Noninvasive Substitution of K+ Sites in Cyclodextrin Metal–Organic Frameworks by Li+ Ions

Patel, Hasmukh A.; Islamoglu, Timur; Liu, Zhichang; Nalluri, Siva Krishna Mohan; Samanta, Avik; Anamimoghadam, Ommid; Malliakas, Christos D.; Farha, Omar K.; Stoddart, J. Fraser

doi:10.1021/jacs.7b06287

Title: Noninvasive Substitution of K⁺ Sites in Cyclodextrin Metal–Organic Frameworks by Li⁺ Ions

Journal Article · Tue Aug 08 00:00:00 EDT 2017 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.7b06287· OSTI ID:1374234

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^[1]; Anamimoghadam, Ommid ^[1]; Malliakas, Christos D. ^[1];

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Department of Chemistry and ∥Integrated Molecular Structure Education and Research Center, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208-3113, United States

Co-crystallization of K+ and Li+ ions with γ-cyclodextrin (γ-CD) has been shown to substitute the K+ ion sites partially by Li+ ions, while retaining the structural integrity and accessible porosity of CD-MOF-1 (MOF, metal–organic framework). A series of experiments, in which the K+/Li+ ratio was varied with respect to that of γ-CD, have been conducted in order to achieve the highest possible proportion of Li+ ions in the framework. Attempts to obtain a CD-MOF containing only Li+ ions resulted in nonporous materials. The structural occupancy on the part of the Li+ ions in the new CD-MOF has been confirmed by single-crystal X-ray analysis by determining the vacancies of K+-ion sites and accounting for the cation/γ-CD ratio in CD-MOF-1. The proportion of Li+ ions has also been confirmed by elemental analysis, whereas powder X-ray diffraction has established the stability of the extended framework. This noninvasive synthetic approach to generating mixed-metal CD-MOFs is a promising method for obtaining porous framework unattainable de novo. Furthermore, the CO2 and H2 capture capacities of the Li+-ion-substituted CD-MOF have been shown to exceed the highest sorption capacities reported so far for CD-MOFs.

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Research Organization:: Northwestern Univ., Evanston, IL (United States). Integrated Molecular Structure Education and Research Center; Northwestern Univ., Evanston, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: FG02-08ER15967

OSTI ID:: 1374234

Alternate ID(s):: OSTI ID: 1473896; OSTI ID: 1508141

Journal Information:: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 67 works

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