Lithium-Doping Stabilized High-Performance P2–Na0.66Li0.18Fe0.12Mn0.7O2 Cathode for Sodium Ion Batteries

Yang, Lufeng; Li, Xiang; Liu, Jue; Xiong, Shan; Ma, Xuetian; Liu, Pan; Bai, Jianming; Xu, Wenqian; Tang, Yuanzhi; Hu, Yan -Yan; Liu, Meilin; Chen, Hailong

doi:10.1021/jacs.9b01855

Title: Lithium-Doping Stabilized High-Performance P2–Na_0.66Li_0.18Fe_0.12Mn_0.7O₂ Cathode for Sodium Ion Batteries

Journal Article · Mon Apr 01 00:00:00 EDT 2019 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.9b01855· OSTI ID:1514702

Yang, Lufeng ^[1]; Li, Xiang ^[2];

^[3]; Xiong, Shan ^[1]; Ma, Xuetian ^[1]; Liu, Pan ^[1]; Bai, Jianming ^[4]; Xu, Wenqian ^[5];

^[1];

^[6];

^[1];

^[1]

Georgia Inst. of Technology, Atlanta, GA (United States)
Florida State Univ., Tallahassee, FL (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)
Florida State Univ., Tallahassee, FL (United States); National High Magnetic Field Lab., Argonne, IL (United States)

While sodium-ion batteries (SIBs) hold great promise for large-scale electric energy storage and low speed electric vehicles, the poor capacity retention of the cathode is one of the bottlenecks in the development of SIBs. Following a strategy of using lithium doping in the transition-metal layer to stabilize the desodiated structure, we have designed and successfully synthesized a novel layered oxide cathode P2–Na_0.66Li_0.18Fe_0.12Mn_0.7O₂, which demonstrated a high capacity of 190 mAh g^–1 and a remarkably high capacity retention of ~87% after 80 cycles within a wide voltage range of 1.5–4.5 V. The outstanding stability is attributed to the reversible migration of lithium during cycling and the elimination of the detrimental P2–O2 phase transition, revealed by ex situ and in situ X-ray diffraction and solid-state nuclear magnetic resonance spectroscopy.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Brookhaven National Lab. (BNL), Upton, NY (United States); Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division

Grant/Contract Number:: SC0012704; AC02-06CH11357

OSTI ID:: 1514702

Alternate ID(s):: OSTI ID: 1548293

Report Number(s):: BNL-211624-2019-JAAM

Journal Information:: Journal of the American Chemical Society, Vol. 141, Issue 16; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 119 works

Citation information provided by
Web of Science

References (47)

