Cooperative self-assembly of porphyrins and derivatives

Wei, Wenbo; Sun, Jiajie; Fan, Hongyou

doi:10.1557/mrs.2019.39

Cooperative self-assembly of porphyrins and derivatives

Journal Article · Mon Mar 11 00:00:00 EDT 2019 · MRS Bulletin

DOI:https://doi.org/10.1557/mrs.2019.39· OSTI ID:1526215

Wei, Wenbo ^[1]; Sun, Jiajie ^[1]; Fan, Hongyou ^[2]

Henan Univ. (China)
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Univ. of New Mexico, Albuquerque, NM (United States)

We report there has been widespread recent interest in self-assembly and synthesis of porphyrin and its derivatives-based ordered arrays aiming to emulate natural light-harvesting processes and energy storage. However, technologies that leverage the structural advantages of individual porphyrins have not been fully realized and have been limited by available synthesis methods. This article provides general perspectives on porphyrin and derivative chemistry, and discussions on surfactant-assisted cooperative self-assembly using amphiphilic surfactants and functional porphyrins and derivatives. The cooperative self-assembly amplifies the intrinsic advantages of individual porphyrins by engineering them into well-defined one-dimensional–three-dimensional (1D–3D) nanostructures. Surfactant-assisted self-assembly of amphiphilic surfactants and porphyrins has been utilized to form well-defined “micelle-like” nanostructures. Lastly, driven by intermolecular interactions, subsequent nucleation and growth confined within these nanostructures lead to the formation of 1D–3D ordered optically and electrically active nanomaterials with structure and function on multiple length scales.

View Accepted Manuscript (DOE)

Research Organization:: Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC04-94AL85000; NA0003525

OSTI ID:: 1526215

Report Number(s):: SAND--2019-6164J; 676100

Journal Information:: MRS Bulletin, Journal Name: MRS Bulletin Journal Issue: 3 Vol. 44; ISSN 0883-7694

Publisher:: Materials Research SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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