Magnetic field-temperature phase diagram of multiferroic [(CH3)2NH2]Mn(HCOO)3

Clune, A. J.; Hughey, K. D.; Lee, C.; Abhyankar, N.; Ding, X.; Dalal, N. S.; Whangbo, M. -H.; Singleton, J.; Musfeldt, J. L.

doi:10.1103/PhysRevB.96.104424

Title: Magnetic field-temperature phase diagram of multiferroic $[{({CH}_{3})}_{2} {NH}_{2}] Mn {(HCOO)}_{3}$

Journal Article · Mon Sep 18 00:00:00 EDT 2017 · Physical Review B

DOI:https://doi.org/10.1103/PhysRevB.96.104424· OSTI ID:1514966

Clune, A. J. ^[1]; Hughey, K. D. ^[1]; Lee, C. ^[2]; Abhyankar, N. ^[3]; Ding, X. ^[4]; Dalal, N. S. ^[5]; Whangbo, M. -H. ^[6]; Singleton, J. ^[4]; Musfeldt, J. L. ^[7]

Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry
North Carolina State Univ., Raleigh, NC (United States). Dept. of Chemistry; Pohang Univ. of Science and Technology (POSTECH) (Korea, Republic of). Dept. of Chemistry
Florida State Univ., Tallahassee, FL (United States). Dept. of Chemistry and Biochemistry. National High Magnetic Field Lab. (MagLab); National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States). Center for Nanoscale Science and Technology
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Florida State Univ., Tallahassee, FL (United States). Dept. of Chemistry and Biochemistry. National High Magnetic Field Lab. (MagLab)
North Carolina State Univ., Raleigh, NC (United States). Dept. of Chemistry
Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry. Dept. of Physics and Astronomy

We combined here pulsed field magnetization and first-principles spin-density calculations to reveal the magnetic field-temperature phase diagram and spin state character in multiferroic $$[{({\mathrm{CH}}_{3})}_{2}{\mathrm{NH}}_{2}]\mathrm{Mn}{(\mathrm{HCOO})}_{3}$$. Despite similarities with the rare earth manganites, the phase diagram is analogous to other Mn-based quantum magnets with a 0.31 T spin flop, a 15.3 T transition to the fully polarized state, and short-range correlations that persist above the ordering temperature. The experimentally accessible saturation field opens the door to exploration of the high-field phase.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Univ. of Tennessee, Knoxville, TN (United States); Florida State Univ., Tallahassee, FL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)

Grant/Contract Number:: 89233218CNA000001; DMR-1707846; CHE 1464955; DMR-1157490

OSTI ID:: 1514966

Report Number(s):: LA-UR-17-27392

Journal Information:: Physical Review B, Vol. 96, Issue 10; ISSN 2469-9950

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 25 works

Citation information provided by
Web of Science

References (39)