Layered Oxide Cathodes for Sodium-Ion Batteries: Phase Transition, Air Stability, and Performance Wang, Peng-Fei; You, Ya; Yin, Ya-Xia Advanced Energy Materials, Vol. 8, Issue 8 https://doi.org/10.1002/aenm.201701912	journal	November 2017
Electrochemistry and Solid‐State Chemistry of NaMeO ₂ (Me = 3d Transition Metals) Kubota, Kei; Kumakura, Shinichi; Yoda, Yusuke Advanced Energy Materials, Vol. 8, Issue 17 https://doi.org/10.1002/aenm.201703415	journal	June 2018
Structural classification and properties of the layered oxides Delmas, C.; Fouassier, C.; Hagenmuller, P. Physica B+C, Vol. 99, Issue 1-4 https://doi.org/10.1016/0378-4363(80)90214-4	journal	January 1980
Challenges in Developing Electrodes, Electrolytes, and Diagnostics Tools to Understand and Advance Sodium-Ion Batteries Xu, Gui-Liang; Amine, Rachid; Abouimrane, Ali Advanced Energy Materials, Vol. 8, Issue 14 https://doi.org/10.1002/aenm.201702403	journal	February 2018
In Situ X-Ray Diffraction Study of P2-Na[sub 2/3][Ni[sub 1/3]Mn[sub 2/3]]O[sub 2] Lu, Zhonghua; Dahn, J. R. Journal of The Electrochemical Society, Vol. 148, Issue 11 https://doi.org/10.1149/1.1407247	journal	January 2001
Simulating Charge, Spin, and Orbital Ordering: Application to Jahn–Teller Distortions in Layered Transition-Metal Oxides Radin, Maxwell D.; Van der Ven, Anton Chemistry of Materials, Vol. 30, Issue 3 https://doi.org/10.1021/acs.chemmater.7b03080	journal	January 2018
Role of Crystal Symmetry in the Reversibility of Stacking-Sequence Changes in Layered Intercalation Electrodes Radin, Maxwell D.; Alvarado, Judith; Meng, Y. Shirley Nano Letters, Vol. 17, Issue 12 https://doi.org/10.1021/acs.nanolett.7b03989	journal	November 2017
Crystallographic Evolution of P2 Na _2/3 Fe _0.4 Mn _0.6 O ₂ Electrodes during Electrochemical Cycling Dose, Wesley M.; Sharma, Neeraj; Pramudita, James C. Chemistry of Materials, Vol. 28, Issue 17 https://doi.org/10.1021/acs.chemmater.6b02714	journal	August 2016
Structure and Electrochemistry of Na _x Fe _x Mn _1-x O ₂ (1.0 ≤ x ≤ 0.5) for Na-Ion Battery Positive Electrodes Thorne, J. S.; Dunlap, R. A.; Obrovac, M. N. Journal of The Electrochemical Society, Vol. 160, Issue 2 https://doi.org/10.1149/2.058302jes	journal	December 2012
P2-Na _x Mn _1/2 Fe _1/2 O ₂ Phase Used as Positive Electrode in Na Batteries: Structural Changes Induced by the Electrochemical (De)intercalation Process Mortemard de Boisse, Benoit; Carlier, Dany; Guignard, Marie Inorganic Chemistry, Vol. 53, Issue 20 https://doi.org/10.1021/ic5017802	journal	September 2014
Suppressing the P2-O2 Phase Transition of Na _0.67 Mn _0.67 Ni _0.33 O ₂ by Magnesium Substitution for Improved Sodium-Ion Batteries Wang, Peng-Fei; You, Ya; Yin, Ya-Xia Angewandte Chemie International Edition, Vol. 55, Issue 26 https://doi.org/10.1002/anie.201602202	journal	May 2016
High-Performance P2-Phase Na _2/3 Mn _0.8 Fe _0.1 Ti _0.1 O ₂ Cathode Material for Ambient-Temperature Sodium-Ion Batteries Han, Man Huon; Gonzalo, Elena; Sharma, Neeraj Chemistry of Materials, Vol. 28, Issue 1 https://doi.org/10.1021/acs.chemmater.5b03276	journal	December 2015
Enabling Sodium Batteries Using Lithium-Substituted Sodium Layered Transition Metal Oxide Cathodes Kim, Donghan; Kang, Sun-Ho; Slater, Michael Advanced Energy Materials, Vol. 1, Issue 3, p. 333-336 https://doi.org/10.1002/aenm.201000061	journal	February 2011
Identifying the Critical Role of Li Substitution in P2–Na _x [Li _y Ni _z Mn _{1– y – z} ]O ₂ (0 < x , y , z < 1) Intercalation Cathode Materials for High-Energy Na-Ion Batteries Xu, Jing; Lee, Dae Hoe; Clément, Raphaële J. Chemistry of Materials, Vol. 26, Issue 2 https://doi.org/10.1021/cm403855t	journal	December 2013
Structurally stable Mg-doped P2-Na _2/3 Mn _1−y Mg _y O ₂ sodium-ion battery cathodes with high rate performance: insights from electrochemical, NMR and diffraction studies Clément, Raphaële J.; Billaud, Juliette; Robert Armstrong, A. Energy & Environmental Science, Vol. 9, Issue 10 https://doi.org/10.1039/C6EE01750A	journal	January 2016
