Data Trend Shifts Induced by Method of Concentration for Trace Metals in Seawater: Automated Online Preconcentration vs Borohydride Reductive Coprecipitation of Nearshore Seawater Samples for Analysis of Ni, Cu, Zn, Cd, and Pb via ICP-MS

Strivens, Jonathan E.; Brandenberger, Jill M.; Johnston, Robert K.

doi:10.1002/lom3.10311

Data Trend Shifts Induced by Method of Concentration for Trace Metals in Seawater: Automated Online Preconcentration vs Borohydride Reductive Coprecipitation of Nearshore Seawater Samples for Analysis of Ni, Cu, Zn, Cd, and Pb via ICP-MS

Journal Article · Mon Apr 01 04:00:00 EDT 2019 · Limnology and Oceanography Methods

DOI:https://doi.org/10.1002/lom3.10311· OSTI ID:1525978

^[1]; Brandenberger, Jill M. ^[1]; Johnston, Robert K. ^[2]

BATTELLE (PACIFIC NW LAB)
US Navy Space and Naval Warfare Systems Center

This research compares performance, reproducibility, and detection limits of ambient seawater analysis for trace metals using both borohydride reductive co-precipitation and an automated chelation column (seaFAST™ 2) co-preconcentration for matrix interferent elimination on total and dissolved grab samples in nearshore to marine waters, over a broad concentration range, prior to ICP-MS injection. A move to an online preconcentration method both minimizes sample preparation, and eliminates correction errors when accounting for trace impurities in precipitated samples, induced via reagents. The reproducability of the online preconcentration method described, coupled with low blanks and method detection limits (MDLs), demonstrates an effective move to an automated procedure using ethylenediaminetriacetic and iminodiacetate acid chelation exchange resin and multi-analyte determination via ICP-MS for total and dissolved Ni, Cu, Zn, Cd, and Pb in marine water samples. Average CASS-5 recoveries using the online preconcentration method (n=9) were 109±7%, 104±5%, 103±7%, 101±3%, and 86±8% respectively. The MDLs obtained from the automated method for Ni, Cu, Zn, Cd and Pb were 3.3, 1.8, 13.5, 4, and 10 times lower, respectively, than for the Borohydride method. There were statistically significant differences between the methods for CASS-5 recoveries of Ni, Cu, Zn (p < 0.0001), and Pb (p = 0.0024). Comparison of methods gave high concordance (rC = 0.90) between methods for total and dissolved Ni, Cu, Zn, and Pb, and total Cd.

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1525978

Report Number(s):: PNNL-SA-140847

Journal Information:: Limnology and Oceanography Methods, Journal Name: Limnology and Oceanography Methods Journal Issue: 4 Vol. 17

Country of Publication:: United States

Language:: English

References (19)

