hydrogen and Oxygen Evolution Jin, Haiyan; Wang, Jing; Su, Diefeng Journal of the American Chemical Society, Vol. 137, Issue 7 https://doi.org/10.1021/ja5127165	journal	February 2015
A mini review of NiFe-based materials as highly active oxygen evolution reaction electrocatalysts Gong, Ming; Dai, Hongjie Nano Research, Vol. 8, Issue 1 https://doi.org/10.1007/s12274-014-0591-z	journal	November 2014
A Bifunctional Nonprecious Metal Catalyst for Oxygen Reduction and Water Oxidation Gorlin, Yelena; Jaramillo, Thomas F. Journal of the American Chemical Society, Vol. 132, Issue 39, p. 13612-13614 https://doi.org/10.1021/ja104587v	journal	October 2010
Ultrathin Iron-Cobalt Oxide Nanosheets with Abundant Oxygen Vacancies for the Oxygen Evolution Reaction Zhuang, Linzhou; Ge, Lei; Yang, Yisu Advanced Materials, Vol. 29, Issue 17 https://doi.org/10.1002/adma.201606793	journal	February 2017
Ultrathin two-dimensional layered metal hydroxides: an emerging platform for advanced catalysis, energy conversion and storage Yin, Huajie; Tang, Zhiyong Chemical Society Reviews, Vol. 45, Issue 18 https://doi.org/10.1039/C6CS00343E	journal	January 2016
Influence of process conditions on gas purity in alkaline water electrolysis Haug, Philipp; Koj, Matthias; Turek, Thomas International Journal of Hydrogen Energy, Vol. 42, Issue 15 https://doi.org/10.1016/j.ijhydene.2016.12.111	journal	April 2017
Water Oxidation Catalysis: Electrocatalytic Response to Metal Stoichiometry in Amorphous Metal Oxide Films Containing Iron, Cobalt, and Nickel Smith, Rodney D. L.; Prévot, Mathieu S.; Fagan, Randal D. Journal of the American Chemical Society, Vol. 135, Issue 31 https://doi.org/10.1021/ja403102j	journal	July 2013
Electrocatalyst performance in industrial water electrolysers Janjua, M.; Leroy, R. International Journal of Hydrogen Energy, Vol. 10, Issue 1 https://doi.org/10.1016/0360-3199(85)90130-2	journal	January 1985
Activating CoOOH Porous Nanosheet Arrays by Partial Iron Substitution for Efficient Oxygen Evolution Reaction Ye, Sheng-Hua; Shi, Zi-Xiao; Feng, Jin-Xian Angewandte Chemie International Edition, Vol. 57, Issue 10 https://doi.org/10.1002/anie.201712549	journal	February 2018
Single-Crystalline Ultrathin Nickel Nanosheets Array from In Situ Topotactic Reduction for Active and Stable Electrocatalysis Kuang, Yun; Feng, Guang; Li, Pengsong Angewandte Chemie International Edition, Vol. 55, Issue 2 https://doi.org/10.1002/anie.201509616	journal	November 2015
Ultrathin Spinel-Structured Nanosheets Rich in Oxygen Deficiencies for Enhanced Electrocatalytic Water Oxidation Bao, Jian; Zhang, Xiaodong; Fan, Bo Angewandte Chemie International Edition, Vol. 54, Issue 25 https://doi.org/10.1002/anie.201502226	journal	May 2015
Ultrathin platinum nanowires grown on single-layered nickel hydroxide with high hydrogen evolution activity Yin, Huajie; Zhao, Shenlong; Zhao, Kun Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7430	journal	March 2015
Hydrothermal Continuous Flow Synthesis and Exfoliation of NiCo Layered Double Hydroxide Nanosheets for Enhanced Oxygen Evolution Catalysis Liang, Hanfeng; Meng, Fei; Cabán-Acevedo, Miguel Nano Letters, Vol. 15, Issue 2 https://doi.org/10.1021/nl504872s	journal	January 2015
