Simultaneously Dual Modification of Ni-Rich Layered Oxide Cathode for High-Energy Lithium-Ion Batteries

Yang, Huiping; Wu, Hong ‐Hui; Ge, Mingyuan; Li, Lingjun; Yuan, Yifei; Yao, Qi; Chen, Jie; Xia, Lingfeng; Zheng, Jiangming; Chen, Zhaoyong; Duan, Junfei; Kisslinger, Kim; Zeng, Xiao Cheng; Lee, Wah ‐Keat; Zhang, Qiaobao; Lu, Jun

doi:10.1002/adfm.201808825

Title: Simultaneously Dual Modification of Ni-Rich Layered Oxide Cathode for High-Energy Lithium-Ion Batteries

Journal Article · Thu Feb 07 00:00:00 EST 2019 · Advanced Functional Materials

DOI:https://doi.org/10.1002/adfm.201808825· OSTI ID:1513538

Yang, Huiping ^[1]; Wu, Hong ‐Hui ^[2]; Ge, Mingyuan ^[3]; Li, Lingjun ^[1]; Yuan, Yifei ^[4]; Yao, Qi ^[1]; Chen, Jie ^[1]; Xia, Lingfeng ^[1]; Zheng, Jiangming ^[5]; Chen, Zhaoyong ^[1]; Duan, Junfei ^[1]; Kisslinger, Kim ^[3]; Zeng, Xiao Cheng ^[2]; Lee, Wah ‐Keat ^[3]; Zhang, Qiaobao ^[6];

^[4]

Changsha Univ. of Science and Technology, Changsha (People's Republic of China)
Univ. of Nebraska‐Lincoln, Lincoln, NE (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)
NingDe Ampere Technology Ltd., Fujian (China)
Xiamen Univ., Fujian (China)

A critical challenge in the commercialization of layer-structured Ni-rich materials is the fast capacity drop and voltage fading due to the interfacial instability and bulk structural degradation of the cathodes during battery operation. Herein, with the guidance of theoretical calculations of migration energy difference between La and Ti from the surface to the inside of LiNi_0.8Co_0.1Mn_0.1O₂, for the first time, Ti-doped and La₄NiLiO₈-coated LiNi_0.8Co_0.1Mn_0.1O₂ cathodes are rationally designed and prepared, via a simple and convenient dual-modification strategy of synchronous synthesis and in situ modification. Impressively, the dual modified materials show remarkably improved electrochemical performance and largely suppressed voltage fading, even under exertive operational conditions at elevated temperature and under extended cutoff voltage. Further studies reveal that the nanoscale structural degradation on material surfaces and the appearance of intergranular cracks associated with the inconsistent evolution of structural degradation at the particle level can be effectively suppressed by the synergetic effect of the conductive La₄NiLiO₈ coating layer and the strong Ti—O bond. The present work demonstrates that our strategy can simultaneously address the two issues with respect to interfacial instability and bulk structural degradation, and it represents a significant progress in the development of advanced cathode materials for high-performance lithium-ion batteries.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States); Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012704; AC02-06CH11357

OSTI ID:: 1513538

Alternate ID(s):: OSTI ID: 1493848; OSTI ID: 1506672

Report Number(s):: BNL-211647-2019-JAAM

Journal Information:: Advanced Functional Materials, Vol. 29, Issue 13; ISSN 1616-301X

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 432 works

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References (64)