Direct determination of trace metals in sea-water using electrothermal vaporization inductively coupled plasma mass spectrometry Chapple, Graeme; Byrne, John P. Journal of Analytical Atomic Spectrometry, Vol. 11, Issue 8 https://doi.org/10.1039/ja9961100549	journal	January 1996
Evaluating Agreement with a Gold Standard in Method Comparison Studies Laurent, Roy T. St. Biometrics, Vol. 54, Issue 2 https://doi.org/10.2307/3109761	journal	June 1998
Direct determination of trace metals in sea-water by inductively coupled plasma mass spectrometry Rosland, Eivind; Lund, Walter Journal of Analytical Atomic Spectrometry, Vol. 13, Issue 11 https://doi.org/10.1039/a804350g	journal	January 1998
Trace metal enrichment by automated on-line column preconcentration for flow-injection atomic absorption spectrometry Hirata, Shizuko; Honda, Kazuto; Kumamaru, Takahiro Analytica Chimica Acta, Vol. 221 https://doi.org/10.1016/S0003-2670(00)81939-X	journal	January 1989
Measurement in Medicine: The Analysis of Method Comparison Studies Altman, D. G.; Bland, J. M. The Statistician, Vol. 32, Issue 3 https://doi.org/10.2307/2987937	journal	September 1983
Determination of Mn, Fe, Co, Ni, Cu, Zn, Cd and Pb in seawater using high resolution magnetic sector inductively coupled mass spectrometry (HR-ICP-MS) Milne, Angela; Landing, William; Bizimis, Michael Analytica Chimica Acta, Vol. 665, Issue 2 https://doi.org/10.1016/j.aca.2010.03.027	journal	April 2010
Trace metal transport by marine microorganisms: implications of metal coordination kinetics Hudson, Robert J. M.; Morel, François M. M. Deep Sea Research Part I: Oceanographic Research Papers, Vol. 40, Issue 1 https://doi.org/10.1016/0967-0637(93)90057-A	journal	January 1993
Determination of trace metals in seawater by on-line column preconcentration inductively coupled plasma mass spectrometry Hirata, Shizuko; Ishida, Yoshiko; Aihara, Masato Analytica Chimica Acta, Vol. 438, Issue 1-2 https://doi.org/10.1016/S0003-2670(01)00859-5	journal	July 2001
Processes regulating cellular metal accumulation and physiological effects: Phytoplankton as model systems Sunda, William G.; Huntsman, Susan A. Science of The Total Environment, Vol. 219, Issue 2-3 https://doi.org/10.1016/S0048-9697(98)00226-5	journal	August 1998
Performance optimization of a commercially available iminodiacetate resin for the determination of Mn, Ni, Cu, Cd and Pb by on-line preconcentration inductively coupled plasma-mass spectrometry Warnken, Kent W.; Tang, Degui; Gill, Gary A. Analytica Chimica Acta, Vol. 423, Issue 2 https://doi.org/10.1016/S0003-2670(00)01137-5	journal	November 2000
Trace metal analysis of natural waters by ICP-MS with on-line preconcentration and ultrasonic nebulization Warnken, Kent W.; Gill, Gary A.; Wen, Liang-Saw Journal of Analytical Atomic Spectrometry, Vol. 14, Issue 2 https://doi.org/10.1039/a806822d	journal	January 1999
Analysis for Cd, Cu, Ni, Zn, and Mn in estuarine water by inductively coupled plasma mass spectrometry coupled with an automated flow injection system Beck, Nicole G.; Franks, Robert P.; Bruland, Kenneth W. Analytica Chimica Acta, Vol. 455, Issue 1 https://doi.org/10.1016/S0003-2670(01)01561-6	journal	March 2002
Automated on-line flow-injection ICP-MS determination of trace metals (Mn, Fe, Co, Ni, Cu and Zn) in open ocean seawater: Application to the GEOTRACES program Lagerström, M. E.; Field, M. P.; Séguret, M. Marine Chemistry, Vol. 155 https://doi.org/10.1016/j.marchem.2013.06.001	journal	September 2013
Concentration of trace elements in water samples by reductive precipitation Skogerboe, R. K.; Hanagan, W. A.; Taylor, H. E. Analytical Chemistry, Vol. 57, Issue 14 https://doi.org/10.1021/ac00291a016	journal	December 1985
Method agreement analysis: A review of correct methodology Watson, P. F.; Petrie, A. Theriogenology, Vol. 73, Issue 9 https://doi.org/10.1016/j.theriogenology.2010.01.003	journal	June 2010
Determination of trace elements in sea water by graphite-furnace atomic absorption spectrometry after preconcentration by tetrahydroborate reductive precipitation Nakashima, S.; Sturgeon, R. E.; Willie, S. N. Analytica Chimica Acta, Vol. 207 https://doi.org/10.1016/S0003-2670(00)80804-1	journal	January 1988
Statistical Methods for Assessing Agreement Between two Methods of Clinical Measurement Martin Bland, J.; Altman, DouglasG. The Lancet, Vol. 327, Issue 8476 https://doi.org/10.1016/S0140-6736(86)90837-8	journal	February 1986
Automated preconcentration of Fe, Zn, Cu, Ni, Cd, Pb, Co, and Mn in seawater with analysis using high-resolution sector field inductively-coupled plasma mass spectrometry Rapp, Insa; Schlosser, Christian; Rusiecka, Dagmara Analytica Chimica Acta, Vol. 976 https://doi.org/10.1016/j.aca.2017.05.008	journal	July 2017
Analysis of Mn, Fe, Co, Ni, Cu, Zn, Cd, and Pb in seawater using the Nobias-chelate PA1 resin and magnetic sector inductively coupled plasma mass spectrometry (ICP-MS) Biller, Dondra V.; Bruland, Kenneth W. Marine Chemistry, Vol. 130-131 https://doi.org/10.1016/j.marchem.2011.12.001	journal	February 2012

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