Oxygen Release Degradation in Li–Ion Battery Cathode Materials: Mechanisms and Mitigating Approaches

Sharifi‐Asl, Soroosh; Lu, Jun; Amine, Khalil; Shahbazian‐Yassar, Reza

doi:10.1002/aenm.201900551

Title: Oxygen Release Degradation in Li–Ion Battery Cathode Materials: Mechanisms and Mitigating Approaches

Journal Article · Mon Apr 29 00:00:00 EDT 2019 · Advanced Energy Materials

DOI:https://doi.org/10.1002/aenm.201900551· OSTI ID:1526722

Sharifi‐Asl, Soroosh ^[1];

^[2]; Amine, Khalil ^[2]; Shahbazian‐Yassar, Reza ^[1]

Univ. of Illinois at Chicago, Chicago, IL (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)

Widespread application of Li–ion batteries (LIBs) in large–scale transportation and grid storage systems requires highly stable and safe performance of the batteries in prolonged and diverse service conditions. Oxygen release from oxygen–containing positive electrode materials is one of the major structural degradations resulting in rapid capacity/voltage fading of the battery and triggering the parasitic thermal runaway events. Herein, the authors summarize the recent progress in understanding the mechanisms of the oxygen release phenomena and correlative structural degradations observed in four major groups of cathode materials: layered, spinel, olivine, and Li–rich cathodes. In addition, the engineering and materials design approaches that improve the structural integrity of the cathode materials and minimize the detrimental O₂ evolution reaction are summarized. As a result, the authors believe that this review can guide researchers on developing mitigation strategies for the design of next–generation oxygen–containing cathode materials where the oxygen release is no longer a major degradation issue.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE

Grant/Contract Number:: AC02-06CH11357; AC02‐06CH11357

OSTI ID:: 1526722

Alternate ID(s):: OSTI ID: 1509941

Journal Information:: Advanced Energy Materials, Vol. 9, Issue 22; ISSN 1614-6832

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 261 works

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