Surface/Interfacial Structure and Chemistry of High-Energy Nickel-Rich Layered Oxide Cathodes: Advances and Perspectives Hou, Peiyu; Yin, Jiangmei; Ding, Meng Small, Vol. 13, Issue 45 https://doi.org/10.1002/smll.201701802	journal	October 2017
LiLaPO4-coated Li[Ni0.5Co0.2Mn0.3]O2 and AlF3-coated Li[Ni0.5Co0.2Mn0.3]O2 blend composite for lithium ion batteries Song, Han Gab; Park, Yong Joon Materials Research Bulletin, Vol. 47, Issue 10 https://doi.org/10.1016/j.materresbull.2012.04.127	journal	October 2012
Reaction mechanism and kinetics of lithium ion battery cathode material LiNiO2 with CO2 Liu, Hansan; Yang, Yong; Zhang, Jiujun Journal of Power Sources, Vol. 173, Issue 1 https://doi.org/10.1016/j.jpowsour.2007.04.083	journal	November 2007
In situ formed LiNi0.8Co0.15Al0.05O2@Li4SiO4 composite cathode material with high rate capability and long cycling stability for lithium-ion batteries Zheng, Jun-chao; Yang, Zhuo; He, Zhen-jiang Nano Energy, Vol. 53 https://doi.org/10.1016/j.nanoen.2018.09.014	journal	November 2018
Controllable Solid Electrolyte Interphase in Nickel-Rich Cathodes by an Electrochemical Rearrangement for Stable Lithium-Ion Batteries Kim, Junhyeok; Lee, Jieun; Ma, Hyunsoo Advanced Materials, Vol. 30, Issue 5 https://doi.org/10.1002/adma.201704309	journal	December 2017
Improved Cycling Stability of Na-Doped Cathode Materials Li _1.2 Ni _0.2 Mn _0.6 O ₂ via a Facile Synthesis Liu, Yunjian; Liu, Dongming; Wu, Hong-Hui ACS Sustainable Chemistry & Engineering, Vol. 6, Issue 10 https://doi.org/10.1021/acssuschemeng.8b02552	journal	August 2018
Fluorescent Anion Receptor of Tweezer-type: Using Pyrene Amide Unit with Cationic Pyridinium Skeleton Ryu, Byung-Ju; Lee, Ah-Leum; Lee, Young-Ju Bulletin of the Korean Chemical Society, Vol. 30, Issue 12 https://doi.org/10.5012/bkcs.2009.30.12.3089	journal	December 2009
Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries Lin, Feng; Markus, Isaac M.; Nordlund, Dennis Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4529	journal	March 2014
Mn(II) deposition on anodes and its effects on capacity fade in spinel lithium manganate–carbon systems Zhan, Chun; Lu, Jun; Jeremy Kropf, A. Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3437	journal	September 2013
A New Coating Method for Alleviating Surface Degradation of LiNi _0.6 Co _0.2 Mn _0.2 O ₂ Cathode Material: Nanoscale Surface Treatment of Primary Particles Kim, Hyejung; Kim, Min Gyu; Jeong, Hu Young Nano Letters, Vol. 15, Issue 3 https://doi.org/10.1021/acs.nanolett.5b00045	journal	February 2015
A grid-based Bader analysis algorithm without lattice bias Tang, W.; Sanville, E.; Henkelman, G. Journal of Physics: Condensed Matter, Vol. 21, Issue 8 https://doi.org/10.1088/0953-8984/21/8/084204	journal	January 2009
Factors Influencing the Irreversible Oxygen Loss and Reversible Capacity in Layered Li[Li _1/3 Mn _2/ ₃ ]O ₂ −Li[M]O ₂ (M = Mn _0.5- _y Ni _0.5- _y Co ₂ _y and Ni _1- _y Co _y ) Solid Solutions Arunkumar, T. A.; Wu, Y.; Manthiram, A. Chemistry of Materials, Vol. 19, Issue 12 https://doi.org/10.1021/cm070389q	journal	June 2007
Improved high voltage electrochemical performance of Li2ZrO3-coated LiNi0.5Co0.2Mn0.3O2 cathode material Wang, Ding; Li, Xinhai; Wang, Zhixing Journal of Alloys and Compounds, Vol. 647 https://doi.org/10.1016/j.jallcom.2015.06.071	journal	October 2015
Unraveling the Origin of Instability in Ni-Rich LiNi _{1–2 x} Co _x Mn _x O ₂ (NCM) Cathode Materials Liang, Chaoping; Kong, Fantai; Longo, Roberto C. The Journal of Physical Chemistry C, Vol. 120, Issue 12 https://doi.org/10.1021/acs.jpcc.6b00369	journal	March 2016