Stainless steel made to rust: a robust water-splitting catalyst with benchmark characteristics Schäfer, Helmut; Sadaf, Shamaila; Walder, Lorenz Energy & Environmental Science, Vol. 8, Issue 9 https://doi.org/10.1039/C5EE01601K	journal	January 2015
Intermittent operation and operation modeling of an alkaline electrolyzer Hug, W.; Bussmann, H.; Brinner, A. International Journal of Hydrogen Energy, Vol. 18, Issue 12 https://doi.org/10.1016/0360-3199(93)90078-O	journal	December 1993
Cobalt–Iron (Oxy)hydroxide Oxygen Evolution Electrocatalysts: The Role of Structure and Composition on Activity, Stability, and Mechanism Burke, Michaela S.; Kast, Matthew G.; Trotochaud, Lena Journal of the American Chemical Society, Vol. 137, Issue 10 https://doi.org/10.1021/jacs.5b00281	journal	March 2015
In Situ Formation of an Oxygen-Evolving Catalyst in Neutral Water Containing Phosphate and Co²⁺ Kanan, M. W.; Nocera, D. G. Science, Vol. 321, Issue 5892, p. 1072-1075 https://doi.org/10.1126/science.1162018	journal	August 2008
Understanding Structure-Dependent Catalytic Performance of Nickel Selenides for Electrochemical Water Oxidation Xu, Kun; Ding, Hui; Lv, Haifeng ACS Catalysis, Vol. 7, Issue 1 https://doi.org/10.1021/acscatal.6b02884	journal	December 2016
Charge-Transfer Effects in Ni–Fe and Ni–Fe–Co Mixed-Metal Oxides for the Alkaline Oxygen Evolution Reaction Bates, Michael K.; Jia, Qingying; Doan, Huong ACS Catalysis, Vol. 6, Issue 1 https://doi.org/10.1021/acscatal.5b01481	journal	December 2015
Ni ₂ P as a Janus catalyst for water splitting: the oxygen evolution activity of Ni ₂ P nanoparticles Stern, Lucas-Alexandre; Feng, Ligang; Song, Fang Energy & Environmental Science, Vol. 8, Issue 8 https://doi.org/10.1039/C5EE01155H	journal	January 2015
Trimetallic Oxyhydroxide Coralloids for Efficient Oxygen Evolution Electrocatalysis Pi, Yecan; Shao, Qi; Wang, Pengtang Angewandte Chemie International Edition, Vol. 56, Issue 16 https://doi.org/10.1002/anie.201701533	journal	March 2017
Phase Transformation Guided Single-Layer β-Co(OH) ₂ Nanosheets for Pseudocapacitive Electrodes Wang, Lei; Lin, Chong; Zhang, Fengxing ACS Nano, Vol. 8, Issue 4 https://doi.org/10.1021/nn500386u	journal	March 2014
Nanostructured materials on 3D nickel foam as electrocatalysts for water splitting Chaudhari, Nitin K.; Jin, Haneul; Kim, Byeongyoon Nanoscale, Vol. 9, Issue 34 https://doi.org/10.1039/C7NR04187J	journal	January 2017
An efficient and pH-universal ruthenium-based catalyst for the hydrogen evolution reaction Mahmood, Javeed; Li, Feng; Jung, Sun-Min Nature Nanotechnology, Vol. 12, Issue 5 https://doi.org/10.1038/nnano.2016.304	journal	February 2017
Cobalt Sulfide Nanoparticles Grown on Nitrogen and Sulfur Codoped Graphene Oxide: An Efficient Electrocatalyst for Oxygen Reduction and Evolution Reactions Ganesan, Pandian; Prabu, Moni; Sanetuntikul, Jakkid ACS Catalysis, Vol. 5, Issue 6 https://doi.org/10.1021/acscatal.5b00154	journal	May 2015
Emerging Two-Dimensional Nanomaterials for Electrocatalysis Jin, Huanyu; Guo, Chunxian; Liu, Xin Chemical Reviews, Vol. 118, Issue 13 https://doi.org/10.1021/acs.chemrev.7b00689	journal	March 2018
