Structure-property relationship in layered BaMn2Sb2 and Ba2Mn3Sb2O2

Zhang, Qiang; Diao, Zhenyu; Cao, Huibo; Saleheen, Ahmad; Chapai, Ramakanta; Gong, Dongliang; Stadler, Shane; Jin, R.

doi:10.1103/PhysRevB.99.184416

Title: Structure-property relationship in layered $BaM n_{2} S b_{2}$ and $B a_{2} M n_{3} S b_{2} O_{2}$

Journal Article · Tue May 14 00:00:00 EDT 2019 · Physical Review B

DOI:https://doi.org/10.1103/PhysRevB.99.184416· OSTI ID:1515656

^[1]; Diao, Zhenyu ^[2];

^[3]; Saleheen, Ahmad ^[2]; Chapai, Ramakanta ^[2]; Gong, Dongliang ^[2]; Stadler, Shane ^[2]; Jin, R. ^[2]

Louisiana State Univ., Baton Rouge, LA (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Louisiana State Univ., Baton Rouge, LA (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Layered transition-metal compounds have received great attention owing to their physical properties. In this work, we present the structural, electronic, thermal, and magnetic properties of BaMn₂Sb₂ and Ba₂Mn₃Sb₂O₂ single crystals, both with the layered structure analogous to high-temperature Cu- and Fe-based superconductors. While the Mn moment in the MnSb₄ tetrahedral environment forms a long-range G-type antiferromagnetic (AFM) ordering in both BaMn₂Sb₂ (T_N1≈443K) and Ba₂Mn₃Sb₂O₂ (T_N1≈314K), a short-range AFM order is found in the intercalated MnO₂ layer at a much lower temperature (T_N2≈60K) coexisting with long-range G-type order in MnSb₄ layer in Ba₂Mn₃Sb₂O₂. The directions of the ordered moments in these two magnetic sublattices of Ba₂Mn₃Sb₂O₂ are perpendicular to each other, even though the system is electrically conductive. The G-type AFM order in MnSb₄ layers in both compounds is distinct from the stripe-like order in Fe-based superconductors, but the in-plane magnetic structure in MnO₂ layers of Ba₂Mn₃Sb₂O₂ is found to be similar to that in the cuprates. Our study acknowledges the significant and distinct roles of the CuO₂- and FeAs₄-type transition metal layers in the structure and their magnetic and electronic properties.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725; SC0012432

OSTI ID:: 1515656

Alternate ID(s):: OSTI ID: 1512538

Journal Information:: Physical Review B, Vol. 99, Issue 18; ISSN 2469-9950

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 3 works

Citation information provided by
Web of Science

References (35)

