A lithium–oxygen battery with a long cycle life in an air-like atmosphere [Lithium-oxygen batteries with long cycle life in a realistic air atmosphere]

Asadi, Mohammad; Sayahpour, Baharak; Abbasi, Pedram; Ngo, Anh T.; Karis, Klas; Jokisaari, Jacob R.; Liu, Cong; Narayanan, Badri; Gerard, Marc; Yasaei, Poya; Hu, Xuan; Mukherjee, Arijita; Lau, Kah Chun; Assary, Rajeev S.; Khalili-Araghi, Fatemeh; Klie, Robert F.; Curtiss, Larry A.; Salehi-Khojin, Amin

doi:10.1038/nature25984

A lithium–oxygen battery with a long cycle life in an air-like atmosphere [Lithium-oxygen batteries with long cycle life in a realistic air atmosphere]

Journal Article · Thu Mar 22 04:00:00 EDT 2018 · Nature (London)

DOI:https://doi.org/10.1038/nature25984· OSTI ID:1508362

Asadi, Mohammad ^[1]; Sayahpour, Baharak ^[2]; Abbasi, Pedram ^[2]; Ngo, Anh T. ^[3]; Karis, Klas ^[2]; Jokisaari, Jacob R. ^[2]; Liu, Cong ^[3]; Narayanan, Badri ^[3]; Gerard, Marc ^[2]; Yasaei, Poya ^[2]; Hu, Xuan ^[2]; Mukherjee, Arijita ^[2]; Lau, Kah Chun ^[4]; Assary, Rajeev S. ^[3]; Khalili-Araghi, Fatemeh ^[2]; Klie, Robert F. ^[2]; Curtiss, Larry A. ^[3]; Salehi-Khojin, Amin ^[2]

Univ. of Illinois at Chicago, Chicago, IL (United States); Illinois Inst. of Technology, Chicago, IL (United States)
Univ. of Illinois at Chicago, Chicago, IL (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)
California State Univ., Northridge, CA (United States)

Lithium-air batteries are considered to be a potential alternative to lithium-ion batteries for transportation applications, owing to their high theoretical specific energy. So far, however, such systems have been largely restricted to pure oxygen environments (lithium oxygen batteries) and have a limited cycle life owing to side reactions involving the cathode, anode and electrolyte. In the presence of nitrogen, carbon dioxide and water vapour, these side reactions can become even more complex. Moreover, because of the need to store oxygen, the volumetric energy densities of lithium-oxygen systems may be too small for practical applications. Here we report a system comprising a lithium carbonate-based protected anode, a molybdenum disulfide cathode and an ionic liquid/di methyl sulfoxide electrolyte that operates as a lithium-air battery in a simulated air atmosphere with a long cycle life of up to 700 cycles. We perform computational studies to provide insight into the operation of the system in this environment. Furthermore this demonstration of a lithium-oxygen battery with a long cycle life in an air-like atmosphere is an important step towards the development of this field beyond lithium-ion technology, with a possibility to obtain much higher specific energy densities than for conventional lithium ion batteries.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States); Energy Frontier Research Centers (EFRC) (United States). Center for Electrochemical Energy Science (CEES)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Scientific User Facilities Division; National Science Foundation (NSF); Univ. of Chicago, Materials Research Science & Engineering Center (MRSEC); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Joint Center for Energy Storage Research (JCESR)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1508362

Alternate ID(s):: OSTI ID: 1470182

Journal Information:: Nature (London), Journal Name: Nature (London) Journal Issue: 7697 Vol. 555; ISSN 0028-0836

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Promoting defective-Li ₂ O ₂ formation via Na doping for Li–O ₂ batteries with low charge overpotentials Lyu, Zhiyang; Wang, Tao; Guo, Rui Journal of Materials Chemistry A, Vol. 7, Issue 17 https://doi.org/10.1039/c9ta01606f	journal	January 2019
Killing two birds with one stone: a Cu ion redox mediator for a non-aqueous Li–O ₂ battery Deng, Han; Qiao, Yu; Zhang, Xueping Journal of Materials Chemistry A, Vol. 7, Issue 29 https://doi.org/10.1039/c9ta04946k	journal	January 2019
Design strategies toward catalytic materials and cathode structures for emerging Li–CO ₂ batteries Hu, Anjun; Shu, Chaozhu; Xu, Chenxi Journal of Materials Chemistry A, Vol. 7, Issue 38 https://doi.org/10.1039/c9ta06506g	journal	January 2019
The importance of anode protection towards lithium oxygen batteries Bi, Xuanxuan; Amine, Khalil; Lu, Jun Journal of Materials Chemistry A, Vol. 8, Issue 7 https://doi.org/10.1039/c9ta12414d	journal	January 2020
Lithium-air batteries: Challenges coexist with opportunities Wang, Chengyi; Xie, Zhaojun; Zhou, Zhen APL Materials, Vol. 7, Issue 4 https://doi.org/10.1063/1.5091444	journal	April 2019
Oxidative decomposition mechanisms of lithium peroxide clusters: an Ab Initio study Assary, Rajeev S.; Curtiss, Larry A. Molecular Physics, Vol. 117, Issue 9-12 https://doi.org/10.1080/00268976.2018.1559955	journal	June 2018
Operando Neutron Depth Profiling to Determine the Spatial Distribution of Li in Li-ion Batteries Verhallen, Tomas W.; Lv, Shasha; Wagemaker, Marnix Frontiers in Energy Research, Vol. 6 https://doi.org/10.3389/fenrg.2018.00062	journal	July 2018
Oxidative decomposition mechanisms of lithium peroxide clusters: an Ab Initio study Assary, Rajeev S.; Curtiss, Larry A. Figshare https://doi.org/10.6084/m9.figshare.7800962.v1	text	January 2019

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