Intercalation of Li ⁺ into a Co-Containing Steel-Ceramic Composite: Substantial Oxygen Evolution at Almost Zero Overpotential Schäfer, Helmut; Kuepper, Karsten; Koppe, Jonas ACS Catalysis, Vol. 8, Issue 11 https://doi.org/10.1021/acscatal.8b03566	journal	September 2018
Blending Cr ₂ O ₃ into a NiO-Ni Electrocatalyst for Sustained Water Splitting Gong, Ming; Zhou, Wu; Kenney, Michael James Angewandte Chemie International Edition, Vol. 54, Issue 41 https://doi.org/10.1002/anie.201504815	journal	August 2015
CoOOH Nanosheets with High Mass Activity for Water Oxidation Huang, Junheng; Chen, Junting; Yao, Tao Angewandte Chemie International Edition, Vol. 54, Issue 30 https://doi.org/10.1002/anie.201502836	journal	June 2015
Bi-Functional Iron-Only Electrodes for Efficient Water Splitting with Enhanced Stability through In Situ Electrochemical Regeneration Martindale, Benjamin C. M.; Reisner, Erwin Advanced Energy Materials, Vol. 6, Issue 6 https://doi.org/10.1002/aenm.201502095	journal	December 2015
Hydrogen Evolution Reaction in Alkaline Media: Alpha- or Beta-Nickel Hydroxide on the Surface of Platinum? Yu, Xiaowen; Zhao, Jun; Zheng, Li-Rong ACS Energy Letters, Vol. 3, Issue 1 https://doi.org/10.1021/acsenergylett.7b01103	journal	November 2017
Recent Advances in the Synthesis and Application of Layered Double Hydroxide (LDH) Nanosheets Wang, Qiang; O’Hare, Dermot Chemical Reviews, Vol. 112, Issue 7 https://doi.org/10.1021/cr200434v	journal	March 2012
An Investigation of Thin-Film Ni–Fe Oxide Catalysts for the Electrochemical Evolution of Oxygen Louie, Mary W.; Bell, Alexis T. Journal of the American Chemical Society, Vol. 135, Issue 33 https://doi.org/10.1021/ja405351s	journal	August 2013
Improved water electrolysis using magnetic heating of FeC–Ni core–shell nanoparticles Niether, Christiane; Faure, Stéphane; Bordet, Alexis Nature Energy, Vol. 3, Issue 6 https://doi.org/10.1038/s41560-018-0132-1	journal	May 2018
Ultrathin metal–organic framework nanosheets for electrocatalytic oxygen evolution Zhao, Shenlong; Wang, Yun; Dong, Juncai Nature Energy, Vol. 1, Issue 12 https://doi.org/10.1038/nenergy.2016.184	journal	November 2016
Ultrahigh Energy Density Realized by a Single-Layer β-Co(OH) ₂ All-Solid-State Asymmetric Supercapacitor Gao, Shan; Sun, Yongfu; Lei, Fengcai Angewandte Chemie International Edition, Vol. 53, Issue 47 https://doi.org/10.1002/anie.201407836	journal	September 2014
Water photolysis at 12.3% efficiency via perovskite photovoltaics and Earth-abundant catalysts Luo, J.; Im, J. -H.; Mayer, M. T. Science, Vol. 345, Issue 6204 https://doi.org/10.1126/science.1258307	journal	September 2014
Electrodeposition of hierarchically structured three-dimensional nickel–iron electrodes for efficient oxygen evolution at high current densities Lu, Xunyu; Zhao, Chuan Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7616	journal	March 2015
Enhanced Catalysis of the Electrochemical Oxygen Evolution Reaction by Iron(III) Ions Adsorbed on Amorphous Cobalt Oxide Gong, Luo; Chng, Xin Yu Esther; Du, Yonghua ACS Catalysis, Vol. 8, Issue 2 https://doi.org/10.1021/acscatal.7b03509	journal	December 2017