Water-Processable P2-Na _0.67 Ni _0.22 Cu _0.11 Mn _0.56 Ti _0.11 O ₂ Cathode Material for Sodium Ion Batteries Mu, Linqin; Hou, Qingping; Yang, Zhenzhong Journal of The Electrochemical Society, Vol. 166, Issue 2 https://doi.org/10.1149/2.0881902jes	journal	January 2019
Empowering multicomponent cathode materials for sodium ion batteries by exploring three-dimensional compositional heterogeneities Rahman, Muhammad Mominur; Xu, Yahong; Cheng, Hao Energy & Environmental Science, Vol. 11, Issue 9 https://doi.org/10.1039/C8EE00309B	journal	January 2018
Review—Manganese-Based P2-Type Transition Metal Oxides as Sodium-Ion Battery Cathode Materials Clément, Raphaële J.; Bruce, Peter G.; Grey, Clare P. Journal of The Electrochemical Society, Vol. 162, Issue 14 https://doi.org/10.1149/2.0201514jes	journal	January 2015
Direct evidence for high Na ⁺ mobility and high voltage structural processes in P2-Na _x [Li _y Ni _z Mn _1−y−z ]O ₂ (x, y, z ≤ 1) cathodes from solid-state NMR and DFT calculations Clément, R. J.; Xu, J.; Middlemiss, D. S. Journal of Materials Chemistry A, Vol. 5, Issue 8 https://doi.org/10.1039/C6TA09601H	journal	January 2017
Layered P2–O3 sodium-ion cathodes derived from earth abundant elements Bianchini, Marco; Gonzalo, Elena; Drewett, Nicholas E. Journal of Materials Chemistry A, Vol. 6, Issue 8 https://doi.org/10.1039/C7TA11180K	journal	January 2018
NaAlTi3O8, A Novel Anode Material for Sodium Ion Battery Ma, Xuetian; An, Ke; Bai, Jianming Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/s41598-017-00202-y	journal	March 2017
Sidorenkite (Na ₃ MnPO ₄ CO ₃ ): A New Intercalation Cathode Material for Na-Ion Batteries Chen, Hailong; Hao, Qing; Zivkovic, Olivera Chemistry of Materials, Vol. 25, Issue 14 https://doi.org/10.1021/cm400805q	journal	July 2013
The structural and dynamical properties of Al clusters adsorbed on Ni surface Wang, Y. X.; Pan, Z. Y.; Ho, Y. K. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 180, Issue 1-4, p. 251-256 https://doi.org/10.1016/S0168-583X(01)00425-6	journal	June 2001
Fundamental parameters line profile fitting in laboratory diffractometers Cheary, R. W.; Coelho, A. A.; Cline, J. P. Journal of Research of the National Institute of Standards and Technology, Vol. 109, Issue 1 https://doi.org/10.6028/jres.109.002	journal	January 2004
New O2/P2-type Li-Excess Layered Manganese Oxides as Promising Multi-Functional Electrode Materials for Rechargeable Li/Na Batteries Yabuuchi, Naoaki; Hara, Ryo; Kajiyama, Masataka Advanced Energy Materials, Vol. 4, Issue 13 https://doi.org/10.1002/aenm.201301453	journal	May 2014
Detailed Studies of a High-Capacity Electrode Material for Rechargeable Batteries, Li ₂ MnO ₃ −LiCo _1/3 Ni _1/3 Mn _1/3 O ₂ Yabuuchi, Naoaki; Yoshii, Kazuhiro; Myung, Seung-Taek Journal of the American Chemical Society, Vol. 133, Issue 12 https://doi.org/10.1021/ja108588y	journal	March 2011
Fundamental understanding and practical challenges of anionic redox activity in Li-ion batteries Assat, Gaurav; Tarascon, Jean-Marie Nature Energy, Vol. 3, Issue 5 https://doi.org/10.1038/s41560-018-0097-0	journal	April 2018
Oxygen redox chemistry without excess alkali-metal ions in Na2/3[Mg0.28Mn0.72]O2 Maitra, Urmimala; House, Robert A.; Somerville, James W. Nature Chemistry, Vol. 10, Issue 3 https://doi.org/10.1038/nchem.2923	journal	January 2018
The structural and chemical origin of the oxygen redox activity in layered and cation-disordered Li-excess cathode materials Seo, Dong-Hwa; Lee, Jinhyuk; Urban, Alexander Nature Chemistry, Vol. 8, Issue 7 https://doi.org/10.1038/nchem.2524	journal	May 2016
Lithium- and Manganese-Rich Oxide Cathode Materials for High-Energy Lithium Ion Batteries Wang, Jun; He, Xin; Paillard, Elie Advanced Energy Materials, Vol. 6, Issue 21 https://doi.org/10.1002/aenm.201600906	journal	August 2016
