Stress-induced charge-ordering process in LiMn 2 O 4

Chen, Yan; Yu, Dunji; An, Ke

doi:10.1080/21663831.2016.1197858

Title: Stress-induced charge-ordering process in LiMn ₂ O ₄

Journal Article · Mon Jul 25 00:00:00 EDT 2016 · Materials Research Letters

DOI:https://doi.org/10.1080/21663831.2016.1197858· OSTI ID:1510148

Chen, Yan ^[1]; Yu, Dunji ^[2]; An, Ke ^[1]

Chemical and Engineering Materials Division, Oak Ridge National Laboratory, Oak Ridge, TN, USA
Chemical and Engineering Materials Division, Oak Ridge National Laboratory, Oak Ridge, TN, USA, School of Chemical Engineering and Technology, Tianjin University, Tianjin, People’s Republic of China

In this letter we report the stress-induced Mn charge-ordering process in the LiMn₂O₄ spinel, evidenced by the lattice strain evolutions due to the Jahn–Teller effects. In situ neutron diffraction reveals the initial stage of this process at low stress, indicating the eg electron localization at the preferential Mn sites during the early phase transition as an underlying charge-ordering mechanism in the charge-frustrated LiMn₂O₄. The initial stage of this transition exhibits as a progressive lattice and charge evolution, without showing a first-order behavior.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Spallation Neutron Source (SNS)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1510148

Alternate ID(s):: OSTI ID: 1340435

Journal Information:: Materials Research Letters, Journal Name: Materials Research Letters Vol. 5 Journal Issue: 2; ISSN 2166-3831

Publisher:: Informa UK LimitedCopyright Statement

Country of Publication:: United Kingdom

Language:: English

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Cited by: 10 works

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Tracing Phase Transformation and Lattice Evolution in a TRIP Sheet Steel under High-Temperature Annealing by Real-Time In Situ Neutron Diffraction Yu, Dunji; Chen, Yan; Huang, Lu Crystals, Vol. 8, Issue 9 https://doi.org/10.3390/cryst8090360	journal	September 2018

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Stress-induced charge-ordering process in LiMn₂O₄ [Supplemental Data] Chen, Yan; Yu, Dunji; An, Ke https://doi.org/10.6084/m9.figshare.3498470 The current record is supplemented by this figure	figure	July 2016
Stress-induced charge-ordering process in LiMn₂O₄ [Supplementary Data] Chen, Yan; Yu, Dunji; An, Ke https://doi.org/10.6084/m9.figshare.3498470.v1 The current record is supplemented by this other	other	July 2016

Title: Stress-induced charge-ordering process in LiMn 2 O 4

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