In situ measurement of temperature and reduction of rutile titania using energy dispersive x-ray diffraction

Charalambous, Harry; Jha, Shikhar Krishn; Phuah, Xin Li; Wang, Han; Wang, Haiyan; Okasinski, John S.; Tsakalakos, Thomas

doi:10.1016/j.jeurceramsoc.2018.08.032

Title: In situ measurement of temperature and reduction of rutile titania using energy dispersive x-ray diffraction

Journal Article · Wed Aug 22 00:00:00 EDT 2018 · Journal of the European Ceramic Society

DOI:https://doi.org/10.1016/j.jeurceramsoc.2018.08.032· OSTI ID:1524579

^[1];

^[1]; Phuah, Xin Li ^[2]; Wang, Han ^[2]; Wang, Haiyan ^[2]; Okasinski, John S. ^[3]; Tsakalakos, Thomas ^[1]

Rutgers Univ., Piscataway, NJ (United States)
Purdue Univ., West Lafayette, IN (United States)
Argonne National Lab. (ANL), Lemont, IL (United States)

Using in situ energy dispersive x-ray diffraction (EDXRD) the average specimen temperature of TiO₂ in the steady state of flash is experimentally determined. Comparison of the microstructure for flash sintering and conventional sintering in addition to the temperature determined from calibration of the unit cell expansion indicates that rapid Joule heating during flash sintering causes densification and grain growth comparable with conventional sintering. An average temperature approximation model is proposed to account for greybody radiation and thermal conduction. In conclusion, the inhomogeneity of the grain growth across the sample length is confirmed to correlate with inhomogeneity in temperature distribution and this suggests a current induced Peltier effect in n-type TiO₂.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: US Department of the Navy, Office of Naval Research (ONR); Argonne National Laboratory, Advanced Photon Source; USDOE

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1524579

Journal Information:: Journal of the European Ceramic Society, Vol. 38, Issue 16; ISSN 0955-2219

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 22 works

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Title: In situ measurement of temperature and reduction of rutile titania using energy dispersive x-ray diffraction

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