Operando X-ray Absorption Study of the Redox Processes Involved upon Cycling of the Li-Rich Layered Oxide Li _1.20 Mn _0.54 Co _0.13 Ni _0.13 O ₂ in Li Ion Batteries Koga, H.; Croguennec, L.; Ménétrier, M. The Journal of Physical Chemistry C, Vol. 118, Issue 11 https://doi.org/10.1021/jp412197z	journal	March 2014
Reversible anionic redox chemistry in high-capacity layered-oxide electrodes Sathiya, M.; Rousse, G.; Ramesha, K. Nature Materials, Vol. 12, Issue 9 https://doi.org/10.1038/nmat3699	journal	July 2013
Charge-compensation in 3d-transition-metal-oxide intercalation cathodes through the generation of localized electron holes on oxygen Luo, Kun; Roberts, Matthew R.; Hao, Rong Nature Chemistry, Vol. 8, Issue 7 https://doi.org/10.1038/nchem.2471	journal	March 2016
A Comparative Study of Layered Transition Metal Oxide Cathodes for Application in Sodium-Ion Battery Hasa, Ivana; Buchholz, Daniel; Passerini, Stefano ACS Applied Materials & Interfaces, Vol. 7, Issue 9 https://doi.org/10.1021/am5080437	journal	February 2015
P2-type Na0.67Mn0.65Fe0.2Ni0.15O2 Cathode Material with High-capacity for Sodium-ion Battery Yuan, Dingding; Hu, Xiaohong; Qian, Jiangfeng Electrochimica Acta, Vol. 116 https://doi.org/10.1016/j.electacta.2013.10.211	journal	January 2014
P2-type Nax[Fe1/2Mn1/2]O2 made from earth-abundant elements for rechargeable Na batteries Yabuuchi, Naoaki; Kajiyama, Masataka; Iwatate, Junichi Nature Materials, Vol. 11, Issue 6 https://doi.org/10.1038/nmat3309	journal	April 2012
Electrochemical Properties of Monoclinic NaMnO2 Ma, Xiaohua; Chen, Hailong; Ceder, Gerbrand Journal of The Electrochemical Society, Vol. 158, Issue 12 https://doi.org/10.1149/2.035112jes	journal	January 2011
Elucidating anionic oxygen activity in lithium-rich layered oxides Xu, Jing; Sun, Meiling; Qiao, Ruimin Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-03403-9	journal	March 2018
Reversible anionic redox activity in Na ₃ RuO ₄ cathodes: a prototype Na-rich layered oxide Qiao, Yu; Guo, Shaohua; Zhu, Kai Energy & Environmental Science, Vol. 11, Issue 2 https://doi.org/10.1039/C7EE03554C	journal	January 2018
Coupling between oxygen redox and cation migration explains unusual electrochemistry in lithium-rich layered oxides Gent, William E.; Lim, Kipil; Liang, Yufeng Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-02041-x	journal	December 2017
Lithiation and Delithiation Dynamics of Different Li Sites in Li-Rich Battery Cathodes Studied by Operando Nuclear Magnetic Resonance Li, Xiang; Tang, Mingxue; Feng, Xuyong Chemistry of Materials, Vol. 29, Issue 19 https://doi.org/10.1021/acs.chemmater.7b02589	journal	September 2017
⁶ Li and ⁷ Li MAS NMR Studies of Lithium Manganate Cathode Materials Lee, Young Joo; Wang, Francis; Grey, Clare P. Journal of the American Chemical Society, Vol. 120, Issue 48 https://doi.org/10.1021/ja9817794	journal	December 1998
NMR Studies of Cathode Materials for Lithium-Ion Rechargeable Batteries Grey, Clare P.; Dupré, Nicolas Chemical Reviews, Vol. 104, Issue 10 https://doi.org/10.1021/cr020734p	journal	October 2004
New manganese dioxides for lithium batteries Bowden, W.; Bofinger, T.; Zhang, F. Journal of Power Sources, Vol. 165, Issue 2 https://doi.org/10.1016/j.jpowsour.2006.10.041	journal	March 2007
High Reversibility of Lattice Oxygen Redox Quantified by Direct Bulk Probes of Both Anionic and Cationic Redox Reactions Dai, Kehua; Wu, Jinpeng; Zhuo, Zengqing Joule, Vol. 3, Issue 2 https://doi.org/10.1016/j.joule.2018.11.014	journal	February 2019
Anionic and cationic redox and interfaces in batteries: Advances from soft X-ray absorption spectroscopy to resonant inelastic scattering Yang, Wanli; Devereaux, Thomas P. Journal of Power Sources, Vol. 389 https://doi.org/10.1016/j.jpowsour.2018.04.018	journal	June 2018
Unified picture of anionic redox in Li/Na-ion batteries Ben Yahia, Mouna; Vergnet, Jean; Saubanère, Matthieu Nature Materials, Vol. 18, Issue 5 https://doi.org/10.1038/s41563-019-0318-3	journal	March 2019

