Isotope-Engineering the Thermal Conductivity of Two-Dimensional MoS2
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Virginia, Charlottesville, VA (United States)
- Rensselaer Polytechnic Inst., Troy, NY (United States)
- Univ. of Kansas, Lawrence, KS (United States)
- Univ. of Virginia, Charlottesville, VA (United States)
Isotopes represent a degree of freedom that might be exploited to tune the physical properties of materials while preserving their chemical behaviors. In this work, we demonstrate that the thermal properties of two-dimensional (2D) transition-metal dichalcogenides can be tailored through isotope engineering. Monolayer crystals of MoS2 were synthesized with isotopically pure 100Mo and 92Mo by chemical vapor deposition employing isotopically enriched molybdenum oxide precursors. The in-plane thermal conductivity of the 100MoS2 monolayers, measured using a non-destructive, optothermal Raman technique, is found to be enhanced by ~50% compared with the MoS2 synthesized using mixed Mo isotopes from naturally occurring molybdenum oxide. The boost of thermal conductivity in isotopically pure MoS2 monolayers is attributed to the combined effects of reduced isotopic disorder and a reduction in defect-related scattering, consistent with observed stronger photoluminescence and longer exciton lifetime. Finally, these results shed light on the fundamentals of 2D nanoscale thermal transport important for the optimization of 2D electronic devices.
- Research Organization:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division
- Grant/Contract Number:
- AC05-00OR22725
- OSTI ID:
- 1528724
- Journal Information:
- ACS Nano, Vol. 13, Issue 2; ISSN 1936-0851
- Publisher:
- American Chemical Society (ACS)Copyright Statement
- Country of Publication:
- United States
- Language:
- English
Web of Science
The role of mid-gap phonon modes in thermal transport of transition metal dichalcogenides
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journal | October 2019 |
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