Strong spin-phonon coupling in infrared and Raman spectra of ${SrMnO}_{3}$ Kamba, S.; Goian, V.; Skoromets, V. Physical Review B, Vol. 89, Issue 6 https://doi.org/10.1103/PhysRevB.89.064308	journal	February 2014
Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
Magnetic nanopantograph in the SrCu ₂ (BO ₃ ) ₂ Shastry–Sutherland lattice Radtke, Guillaume; Saúl, Andrés; Dabkowska, Hanna A. Proceedings of the National Academy of Sciences, Vol. 112, Issue 7 https://doi.org/10.1073/pnas.1421414112	journal	February 2015
Magnetic-field-induced color change in $α$ -Fe $_{2}$ O $_{3}$ single crystals Chen, P.; Lee, N.; McGill, S. Physical Review B, Vol. 85, Issue 17 https://doi.org/10.1103/PhysRevB.85.174413	journal	May 2012
Electron-Phonon and Magnetoelastic Interactions in Ferromagnetic $Co [N (CN)_{2}]_{2}$ Brinzari, T. V.; Haraldsen, J. T.; Chen, P. Physical Review Letters, Vol. 111, Issue 4 https://doi.org/10.1103/PhysRevLett.111.047202	journal	July 2013
Order–Disorder Transition and Weak Ferromagnetism in the Perovskite Metal Formate Frameworks of [(CH ₃ ) ₂ NH ₂ ][M(HCOO) ₃ ] and [(CH ₃ ) ₂ ND ₂ ][M(HCOO) ₃ ] (M = Ni, Mn) Mączka, Mirosław; Gągor, Anna; Macalik, Bogusław Inorganic Chemistry, Vol. 53, Issue 1 https://doi.org/10.1021/ic402425n	journal	December 2013
Projector augmented-wave method Blöchl, P. E. Physical Review B, Vol. 50, Issue 24, p. 17953-17979 https://doi.org/10.1103/PhysRevB.50.17953	journal	December 1994
Experimentally determining the exchange parameters of quasi-two-dimensional Heisenberg magnets Goddard, P. A.; Singleton, J.; Sengupta, P. New Journal of Physics, Vol. 10, Issue 8 https://doi.org/10.1088/1367-2630/10/8/083025	journal	August 2008
Computer graphics and graphical user interfaces as tools in simulations of matter at the atomic scale Kokalj, Anton Computational Materials Science, Vol. 28, Issue 2 https://doi.org/10.1016/S0927-0256(03)00104-6	journal	October 2003
A 3D Porous Cobalt−Organic Framework Exhibiting Spin-Canted Antiferromagnetism and Field-Induced Spin-Flop Transition Huang, You-Gui; Yuan, Da-Qiang; Pan, Long Inorganic Chemistry, Vol. 46, Issue 23 https://doi.org/10.1021/ic700559z	journal	November 2007
Magnetic Susceptibility of $α {Fe}_{2} O_{3}$ and $α {Fe}_{2} O_{3}$ with Added Titanium Morin, F. J. Physical Review, Vol. 78, Issue 6 https://doi.org/10.1103/PhysRev.78.819.2	journal	June 1950
Multiferroics of spin origin Tokura, Yoshinori; Seki, Shinichiro; Nagaosa, Naoto Reports on Progress in Physics, Vol. 77, Issue 7 https://doi.org/10.1088/0034-4885/77/7/076501	journal	July 2014
Magnetic Structure and Exchange Interactions in Quasi-One-Dimensional MnCl ₂ (urea) ₂ Manson, Jamie L.; Huang, Qing-zhen; Brown, Craig M. Inorganic Chemistry, Vol. 54, Issue 24 https://doi.org/10.1021/acs.inorgchem.5b02162	journal	December 2015
Spin-Flopping in MnF2 by High Magnetic Fields Jacobs, I. S. Journal of Applied Physics, Vol. 32, Issue 3 https://doi.org/10.1063/1.2000500	journal	March 1961
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Kresse, G.; Furthmüller, J. Physical Review B, Vol. 54, Issue 16, p. 11169-11186 https://doi.org/10.1103/PhysRevB.54.11169	journal	October 1996
From ultrasoft pseudopotentials to the projector augmented-wave method Kresse, G.; Joubert, D. Physical Review B, Vol. 59, Issue 3, p. 1758-1775 https://doi.org/10.1103/PhysRevB.59.1758	journal	January 1999
Understanding Ferroelectricity in the Pb-Free Perovskite-Like Metal–Organic Framework [(CH ₃ ) ₂ NH ₂ ]Zn(HCOO) ₃ : Dielectric, 2D NMR, and Theoretical Studies Abhyankar, Nandita; Kweon, Jin Jung; Orio, Maylis The Journal of Physical Chemistry C, Vol. 121, Issue 11 https://doi.org/10.1021/acs.jpcc.7b00596	journal	March 2017
Magnetoelectric coupling in the paramagnetic state of a metal-organic framework Wang, W.; Yan, L. -Q.; Cong, J. -Z. Scientific Reports, Vol. 3, Issue 1 https://doi.org/10.1038/srep02024	journal	June 2013
Cross coupling between electric and magnetic orders in a multiferroic metal-organic framework Tian, Ying; Stroppa, Alessandro; Chai, Yisheng Scientific Reports, Vol. 4, Issue 1 https://doi.org/10.1038/srep06062	journal	August 2014
Electron-energy-loss spectra and the structural stability of nickel oxide: An LSDA+U study Dudarev, S. L.; Botton, G. A.; Savrasov, S. Y. Physical Review B, Vol. 57, Issue 3, p. 1505-1509 https://doi.org/10.1103/PhysRevB.57.1505	journal	January 1998
Combining microscopic and macroscopic probes to untangle the single-ion anisotropy and exchange energies in an $S = 1$ quantum antiferromagnet Brambleby, Jamie; Manson, Jamie L.; Goddard, Paul A. Physical Review B, Vol. 95, Issue 13 https://doi.org/10.1103/PhysRevB.95.134435	journal	April 2017