Effect of Al substitution sites on Li 1−x Al x (Ni 0.5 Co 0.2 Mn 0.3 ) 1−y Al y O 2 cathode materials for lithium ion batteries Li, Lingjun; Yao, Qi; Zhu, Huali Journal of Alloys and Compounds, Vol. 686 https://doi.org/10.1016/j.jallcom.2016.05.333	journal	November 2016
Oxygen Release Induced Chemomechanical Breakdown of Layered Cathode Materials Mu, Linqin; Lin, Ruoqian; Xu, Rong Nano Letters, Vol. 18, Issue 5 https://doi.org/10.1021/acs.nanolett.8b01036	journal	April 2018
High dielectric constant gate oxides for metal oxide Si transistors Robertson, John Reports on Progress in Physics, Vol. 69, Issue 2 https://doi.org/10.1088/0034-4885/69/2/R02	journal	December 2005
Multiple Linkage Modification of Lithium-Rich Layered Oxide Li _1.2 Mn _0.54 Ni _0.13 Co _0.13 O ₂ for Lithium Ion Battery Zheng, Jun-chao; Yang, Zhuo; Wang, Peng-bo ACS Applied Materials & Interfaces, Vol. 10, Issue 37 https://doi.org/10.1021/acsami.8b09256	journal	August 2018
Stabilizing the Electrode/Electrolyte Interface of LiNi _0.8 Co _0.15 Al _0.05 O ₂ through Tailoring Aluminum Distribution in Microspheres as Long-Life, High-Rate, and Safe Cathode for Lithium-Ion Batteries Hou, Peiyu; Zhang, Hongzhou; Deng, Xiaolong ACS Applied Materials & Interfaces, Vol. 9, Issue 35 https://doi.org/10.1021/acsami.7b05986	journal	August 2017
Electrochemical and Physical Properties of Ti-Substituted Layered Nickel Manganese Cobalt Oxide (NMC) Cathode Materials Kam, Kinson C.; Mehta, Apurva; Heron, John T. Journal of The Electrochemical Society, Vol. 159, Issue 8 https://doi.org/10.1149/2.060208jes	journal	January 2012
Dissolution, migration, and deposition of transition metal ions in Li-ion batteries exemplified by Mn-based cathodes – a critical review Zhan, Chun; Wu, Tianpin; Lu, Jun Energy & Environmental Science, Vol. 11, Issue 2 https://doi.org/10.1039/C7EE03122J	journal	January 2018
High-voltage positive electrode materials for lithium-ion batteries Li, Wangda; Song, Bohang; Manthiram, Arumugam Chemical Society Reviews, Vol. 46, Issue 10 https://doi.org/10.1039/C6CS00875E	journal	January 2017
Impact of Microcrack Generation and Surface Degradation on a Nickel-Rich Layered Li[Ni _0.9 Co _0.05 Mn _0.05 ]O ₂ Cathode for Lithium-Ion Batteries Sun, Ho-Hyun; Manthiram, Arumugam Chemistry of Materials, Vol. 29, Issue 19 https://doi.org/10.1021/acs.chemmater.7b03268	journal	September 2017
Cation Ordering of Zr-Doped LiNiO ₂ Cathode for Lithium-Ion Batteries Yoon, Chong S.; Choi, Min-Jae; Jun, Do-Wook Chemistry of Materials, Vol. 30, Issue 5 https://doi.org/10.1021/acs.chemmater.8b00619	journal	February 2018
Investigation on the effect of Na doping on structure and Li-ion kinetics of layered LiNi0.6Co0.2Mn0.2O2 cathode material Huang, Zhenjun; Wang, Zhixing; Jing, Qun Electrochimica Acta, Vol. 192 https://doi.org/10.1016/j.electacta.2016.01.139	journal	February 2016
Nanostructured high-energy cathode materials for advanced lithium batteries Sun, Yang-Kook; Chen, Zonghai; Noh, Hyung-Joo Nature Materials, Vol. 11, Issue 11 https://doi.org/10.1038/nmat3435	journal	October 2012
The cathode–electrolyte interface in the Li-ion battery Edström, K.; Gustafsson, T.; Thomas, J. O. Electrochimica Acta, Vol. 50, Issue 2-3 https://doi.org/10.1016/j.electacta.2004.03.049	journal	November 2004
Coupling of electrochemically triggered thermal and mechanical effects to aggravate failure in a layered cathode Yan, Pengfei; Zheng, Jianming; Chen, Tianwu Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-04862-w	journal	June 2018
