Dendrite-Free and Performance-Enhanced Lithium Metal Batteries through Optimizing Solvent Compositions and Adding Combinational Additives

Li, Xing; Zheng, Jianming; Ren, Xiaodi; Engelhard, Mark H.; Zhao, Wengao; Li, Qiuyan; Zhang, Jiguang; Xu, Wu

doi:10.1002/aenm.201703022

Title: Dendrite-Free and Performance-Enhanced Lithium Metal Batteries through Optimizing Solvent Compositions and Adding Combinational Additives

Journal Article · Fri May 25 00:00:00 EDT 2018 · Advanced Energy Materials

DOI:https://doi.org/10.1002/aenm.201703022· OSTI ID:1525995

Li, Xing ^[1];

^[2]; Ren, Xiaodi ^[2];

^[2]; Zhao, Wengao ^[1];

^[2];

^[2]

UNIVERSITY PROGRAMS
BATTELLE (PACIFIC NW LAB)

The instability of lithium (Li) metal anode due to the dendritic growth and low Coulombic efficiency hinders the practical application of the well-regarded high-energy-density Li metal batteries. Here we report the systematic studies of improving the stability of Li metal anode and the electrochemical performances of the related Li metal batteries through the addition of combinational additives and the optimization of solvent compositions in dual-salt/carbonate electrolytes. A dendrite-free and high Coulombic efficiency of 98.1% for Li metal anode is achieved. The well protection of the Li metal anode and the excellent cyclability and rate capability of the 4-V Li metal batteries have been obtained. This is attributed to the formation of a robust, denser, more polymeric and higher ionic conductive surface film on the Li metal anode via the electrochemical reductive decompositions of the electrolyte components and the ring-opening polymerization of additives and cyclic carbonate solvents. The key findings of this work emphasize that the optimization of solvent compositions and the manipulation of the additives are facile and effective to enhance the Li metal battery performances.

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Research Organization:: Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1525995

Report Number(s):: PNNL-SA-129776

Journal Information:: Advanced Energy Materials, Vol. 8, Issue 15

Country of Publication:: United States

Language:: English

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