Magnetic, transport, and thermal properties of single crystals of the layered arsenide ${BaMn}_{2} {As}_{2}$ Singh, Yogesh; Ellern, A.; Johnston, D. C. Physical Review B, Vol. 79, Issue 9 https://doi.org/10.1103/PhysRevB.79.094519	journal	March 2009
Strong magnetic correlations to 900 K in single crystals of the trigonal antiferromagnetic insulators ${SrMn}_{2} {As}_{2}$ and ${CaMn}_{2} {As}_{2}$ Sangeetha, N. S.; Pandey, Abhishek; Benson, Zackery A. Physical Review B, Vol. 94, Issue 9 https://doi.org/10.1103/PhysRevB.94.094417	journal	September 2016
Structure and magnetic properties of $L n MnSbO$ ( $L n = La$ and Ce) Zhang, Qiang; Kumar, C. M. N.; Tian, Wei Physical Review B, Vol. 93, Issue 9 https://doi.org/10.1103/PhysRevB.93.094413	journal	March 2016
Crystals, magnetic and electronic properties of a new ThCr2Si2-type BaMn2Bi2 and K-doped compositions Saparov, Bayrammurad; Sefat, Athena S. Journal of Solid State Chemistry, Vol. 204 https://doi.org/10.1016/j.jssc.2013.05.010	journal	August 2013
Superconductivity up to 29 K in SrFe ₂ As ₂ and BaFe ₂ As ₂ at high pressures Alireza, Patricia L.; Ko, Y. T. Chris; Gillett, Jack Journal of Physics: Condensed Matter, Vol. 21, Issue 1 https://doi.org/10.1088/0953-8984/21/1/012208	journal	December 2008
Darstellung und Kristallstruktur von BaMn2Sb2, BaZn2Sb2 und BaCd2Sb2 / Preparation and Crystal Structure of BaMn2Sb2 , BaZn2Sb2 and BaCd2Sb2 Brechtel, Erwin; Cordier, Gerhard; Schäfer, Herbert Zeitschrift für Naturforschung B, Vol. 34, Issue 7 https://doi.org/10.1515/znb-1979-0708	journal	July 1979
Magnetic order in ${BaMn}_{2} {As}_{2}$ from neutron diffraction measurements Singh, Yogesh; Green, M. A.; Huang, Q. Physical Review B, Vol. 80, Issue 10 https://doi.org/10.1103/PhysRevB.80.100403	journal	September 2009
An overview on iron based superconductors Aswathy, P. M.; Anooja, J. B.; Sarun, P. M. Superconductor Science and Technology, Vol. 23, Issue 7 https://doi.org/10.1088/0953-2048/23/7/073001	journal	June 2010
Antiferromagnetism in semiconducting ${SrMn}_{2} {Sb}_{2}$ and ${BaMn}_{2} {Sb}_{2}$ single crystals Sangeetha, N. S.; Smetana, V.; Mudring, A. -V. Physical Review B, Vol. 97, Issue 1 https://doi.org/10.1103/PhysRevB.97.014402	journal	January 2018
Combined Experimental and Density Functional Theory Studies on the Crystal Structures and Magnetic Properties of Mg(Mg _{1- x} Mn _x ) ₂ Sb ₂ ( x ≈ 0.25) and BaMn ₂ Sb ₂ Xia, Sheng-Qing; Myers, Chad; Bobev, Svilen European Journal of Inorganic Chemistry, Vol. 2008, Issue 27 https://doi.org/10.1002/ejic.200800572	journal	September 2008
Recent advances in magnetic structure determination by neutron powder diffraction Rodríguez-Carvajal, Juan Physica B: Condensed Matter, Vol. 192, Issue 1-2 https://doi.org/10.1016/0921-4526(93)90108-I	journal	October 1993
Chemistry of layered d -metal pnictide oxides and their potential as candidates for new superconductors Ozawa, Tadashi C.; Kauzlarich, Susan M. Science and Technology of Advanced Materials, Vol. 9, Issue 3 https://doi.org/10.1088/1468-6996/9/3/033003	journal	July 2008
Crystal chemical simulation of superconductors on the basis of oxide and intermetallic layers Volkova, L. M. Superconductor Science and Technology, Vol. 21, Issue 9 https://doi.org/10.1088/0953-2048/21/9/095019	journal	July 2008
Specific Heats at Low Temperatures Gopal, E. S. R. https://doi.org/10.1007/978-1-4684-9081-7	book	January 1966
Four-circle single-crystal neutron diffractometer at the High Flux Isotope Reactor Chakoumakos, Bryan C.; Cao, Huibo; Ye, Feng Journal of Applied Crystallography, Vol. 44, Issue 3 https://doi.org/10.1107/S0021889811012301	journal	May 2011
Synthesis, structure, and properties of tetragonal ${Sr}_{2} M_{3} {As}_{2} O_{2}$ ( $M_{3} = {Mn}_{3}$ , ${Mn}_{2} Cu$ , and ${MnZn}_{2}$ ) compounds containing alternating ${CuO}_{2}$ -type and FeAs-type layers Nath, R.; Garlea, V. O.; Goldman, A. I. Physical Review B, Vol. 81, Issue 22 https://doi.org/10.1103/PhysRevB.81.224513	journal	June 2010
Neutron-diffraction study of the carrier-concentration-induced ferromagnet-to-spin-glass transition in the diluted magnetic semiconductor ${Sn}_{1 - x}$ ${Mn}_{x}$ Te Vennix, C. W. H. M.; Frikkee, E.; Eggenkamp, P. J. T. Physical Review B, Vol. 48, Issue 6 https://doi.org/10.1103/PhysRevB.48.3770	journal	August 1993