Cited By (3)

Li‐doping stabilized P2‐Li _0.2 Na _1.0 Mn _0.8 O ₂ sodium ion cathode with oxygen redox activity Zhu, Youhuan; Nie, Wangyan; Chen, Pengpeng International Journal of Energy Research, Vol. 44, Issue 4 https://doi.org/10.1002/er.5120	journal	December 2019
P2‐Na _0.67 Al _x Mn _{1− x} O ₂ : Cost‐Effective, Stable and High‐Rate Sodium Electrodes by Suppressing Phase Transitions and Enhancing Sodium Cation Mobility Liu, Xiangsi; Zuo, Wenhua; Zheng, Bizhu Angewandte Chemie, Vol. 131, Issue 50 https://doi.org/10.1002/ange.201911698	journal	October 2019
P2-Na 0.67 Al x Mn 1− x O 2 : Cost-Effective, Stable and High-Rate Sodium Electrodes by Suppressing Phase Transitions and Enhancing Sodium Cation Mobility Liu, Xiangsi; Zuo, Wenhua; Zheng, Bizhu Angewandte Chemie International Edition, Vol. 58, Issue 50 https://doi.org/10.1002/anie.201911698	journal	October 2019

Similar Records

Utilizing Co²⁺/Co³⁺ Redox Couple in P2-Layered Na_0.66Co_0.22 Mn_0.44Ti_0.34O₂ Cathode for Sodium-Ion Batteries

Journal Article · Thu Jul 06 00:00:00 EDT 2017 · Advanced Science · OSTI ID:1514702

Wang, Qin-Chao; Hu, Enyuan; Pan, Yang; +7 more

A Co- and Ni-Free P2/O3 Biphasic Lithium Stabilized Layered Oxide for Sodium-Ion Batteries and its Cycling Behavior

Journal Article · Fri Aug 21 00:00:00 EDT 2020 · Advanced Functional Materials · OSTI ID:1514702

Yang, Liangtao; Amo, Juan López; Shadike, Zulipiya; +8 more

Realizing Complete Solid-Solution Reaction in High Sodium Content P2-Type Cathode for High-Performance Sodium-Ion Batteries

Journal Article · Fri Jun 05 00:00:00 EDT 2020 · Angewandte Chemie · OSTI ID:1514702

Jin, Ting; Wang, Peng‐Fei; Wang, Qin‐Chao; +7 more

Related Subjects

25 ENERGY STORAGE

Title: Lithium-Doping Stabilized High-Performance P2–Na0.66Li0.18Fe0.12Mn0.7O2 Cathode for Sodium Ion Batteries

Citation Formats

References (47)

Cited By (3)

Similar Records

Related Subjects

Title: Lithium-Doping Stabilized High-Performance P2–Na_0.66Li_0.18Fe_0.12Mn_0.7O₂ Cathode for Sodium Ion Batteries