Microstructural Degradation of Ni-Rich Li[Ni _x Co _y Mn ₁ _−x−y ]O ₂ Cathodes During Accelerated Calendar Aging Ryu, Hoon-Hee; Park, Geon-Tae; Yoon, Chong S. Small, Vol. 14, Issue 45 https://doi.org/10.1002/smll.201803179	journal	September 2018
TomoPy: a framework for the analysis of synchrotron tomographic data Gürsoy, Dogˇa; De Carlo, Francesco; Xiao, Xianghui Journal of Synchrotron Radiation, Vol. 21, Issue 5 https://doi.org/10.1107/S1600577514013939	journal	August 2014
Characterization and electrochemical performance of lithium-active titanium dioxide inlaid LiNi0.5Co0.2Mn0.3O2 material prepared by lithium residue-assisted method Li, Lingjun; Chen, Zhaoyong; Song, Liubin Journal of Alloys and Compounds, Vol. 638 https://doi.org/10.1016/j.jallcom.2015.03.071	journal	July 2015
Development of Microstrain in Aged Lithium Transition Metal Oxides Lee, Eung-Ju; Chen, Zonghai; Noh, Hyung-Ju Nano Letters, Vol. 14, Issue 8 https://doi.org/10.1021/nl5022859	journal	June 2014
Layered Li _x Ni _y Mn _y Co _1-2 _y O ₂ Cathodes for Lithium Ion Batteries: Understanding Local Structure via Magnetic Properties Chernova, Natasha A.; Ma, Miaomiao; Xiao, Jie Chemistry of Materials, Vol. 19, Issue 19 https://doi.org/10.1021/cm0708867	journal	September 2007
30 Years of Lithium-Ion Batteries Li, Matthew; Lu, Jun; Chen, Zhongwei Advanced Materials, Vol. 30, Issue 33 https://doi.org/10.1002/adma.201800561	journal	June 2018
Effect of titanium addition as nickel oxide formation inhibitor in nickel-rich cathode material for lithium-ion batteries Nurpeissova, Arailym; Choi, Moon Ho; Kim, Jik-Soo Journal of Power Sources, Vol. 299 https://doi.org/10.1016/j.jpowsour.2015.09.016	journal	December 2015
Improved cyclic stability of LiNi0.8Co0.1Mn0.1O2 via Ti substitution with a cut-off potential of 4.5V Du, Rui; Bi, Yujing; Yang, Wenchao Ceramics International, Vol. 41, Issue 5 https://doi.org/10.1016/j.ceramint.2015.02.026	journal	June 2015
Role of LaNiO3 in suppressing voltage decay of layered lithium-rich cathode materials Wu, Feng; Li, Qing; Bao, Liying Electrochimica Acta, Vol. 260 https://doi.org/10.1016/j.electacta.2017.12.034	journal	January 2018
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Kresse, G.; Furthmüller, J. Physical Review B, Vol. 54, Issue 16, p. 11169-11186 https://doi.org/10.1103/PhysRevB.54.11169	journal	October 1996
Tailoring Anisotropic Li-Ion Transport Tunnels on Orthogonally Arranged Li-Rich Layered Oxide Nanoplates Toward High-Performance Li-Ion Batteries Xu, Ming; Fei, Linfeng; Zhang, Weibing Nano Letters, Vol. 17, Issue 3 https://doi.org/10.1021/acs.nanolett.6b04951	journal	February 2017
Commentary: The Materials Project: A materials genome approach to accelerating materials innovation Jain, Anubhav; Ong, Shyue Ping; Hautier, Geoffroy APL Materials, Vol. 1, Issue 1 https://doi.org/10.1063/1.4812323	journal	July 2013
Modified High-Nickel Cathodes with Stable Surface Chemistry Against Ambient Air for Lithium-Ion Batteries You, Ya; Celio, Hugo; Li, Jianyu Angewandte Chemie International Edition, Vol. 57, Issue 22 https://doi.org/10.1002/anie.201801533	journal	April 2018
Effects of lithium-active manganese trioxide coating on the structural and electrochemical characteristics of LiNi0.5Co0.2Mn0.3O2 as cathode materials for lithium ion battery Li, Lingjun; Yao, Qi; Chen, Zhaoyong Journal of Alloys and Compounds, Vol. 650 https://doi.org/10.1016/j.jallcom.2015.08.041	journal	November 2015