Ultrathin Fe-N-C Nanosheets Coordinated Fe-Doped CoNi Alloy Nanoparticles for Electrochemical Water Splitting Zhang, Qingran; Webster, Richard F.; Cheong, Soshan Particle & Particle Systems Characterization, Vol. 36, Issue 1 https://doi.org/10.1002/ppsc.201800252	journal	September 2018
One-step direct synthesis of layered double hydroxide single-layer nanosheets Yu, Jingfang; Martin, Benjamin R.; Clearfield, Abraham Nanoscale, Vol. 7, Issue 21 https://doi.org/10.1039/C5NR01077B	journal	January 2015
Binary FeCo Oxyhydroxide Nanosheets as Highly Efficient Bifunctional Electrocatalysts for Overall Water Splitting Nguyen, Trang‐Thi Hong; Lee, Jooyoung; Bae, Joonwon Chemistry – A European Journal, Vol. 24, Issue 18 https://doi.org/10.1002/chem.201800022	journal	February 2018
Exfoliation of layered double hydroxides for enhanced oxygen evolution catalysis Song, Fang; Hu, Xile Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5477	journal	July 2014
A sea-change: manganese doped nickel/nickel oxide electrocatalysts for hydrogen generation from seawater Lu, Xunyu; Pan, Jian; Lovell, Emma Energy & Environmental Science, Vol. 11, Issue 7 https://doi.org/10.1039/C8EE00976G	journal	January 2018
Tuning Electronic Structure of NiFe Layered Double Hydroxides with Vanadium Doping toward High Efficient Electrocatalytic Water Oxidation Li, Pengsong; Duan, Xinxuan; Kuang, Yun Advanced Energy Materials, Vol. 8, Issue 15 https://doi.org/10.1002/aenm.201703341	journal	February 2018
Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction McCrory, Charles C. L.; Jung, Suho; Peters, Jonas C. Journal of the American Chemical Society, Vol. 135, Issue 45 https://doi.org/10.1021/ja407115p	journal	October 2013
Homogeneously dispersed multimetal oxygen-evolving catalysts Zhang, B.; Zheng, X.; Voznyy, O. Science, Vol. 352, Issue 6283 https://doi.org/10.1126/science.aaf1525	journal	March 2016
Extraction of nickel from NiFe-LDH into Ni ₂ P@NiFe hydroxide as a bifunctional electrocatalyst for efficient overall water splitting Zhang, Fang-Shuai; Wang, Jia-Wei; Luo, Jun Chemical Science, Vol. 9, Issue 5 https://doi.org/10.1039/C7SC04569G	journal	January 2018
Oxygen Evolution Reaction Dynamics, Faradaic Charge Efficiency, and the Active Metal Redox States of Ni–Fe Oxide Water Splitting Electrocatalysts Görlin, Mikaela; Chernev, Petko; Ferreira de Araújo, Jorge Journal of the American Chemical Society, Vol. 138, Issue 17 https://doi.org/10.1021/jacs.6b00332	journal	April 2016
Identification of Highly Active Fe Sites in (Ni,Fe)OOH for Electrocatalytic Water Splitting Friebel, Daniel; Louie, Mary W.; Bajdich, Michal Journal of the American Chemical Society, Vol. 137, Issue 3 https://doi.org/10.1021/ja511559d	journal	January 2015
Electrocatalytic Oxygen Evolution Reaction in Acidic Environments - Reaction Mechanisms and Catalysts Reier, Tobias; Nong, Hong Nhan; Teschner, Detre Advanced Energy Materials, Vol. 7, Issue 1 https://doi.org/10.1002/aenm.201601275	journal	October 2016
Bifunctional Porous NiFe/NiCo ₂ O ₄ /Ni Foam Electrodes with Triple Hierarchy and Double Synergies for Efficient Whole Cell Water Splitting Xiao, Changlong; Li, Yibing; Lu, Xunyu Advanced Functional Materials, Vol. 26, Issue 20 https://doi.org/10.1002/adfm.201505302	journal	April 2016
