Lithiation-Induced Non-Noble Metal Nanoparticles for Li–O2 Batteries

Guo, Yuanyuan; Dai, Zhengfei; Lu, Jun; Zeng, Xiaoqiao; Yuan, Yifei; Bi, Xuanxuan; Ma, Lu; Wu, Tianpin; Yan, Qingyu; Amine, Khalil

doi:10.1021/acsami.8b17417

Title: Lithiation-Induced Non-Noble Metal Nanoparticles for Li–O₂ Batteries

Journal Article · Tue Dec 04 00:00:00 EST 2018 · ACS Applied Materials and Interfaces

DOI:https://doi.org/10.1021/acsami.8b17417· OSTI ID:1515839

Guo, Yuanyuan ^[1];

^[2];

^[3]; Zeng, Xiaoqiao ^[3]; Yuan, Yifei ^[3]; Bi, Xuanxuan ^[3]; Ma, Lu ^[4]; Wu, Tianpin ^[4];

^[5];

^[3]

Argonne National Lab. (ANL), Argonne, IL (United States); Nanyang Technological Univ. (Singapore)
Nanyang Technological Univ. (Singapore); Xi’an Jiaotong Univ., Xi’an (China)
Argonne National Lab. (ANL), Argonne, IL (United States)
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Nanyang Technological Univ. (Singapore)

Low-cost and highly active electrocatalysts are attractive for Li-O₂ applications. Herein, a 3D interconnected plate architecture consisting of ultrasmall Co-Ni grains embedded in lithium hydroxide nanoplates (Co₂Ni@LiOH) is designed and prepared by a lithiation strategy at room temperature. This catalyst exhibits a remarkably reduced charge potential of similar to 3.4 V at 50 mu A cm^-2, which leads to the high roundtrip efficiency of similar to 79%, among the best levels reported and a cycle life of up to 40 cycles. The well-aligned network facilitates the oxygen diffusion and the electrolyte match penetration into the electrode. The enhanced electrical conductivity net-work improves the charge transport kinetics and more active sites are exposed, which facilitate the adsorption and dissociation of oxygen during the oxygen reduction reaction and the oxygen evolution reaction. This new catalyst design inspires the development of an effective non-noble metal catalyst for Li-O₂ batteries.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1515839

Journal Information:: ACS Applied Materials and Interfaces, Vol. 11, Issue 1; ISSN 1944-8244

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 12 works

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Title: Lithiation-Induced Non-Noble Metal Nanoparticles for Li–O₂ Batteries