Magnetochromic effect in multiferroic $R {In}_{1 - x} {Mn}_{x} O_{3}$ ( $R = Tb$ , Dy) Chen, P.; Holinsworth, B. S.; O'Neal, K. R. Physical Review B, Vol. 91, Issue 20 https://doi.org/10.1103/PhysRevB.91.205130	journal	May 2015
Quantum Critical Transition Amplifies Magnetoelastic Coupling in $Mn [N (CN)_{2}]_{2}$ Brinzari, T. V.; Chen, P.; Sun, Q. -C. Physical Review Letters, Vol. 110, Issue 23 https://doi.org/10.1103/PhysRevLett.110.237202	journal	June 2013
Efficient synthesis and tailoring of magnetic and dielectric properties of Pb-free perovskite-like ABX ₃ metal-organic frameworks Abhyankar, Nandita; Lee, Minseong; Foley, Megan physica status solidi (RRL) - Rapid Research Letters, Vol. 10, Issue 8 https://doi.org/10.1002/pssr.201600175	journal	July 2016
Quantum criticality Coleman, Piers; Schofield, Andrew J. Nature, Vol. 433, Issue 7023 https://doi.org/10.1038/nature03279	journal	January 2005
Quantum Tunneling of Magnetization in a Metal-Organic Framework Tian, Ying; Wang, Wei; Chai, Yisheng Physical Review Letters, Vol. 112, Issue 1 https://doi.org/10.1103/PhysRevLett.112.017202	journal	January 2014
Magnetoelastic Coupling through the Antiferromagnet-to-Ferromagnet Transition of Quasi-Two-Dimensional $[Cu ({HF}_{2}) (pyz)_{2}] {BF}_{4}$ Using Infrared Spectroscopy Musfeldt, J. L.; Vergara, L. I.; Brinzari, T. V. Physical Review Letters, Vol. 103, Issue 15 https://doi.org/10.1103/PhysRevLett.103.157401	journal	October 2009
Magnetic field induced quantum phase transition of the $S = \frac{1}{2}$ antiferromagnet $K_{2} {NaCrO}_{8}$ Nellutla, S.; Pati, M.; Jo, Y. -J. Physical Review B, Vol. 81, Issue 6 https://doi.org/10.1103/PhysRevB.81.064431	journal	February 2010
Electric Control of Magnetization and Interplay between Orbital Ordering and Ferroelectricity in a Multiferroic Metal-Organic Framework Stroppa, Alessandro; Jain, Prashant; Barone, Paolo Angewandte Chemie International Edition, Vol. 50, Issue 26 https://doi.org/10.1002/anie.201101405	journal	May 2011
Successive Magnetic-Field-Induced Transitions and Colossal Magnetoelectric Effect in ${Ni}_{3} {TeO}_{6}$ Kim, Jae Wook; Artyukhin, S.; Mun, E. D. Physical Review Letters, Vol. 115, Issue 13 https://doi.org/10.1103/PhysRevLett.115.137201	journal	September 2015
Growth of centimeter-sized [(CH ₃ ) ₂ NH ₂ ][Mn(HCOO) ₃ ] hybrid formate perovskite single crystals and Raman evidence of pressure-induced phase transitions Xin, Lipeng; Fan, Zhen; Li, Guanghui New Journal of Chemistry, Vol. 41, Issue 1 https://doi.org/10.1039/C6NJ02798A	journal	January 2017
Muon spin relaxation investigation of magnetic ordering in the hybrid organic-inorganic perovskites $[{({CH}_{3})}_{2} {NH}_{2}] M {(HCOO)}_{3}$ $(M = Ni, Co, Mn, Cu)$ Baker, P. J.; Lancaster, T.; Franke, I. Physical Review B, Vol. 82, Issue 1 https://doi.org/10.1103/PhysRevB.82.012407	journal	July 2010
Strong spin-lattice coupling in CrSiTe ₃ Casto, L. D.; Clune, A. J.; Yokosuk, M. O. APL Materials, Vol. 3, Issue 4 https://doi.org/10.1063/1.4914134	journal	April 2015
Multiferroic Behavior Associated with an Order−Disorder Hydrogen Bonding Transition in Metal−Organic Frameworks (MOFs) with the Perovskite ABX ₃ Architecture Jain, Prashant; Ramachandran, Vasanth; Clark, Ronald J. Journal of the American Chemical Society, Vol. 131, Issue 38 https://doi.org/10.1021/ja904156s	journal	September 2009
Perovskite-like Metal Formates with Weak Ferromagnetism and as Precursors to Amorphous Materials Wang, Xin-Yi; Gan, Lin; Zhang, Shi-Wei Inorganic Chemistry, Vol. 43, Issue 15 https://doi.org/10.1021/ic0498081	journal	July 2004
Magnetic behavior of the metal organic framework [(CH ₃ ) ₂ NH ₂ ]Co(HCOO) ₃ Vinod, K.; Deepak, C. S.; Sharma, Shilpam RSC Advances, Vol. 5, Issue 47 https://doi.org/10.1039/C5RA01417D	journal	January 2015
Magnetoelectric Coupling through the Spin Flop Transition in ${Ni}_{3} {TeO}_{6}$ Yokosuk, M. O.; al-Wahish, Amal; Artyukhin, Sergey Physical Review Letters, Vol. 117, Issue 14 https://doi.org/10.1103/PhysRevLett.117.147402	journal	September 2016
Local structure of the metal–organic perovskite dimethylammonium manganese( ii ) formate Duncan, Helen D.; Dove, Martin T.; Keen, David A. Dalton Transactions, Vol. 45, Issue 10 https://doi.org/10.1039/C5DT03687A	journal	January 2016
Switchable electric polarization and ferroelectric domains in a metal-organic-framework Jain, Prashant; Stroppa, Alessandro; Nabok, Dmitrii npj Quantum Materials, Vol. 1, Issue 1 https://doi.org/10.1038/npjquantmats.2016.12	journal	September 2016