Magnetic structure and spin excitations in ${BaMn}_{2} {Bi}_{2}$ Calder, S.; Saparov, B.; Cao, H. B. Physical Review B, Vol. 89, Issue 6 https://doi.org/10.1103/PhysRevB.89.064417	journal	February 2014
Cation effects in doped La2CuO4 superconductors Attfield, J. P.; Kharlanov, A. L.; McAllister, J. A. Nature, Vol. 394, Issue 6689 https://doi.org/10.1038/28120	journal	July 1998
Superconductivity at 38 K in the Iron Arsenide $({Ba}_{1 - x} K_{x}) {Fe}_{2} {As}_{2}$ Rotter, Marianne; Tegel, Marcus; Johrendt, Dirk Physical Review Letters, Vol. 101, Issue 10 https://doi.org/10.1103/PhysRevLett.101.107006	journal	September 2008
A new protocol for the determination of magnetic structures using simulated annealing and representational analysis (SARAh) Wills, A. S. Physica B: Condensed Matter, Vol. 276-278 https://doi.org/10.1016/S0921-4526(99)01722-6	journal	March 2000
Antiferromagnetism in ${La}_{2}$ ${CuO}_{4 - y}$ Vaknin, D.; Sinha, S. K.; Moncton, D. E. Physical Review Letters, Vol. 58, Issue 26 https://doi.org/10.1103/PhysRevLett.58.2802	journal	June 1987
A Metal-Insulator Transition of the Buried MnO ₂ Monolayer in Complex Oxide Heterostructure Liu, Heng-Jui; Lin, Jheng-Cyuan; Fang, Yue-Wen Advanced Materials, Vol. 28, Issue 41 https://doi.org/10.1002/adma.201602281	journal	August 2016
Magnetic interactions in iron superconductors studied with a five-orbital model within the Hartree-Fock and Heisenberg approximations Calderón, M. J.; León, G.; Valenzuela, B. Physical Review B, Vol. 86, Issue 10 https://doi.org/10.1103/PhysRevB.86.104514	journal	September 2012
The magnetic structures of the mixed layer pnictide oxide compounds Sr2Mn3Pn2O2 (Pn = As, Sb) Brock, Stephanie L.; Raju, N. P.; Greedan, J. E. Journal of Alloys and Compounds, Vol. 237, Issue 1-2 https://doi.org/10.1016/0925-8388(95)02066-7	journal	April 1996
Possible superconductivity in Fe-Sb based materials: Density functional study of LiFeSb Zhang, Lijun; Subedi, Alaska; Singh, D. J. Physical Review B, Vol. 78, Issue 17 https://doi.org/10.1103/PhysRevB.78.174520	journal	November 2008
Manganese-induced magnetic symmetry breaking and its correlation with the metal-insulator transition in bilayered $S r_{3} {(R u_{1 - x} M n_{x})}_{2} O_{7}$ Zhang, Qiang; Ye, Feng; Tian, Wei Physical Review B, Vol. 95, Issue 22 https://doi.org/10.1103/PhysRevB.95.220403	journal	June 2017
Structure-property relationships in a series of mixed layer pnictide oxide compounds: A2Mn3Pn2O2 (A Sr, Ba; PnP, As, Sb) Brock, Stephanie L.; Kauzlarich, Susan M. Journal of Alloys and Compounds, Vol. 241, Issue 1-2 https://doi.org/10.1016/0925-8388(96)02312-2	journal	August 1996
Resistivity and Magnetism of AMn2P2 (A = Sr, Ba): The Effect of Structure Type on Physical Properties Brock, Stephanie L.; Greedan, J. E.; Kauzlarich, Susan M. Journal of Solid State Chemistry, Vol. 113, Issue 2 https://doi.org/10.1006/jssc.1994.1375	journal	December 1994
Electronic structure and magnetism in ${BaMn}_{2} {As}_{2}$ and ${BaMn}_{2} {Sb}_{2}$ An, Jiming; Sefat, A. S.; Singh, D. J. Physical Review B, Vol. 79, Issue 7 https://doi.org/10.1103/PhysRevB.79.075120	journal	February 2009
A New Type of Antiferromagnetic Structure in the Rutile Type Crystal Yoshimori, Akio Journal of the Physical Society of Japan, Vol. 14, Issue 6 https://doi.org/10.1143/JPSJ.14.807	journal	June 1959
Crystal, magnetic and electronic structures and properties of new BaMnPnF (Pn = As, Sb, Bi) Saparov, Bayrammurad; Singh, David J.; Garlea, Vasile O. Scientific Reports, Vol. 3, Issue 1 https://doi.org/10.1038/srep02154	journal	July 2013
Superconductivity drives magnetism in $δ$ -doped ${La}_{2} {CuO}_{4}$ Suter, A.; Logvenov, G.; Boris, A. V. Physical Review B, Vol. 97, Issue 13 https://doi.org/10.1103/PhysRevB.97.134522	journal	April 2018
Magnetic exchange interactions in ${BaMn}_{2} {As}_{2}$ : A case study of the $J_{1}$ - $J_{2}$ - $J_{c}$ Heisenberg model Johnston, D. C.; McQueeney, R. J.; Lake, B. Physical Review B, Vol. 84, Issue 9 https://doi.org/10.1103/PhysRevB.84.094445	journal	September 2011
Spin reorientation and Ce-Mn coupling in antiferromagnetic oxypnictide CeMnAsO Zhang, Qiang; Tian, Wei; Peterson, Spencer G. Physical Review B, Vol. 91, Issue 6 https://doi.org/10.1103/PhysRevB.91.064418	journal	February 2015