Activating cobalt(II) oxide nanorods for efficient electrocatalysis by strain engineering Ling, Tao; Yan, Dong-Yang; Wang, Hui Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-01872-y	journal	November 2017
Layered Double Hydroxide Nanosheets with Multiple Vacancies Obtained by Dry Exfoliation as Highly Efficient Oxygen Evolution Electrocatalysts Wang, Yanyong; Zhang, Yiqiong; Liu, Zhijuan Angewandte Chemie International Edition, Vol. 56, Issue 21 https://doi.org/10.1002/anie.201701477	journal	April 2017
Synthesis of Hexagonal Nickel Hydroxide Nanosheets by Exfoliation of Layered Nickel Hydroxide Intercalated with Dodecyl Sulfate Ions Ida, Shintaro; Shiga, Daisuke; Koinuma, Michio Journal of the American Chemical Society, Vol. 130, Issue 43 https://doi.org/10.1021/ja804397n	journal	October 2008
Atomically-thin two-dimensional sheets for understanding active sites in catalysis Sun, Yongfu; Gao, Shan; Lei, Fengcai Chemical Society Reviews, Vol. 44, Issue 3 https://doi.org/10.1039/C4CS00236A	journal	January 2015
Advanced water electrolysis and catalyst stability under discontinuous operation Divisek, J.; Mergel, J.; Schmitz, H. International Journal of Hydrogen Energy, Vol. 15, Issue 2 https://doi.org/10.1016/0360-3199(90)90032-T	journal	January 1990
Ultrathin Co ₃ S ₄ Nanosheets that Synergistically Engineer Spin States and Exposed Polyhedra that Promote Water Oxidation under Neutral Conditions Liu, Youwen; Xiao, Chong; Lyu, Mengjie Angewandte Chemie International Edition, Vol. 54, Issue 38 https://doi.org/10.1002/anie.201505320	journal	July 2015
Combining theory and experiment in electrocatalysis: Insights into materials design Seh, Zhi Wei; Kibsgaard, Jakob; Dickens, Colin F. Science, Vol. 355, Issue 6321 https://doi.org/10.1126/science.aad4998	journal	January 2017
Anodic deposition of a robust iridium-based water-oxidation catalyst from organometallic precursors Blakemore, James D.; Schley, Nathan D.; Olack, Gerard W. Chem. Sci., Vol. 2, Issue 1 https://doi.org/10.1039/C0SC00418A	journal	January 2011
Fabrication of Nanoporous Nickel–Iron Hydroxylphosphate Composite as Bifunctional and Reversible Catalyst for Highly Efficient Intermittent Water Splitting Lei, Zhanwu; Bai, Jingjing; Li, Yibing ACS Applied Materials & Interfaces, Vol. 9, Issue 41 https://doi.org/10.1021/acsami.7b10385	journal	October 2017
Iron Vacancies Induced Bifunctionality in Ultrathin Feroxyhyte Nanosheets for Overall Water Splitting Liu, Bin; Wang, Yun; Peng, Hui-Qing Advanced Materials, Vol. 30, Issue 36 https://doi.org/10.1002/adma.201803144	journal	July 2018
Low Overpotential in Vacancy-Rich Ultrathin CoSe ₂ Nanosheets for Water Oxidation Liu, Youwen; Cheng, Hao; Lyu, Mengjie Journal of the American Chemical Society, Vol. 136, Issue 44 https://doi.org/10.1021/ja5085157	journal	October 2014
Electrochemistry of Nanostructured Layered Transition-Metal Dichalcogenides Chia, Xinyi; Eng, Alex Yong Sheng; Ambrosi, Adriano Chemical Reviews, Vol. 115, Issue 21 https://doi.org/10.1021/acs.chemrev.5b00287	journal	October 2015

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