Cited By (8)

Strain Coupling and Dynamic Relaxation in a Molecular Perovskite-Like Multiferroic Metal-Organic Framework Xin, Lipeng; Zhang, Zhiying; Carpenter, Michael A. Advanced Functional Materials, Vol. 28, Issue 52 https://doi.org/10.1002/adfm.201806013	journal	November 2018
Magnetic field-temperature phase diagram of multiferroic (NH4)2FeCl5·H2O Clune, Amanda J.; Nam, Jisoo; Lee, Minseong npj Quantum Materials, Vol. 4, Issue 1 https://doi.org/10.1038/s41535-019-0180-1	journal	August 2019
Electron paramagnetic resonance of a copper doped [(CH ₃ ) ₂ NH ₂ ][Zn(HCOO) ₃ ] hybrid perovskite framework Šimėnas, Mantas; Ciupa, Aneta; Usevičius, Gediminas Physical Chemistry Chemical Physics, Vol. 20, Issue 17 https://doi.org/10.1039/c8cp01426d	journal	January 2018
Tuning the structure and properties of a multiferroic metal–organic-framework via growing under high magnetic fields Hu, Lin; Wang, Zhe; Wang, Hui RSC Advances, Vol. 8, Issue 25 https://doi.org/10.1039/c8ra00799c	journal	January 2018
On the origin of ferroelectric structural phases in perovskite-like metal–organic formate Sieradzki, Adam; Mączka, Mirosław; Simenas, Mantas Journal of Materials Chemistry C, Vol. 6, Issue 35 https://doi.org/10.1039/c8tc02421a	journal	January 2018
Elucidation of dipolar dynamics and the nature of structural phases in the [(CH ₃ ) ₂ NH ₂ ][Zn(HCOO) ₃ ] hybrid perovskite framework Šimėnas, Mantas; Balčiūnas, Sergejus; Ciupa, Aneta Journal of Materials Chemistry C, Vol. 7, Issue 22 https://doi.org/10.1039/c9tc01275c	journal	January 2019
First-principles study of the structural, electronic, magnetic, and ferroelectric properties of a charge-ordered iron( ii )-iron( iii ) formate framework Tang, Gang; Ren, Wei; Hong, Jiawang The Journal of Chemical Physics, Vol. 151, Issue 12 https://doi.org/10.1063/1.5116343	journal	September 2019
First-principles study of the structural, electronic, magnetic and ferroelectric properties of a charge ordered Iron(II)- Iron(III) formate framework Tang, Gang; Ren, Wei; Hong, Jiawang arXiv https://doi.org/10.48550/arxiv.1906.10512	text	January 2019

Figures / Tables (4)

Similar Records

Phonon mode links ferroicities in multiferroic

[{({CH}_{3})}_{2} {NH}_{2}] {Mn (HCOO)}_{3}

Journal Article · Wed Nov 22 00:00:00 EST 2017 · Physical Review B · OSTI ID:1514966

Hughey, Kendall D.; Clune, Amanda J.; Yokosuk, Michael O.; +9 more

Structure–Property Relations in Multiferroic [(CH₃)₂NH₂]M(HCOO)₃ (M = Mn, Co, Ni)

Journal Article · Fri Aug 24 00:00:00 EDT 2018 · Inorganic Chemistry · OSTI ID:1514966

Hughey, Kendall D.; Clune, Amanda J.; Yokosuk, Michael O.; +8 more

Magnetic properties of double perovskite

L n_{2} {CoIrO}_{6}

(L n = Eu, Tb, Ho)

: Hetero-tri-spin

3 d - 5 d - 4 f

systems

Journal Article · Thu Jan 31 00:00:00 EST 2019 · Physical Review B · OSTI ID:1514966

Ding, Xiaxin; Gao, Bin; Krenkel, Elizabeth; +4 more

Related Subjects

75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
antiferromagnetism
magnetic phase transitions
molecular magnetism
phase diagrams

Title: Magnetic field-temperature phase diagram of multiferroic [ ( CH 3 ) 2 NH 2 ] Mn ( HCOO ) 3

Citation Formats