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“Interpenetration Isomerism” of Triptycene-Based Hydrogen-Bonded Organic Frameworks

Journal Article · · Angewandte Chemie (International Edition)
 [1];  [2];  [3];  [4];  [2];  [2];  [5]
  1. Northwestern Univ., Evanston, IL (United States); University of Notre Dame
  2. Northwestern Univ., Evanston, IL (United States)
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  4. Westlake University, Hangzhou (China)
  5. Northwestern Univ., Evanston, IL (United States); Tianjin University (China); University of New South Wales, Sydney (Australia)
In this work, we describe an example of “interpenetration isomerism” in three-dimensional (3D) hydrogen-bonded organic frameworks (HOFs). By exploiting the crystallization conditions for a peripherally extended triptycene H6PET, we can modulate the interpenetration of the assembled frameworks, yielding a two-fold interpenetrated structure PETHOF-1 (acs-2c topology) and a five-fold interpenetrated structure PETHOF-2 (acs-5c topology) as “interpenetration isomers”. In PETHOF-1, two individual nets are related by inversion symmetry and form an interwoven topology with a strikingly large guest-accessible volume of about 80%. In PETHOF-2, five individual nets are related by translational symmetry and are stacked in an alternating fashion. Additionally, the activated materials show permanent porosity with high Brunauer–Emmett–Teller (BET) areas exceeding 1100 m2•g-1. Finally, we believe that synthetic control over the framework interpenetration can serve as a new design strategy to construct diverse and complex supramolecular architectures from simple organic building blocks.
Research Organization:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Univ. of Notre Dame, IN (United States)
Sponsoring Organization:
USDOE; USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Scientific User Facilities Division
Grant/Contract Number:
AC02-05CH11231; AC05-00OR22725; NA0003763
OSTI ID:
1488530
Alternate ID(s):
OSTI ID: 1513397
OSTI ID: 1492749
Journal Information:
Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Journal Issue: 6 Vol. 58; ISSN 1433-7851
Publisher:
WileyCopyright Statement
Country of Publication:
United States
Language:
English

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