A new insight into continuous performance decay mechanism of Ni-rich layered oxide cathode for high energy lithium ion batteries Lin, Qingyun; Guan, Wenhao; Meng, Jie Nano Energy, Vol. 54 https://doi.org/10.1016/j.nanoen.2018.09.066	journal	December 2018
Co-modification of LiNi0.5Co0.2Mn0.3O2 cathode materials with zirconium substitution and surface polypyrrole coating: towards superior high voltage electrochemical performances for lithium ion batteries Wang, Ding; Li, Xinhai; Wang, Zhixing Electrochimica Acta, Vol. 196 https://doi.org/10.1016/j.electacta.2016.02.156	journal	April 2016
Intragranular cracking as a critical barrier for high-voltage usage of layer-structured cathode for lithium-ion batteries Yan, Pengfei; Zheng, Jianming; Gu, Meng Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14101	journal	January 2017
Atomic Layer Deposition of Stable LiAlF ₄ Lithium Ion Conductive Interfacial Layer for Stable Cathode Cycling Xie, Jin; Sendek, Austin D.; Cubuk, Ekin D. ACS Nano, Vol. 11, Issue 7 https://doi.org/10.1021/acsnano.7b02561	journal	July 2017
One-minute nano-tomography using hard X-ray full-field transmission microscope Ge, Mingyuan; Coburn, David Scott; Nazaretski, Evgeny Applied Physics Letters, Vol. 113, Issue 8 https://doi.org/10.1063/1.5048378	journal	August 2018
Atomic Resolution Structural and Chemical Imaging Revealing the Sequential Migration of Ni, Co, and Mn upon the Battery Cycling of Layered Cathode Yan, Pengfei; Zheng, Jianming; Zhang, Ji-Guang Nano Letters, Vol. 17, Issue 6 https://doi.org/10.1021/acs.nanolett.7b01546	journal	May 2017
Role of V2O5 coating on LiNiO2-based materials for lithium ion battery Xiong, Xunhui; Wang, Zhixing; Yan, Guochun Journal of Power Sources, Vol. 245 https://doi.org/10.1016/j.jpowsour.2013.06.133	journal	January 2014
Sufficient Utilization of Zirconium Ions to Improve the Structure and Surface properties of Nickel-Rich Cathode Materials for Lithium-Ion Batteries He, Tao; Lu, Yun; Su, Yuefeng ChemSusChem, Vol. 11, Issue 10 https://doi.org/10.1002/cssc.201702451	journal	April 2018
Nickel-Rich Layered Cathode Materials for Automotive Lithium-Ion Batteries: Achievements and Perspectives Myung, Seung-Taek; Maglia, Filippo; Park, Kang-Joon ACS Energy Letters, Vol. 2, Issue 1 https://doi.org/10.1021/acsenergylett.6b00594	journal	December 2016
Enhanced electrochemical properties of LiCo0.5Ni0.5O2 by Ti-doping: A first-principle study Hao, Shuang; Zhao, Naiqin; Shi, Chunsheng Ceramics International, Vol. 41, Issue 2 https://doi.org/10.1016/j.ceramint.2014.10.034	journal	March 2015
Reaction Heterogeneity in LiNi _0.8 Co _0.15 Al _0.05 O ₂ Induced by Surface Layer Grenier, Antonin; Liu, Hao; Wiaderek, Kamila M. Chemistry of Materials, Vol. 29, Issue 17 https://doi.org/10.1021/acs.chemmater.7b02236	journal	August 2017
Nickel-Rich and Lithium-Rich Layered Oxide Cathodes: Progress and Perspectives Manthiram, Arumugam; Knight, James C.; Myung, Seung-Taek Advanced Energy Materials, Vol. 6, Issue 1 https://doi.org/10.1002/aenm.201501010	journal	October 2015
MnPO ₄ -Coated Li(Ni _0.4 Co _0.2 Mn _0.4 )O ₂ for Lithium(-Ion) Batteries with Outstanding Cycling Stability and Enhanced Lithiation Kinetics Chen, Zhen; Kim, Guk-Tae; Bresser, Dominic Advanced Energy Materials, Vol. 8, Issue 27 https://doi.org/10.1002/aenm.201801573	journal	August 2018
