Understanding the effects of backbone chemistry and anion type on the structure and thermal behaviors of imidazolium polyimide‐ionenes

O'Harra, Kathryn E.; Kammakakam, Irshad; Bara, Jason E.; Jackson, Enrique M.

doi:10.1002/pi.5825

Understanding the effects of backbone chemistry and anion type on the structure and thermal behaviors of imidazolium polyimide‐ionenes

Journal Article · Thu May 02 00:00:00 EDT 2019 · Polymer International

DOI:https://doi.org/10.1002/pi.5825· OSTI ID:1510359

O'Harra, Kathryn E. ^[1]; ^[1]; ^[1]; Jackson, Enrique M. ^[2]

Department of Chemical and Biological Engineering University of Alabama Tuscaloosa AL USA
NASA Marshall Space Flight Center Huntsville AL USA

Abstract

Advancements in the performance and properties of ionenes can be achieved via rational molecular design strategies which combine structural elements of ionic liquids (ILs) and high‐performance polymers. The use of imidazole‐amine molecules with asymmetric reactivity has enabled the synthesis of new bis(imidazole) diimide monomers which are then polymerized via the Menshutkin reaction, followed by anion exchange to various molecular species well known in the IL literature. In this work, three types of imidazolium polyimide‐ionene backbones were synthesized starting from 1‐(3‐aminopropyl)imidazole and pyromellitic dianhydride (PMDA) or 4,4′‐(hexafluoroisopropylidene)diphthalic anhydride (6FDA) or from 1‐(4‐aminophenyl)imidazole and 6FDA, with these monomers then reacted with para ‐dichloroxylene. The Cl ⁻ anions on the resultant ionenes were then exchanged with one of six molecular anions yielding a total of 18 distinct polymer compositions. The functional groups present within the cationic backbone as well as the anion type were observed to strongly influence both the thermal and organizational properties of these new ionenes. © 2019 Society of Chemical Industry

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0018181

OSTI ID:: 1510359

Journal Information:: Polymer International, Journal Name: Polymer International Journal Issue: 9 Vol. 68; ISSN 0959-8103

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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