Electronic structures and thermoelectric properties of layered BiCuOCh oxychalcogenides (Ch = S, Se and Te): first-principles calculations Zou, Daifeng; Xie, Shuhong; Liu, Yunya Journal of Materials Chemistry A, Vol. 1, Issue 31 https://doi.org/10.1039/c3ta11222e	journal	January 2013
Capacity Fading of Ni-Rich Li[Ni _x Co _y Mn _{1– x – y} ]O ₂ (0.6 ≤ x ≤ 0.95) Cathodes for High-Energy-Density Lithium-Ion Batteries: Bulk or Surface Degradation? Ryu, Hoon-Hee; Park, Kang-Joon; Yoon, Chong S. Chemistry of Materials, Vol. 30, Issue 3 https://doi.org/10.1021/acs.chemmater.7b05269	journal	January 2018
Mg doping and zirconium oxyfluoride coating co-modification to enhance the high-voltage performance of LiCoO2 for lithium ion battery Wang, Zhiguo; Wang, Zhixing; Guo, Huajun Journal of Alloys and Compounds, Vol. 621 https://doi.org/10.1016/j.jallcom.2014.09.147	journal	February 2015
Significantly improving cycling performance of cathodes in lithium ion batteries: The effect of Al2O3 and LiAlO2 coatings on LiNi0.6Co0.2Mn0.2O2 Liu, Wen; Li, Xifei; Xiong, Dongbin Nano Energy, Vol. 44 https://doi.org/10.1016/j.nanoen.2017.11.010	journal	February 2018
Enabling the high capacity of lithium-rich anti-fluorite lithium iron oxide by simultaneous anionic and cationic redox Zhan, Chun; Yao, Zhenpeng; Lu, Jun Nature Energy, Vol. 2, Issue 12 https://doi.org/10.1038/s41560-017-0043-6	journal	December 2017
Enhancing Interfacial Bonding between Anisotropically Oriented Grains Using a Glue-Nanofiller for Advanced Li-Ion Battery Cathode Kim, Hyejung; Lee, Sanghan; Cho, Hyeon Advanced Materials, Vol. 28, Issue 23 https://doi.org/10.1002/adma.201506256	journal	April 2016
From Surface ZrO ₂ Coating to Bulk Zr Doping by High Temperature Annealing of Nickel-Rich Lithiated Oxides and Their Enhanced Electrochemical Performance in Lithium Ion Batteries Schipper, Florian; Bouzaglo, Hana; Dixit, Mudit Advanced Energy Materials, Vol. 8, Issue 4 https://doi.org/10.1002/aenm.201701682	journal	September 2017
Structural Changes and Thermal Stability of Charged LiNi _x Mn _y Co _z O ₂ Cathode Materials Studied by Combined In Situ Time-Resolved XRD and Mass Spectroscopy Bak, Seong-Min; Hu, Enyuan; Zhou, Yongning ACS Applied Materials & Interfaces, Vol. 6, Issue 24 https://doi.org/10.1021/am506712c	journal	December 2014
TomoPy: A framework for the analysis of synchrotron tomographic data Gürsoy, Doğa; De Carlo, Francesco; Xiao, Xianghui SPIE Optical Engineering + Applications, SPIE Proceedings https://doi.org/10.1117/12.2061373	conference	September 2014

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Decoration by dual-phase Li ₂ ZrO ₃ islands with core–shell structures enhances the electrochemical performance of high-voltage LiNi _0.5 Mn _1.5 O ₄ Zhao, R.; Li, L.; Li, Y. P. Applied Physics Letters, Vol. 116, Issue 2 https://doi.org/10.1063/1.5130432	journal	January 2020
Safety Issues in Lithium Ion Batteries: Materials and Cell Design Wu, Xiangkun; Song, Kaifang; Zhang, Xiaoyan Frontiers in Energy Research, Vol. 7 https://doi.org/10.3389/fenrg.2019.00065	journal	July 2019
Effect of Different Composition on Voltage Attenuation of Li-Rich Cathode Material for Lithium-Ion Batteries Liu, Jun; Liu, Qiming; Zhu, Huali Materials, Vol. 13, Issue 1 https://doi.org/10.3390/ma13010040	journal	December 2019
The Effects of Reversibility of H2-H3 Phase Transition on Ni-Rich Layered Oxide Cathode for High-Energy Lithium-Ion Batteries Chen, Jie; Yang, Huiping; Li, Tianhao Frontiers in Chemistry, Vol. 7 https://doi.org/10.3389/fchem.2019.00500	journal	July 2019

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