Beyond fossil fuel–driven nitrogen transformations

Chen, Jingguang G.; Crooks, Richard M.; Seefeldt, Lance C.; Bren, Kara L.; Bullock, R. Morris; Darensbourg, Marcetta Y.; Holland, Patrick L.; Hoffman, Brian; Janik, Michael J.; Jones, Anne K.; Kanatzidis, Mercouri G.; King, Paul; Lancaster, Kyle M.; Lymar, Sergei V.; Pfromm, Peter; Schneider, William F.; Schrock, Richard R.

doi:10.1126/science.aar6611

Beyond fossil fuel–driven nitrogen transformations

Journal Article · Thu May 24 04:00:00 EDT 2018 · Science

DOI:https://doi.org/10.1126/science.aar6611· OSTI ID:1508046

; ; ; ; ; Darensbourg, Marcetta Y.; ; ; Janik, Michael J.; ; ; ; ; ; ; ;

This review summarizes chemical reactions of nitrogen, both oxidative and reductive reactions, as an outlook for moving beyond fossil-fuel driven reactions. The article focuses on the challenges and opportunities associated with the chemistry of N2, including thermodynamics of the nitrogen cycle, and then focusing on the reduced forms of nitrogen, primarily NH3, and then the oxidized forms. This article evolved from presentations and discussion at the workshop “Frontiers, Opportunities, and Challenges in Biochemical and Chemical N2 activation” held in October 2016, in Gaithersburg, Maryland. The workshop was sponsored by the Council on Chemical Sciences, Geosciences and Biosciences of the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. The authors thank the members of the Council for their encouragement and assistance in developing this workshop. In addition, the authors are indebted to the agencies responsible for funding of their individual research efforts, without which this work would not have been possible.

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1508046

Report Number(s):: PNNL-SA-130348

Journal Information:: Science, Journal Name: Science Journal Issue: 6391 Vol. 360; ISSN 0036-8075

Publisher:: AAAS

Country of Publication:: United States

Language:: English

References (72)

Fundamentals of Industrial Catalytic Processes Bartholomew, Calvin H.; Farrauto, Robert J. John Wiley & Sons, Inc. https://doi.org/10.1002/9780471730071	book	January 2005
Bioelectrochemical Haber-Bosch Process: An Ammonia-Producing H 2 /N 2 Fuel Cell Milton, Ross D.; Cai, Rong; Abdellaoui, Sofiene Angewandte Chemie, Vol. 129, Issue 10 https://doi.org/10.1002/ange.201612500	journal	February 2017
Bioelectrochemical Haber-Bosch Process: An Ammonia-Producing H ₂ /N ₂ Fuel Cell Milton, Ross D.; Cai, Rong; Abdellaoui, Sofiene Angewandte Chemie International Edition, Vol. 56, Issue 10 https://doi.org/10.1002/anie.201612500	journal	February 2017
Structural conservation of the B subunit in the ammonia monooxygenase/particulate methane monooxygenase superfamily: Structure of an Archaeal amoB Domain Lawton, Thomas J.; Ham, Jungwha; Sun, Tianlin Proteins: Structure, Function, and Bioinformatics, Vol. 82, Issue 9 https://doi.org/10.1002/prot.24535	journal	March 2014
The Brønsted–Evans–Polanyi Relation and the Volcano Plot for Ammonia Synthesis over Transition Metal Catalysts Logadottir, A.; Rod, T. H.; Nørskov, J. K. Journal of Catalysis, Vol. 197, Issue 2 https://doi.org/10.1006/jcat.2000.3087	journal	January 2001
Combustion Chemistry of Nitrogen Dean, Anthony M.; Bozzelli, Joseph W. Gas-Phase Combustion Chemistry https://doi.org/10.1007/978-1-4612-1310-9_2	book	January 2000
Mechanism and modeling of nitrogen chemistry in combustion Miller, James A.; Bowman, Craig T. Progress in Energy and Combustion Science, Vol. 15, Issue 4 https://doi.org/10.1016/0360-1285(89)90017-8	journal	January 1989
Twenty-five years after introduction of automotive catalysts: what next? Shelef, M.; McCabe, R. W. Catalysis Today, Vol. 62, Issue 1 https://doi.org/10.1016/S0920-5861(00)00407-7	journal	September 2000
Catalytic removal of NO Pârvulescu, V. I.; Grange, P.; Delmon, B. Catalysis Today, Vol. 46, Issue 4, p. 233-316 https://doi.org/10.1016/S0920-5861(98)00399-X	journal	December 1998
NO reduction by H2 over promoted Pt catalysts Mergler, Y. J.; Nieuwenhuys, B. E. Applied Catalysis B: Environmental, Vol. 12, Issue 2-3 https://doi.org/10.1016/S0926-3373(96)00068-9	journal	June 1997
A 1000 MWth boiler for chemical-looping combustion of solid fuels – Discussion of design and costs Lyngfelt, Anders; Leckner, Bo Applied Energy, Vol. 157 https://doi.org/10.1016/j.apenergy.2015.04.057	journal	November 2015
Plasma N2-fixation: 1900–2014 Patil, B. S.; Wang, Q.; Hessel, V. Catalysis Today, Vol. 256 https://doi.org/10.1016/j.cattod.2015.05.005	journal	November 2015
Progress in the Electrochemical Synthesis of Ammonia Kyriakou, V.; Garagounis, I.; Vasileiou, E. Catalysis Today, Vol. 286 https://doi.org/10.1016/j.cattod.2016.06.014	journal	May 2017
A review of the existing and alternative methods for greener nitrogen fixation Cherkasov, N.; Ibhadon, A. O.; Fitzpatrick, P. Chemical Engineering and Processing: Process Intensification, Vol. 90 https://doi.org/10.1016/j.cep.2015.02.004	journal	April 2015
Energy efficiency improvements in ammonia production—perspectives and uncertainties Rafiqul, Islam; Weber, Christoph; Lehmann, Bianca Energy, Vol. 30, Issue 13 https://doi.org/10.1016/j.energy.2004.12.004	journal	October 2005
A comprehensive review on PEM water electrolysis Carmo, Marcelo; Fritz, David L.; Mergel, Jürgen International Journal of Hydrogen Energy, Vol. 38, Issue 12, p. 4901-4934 https://doi.org/10.1016/j.ijhydene.2013.01.151	journal	April 2013
From the Sabatier principle to a predictive theory of transition-metal heterogeneous catalysis Medford, Andrew J.; Vojvodic, Aleksandra; Hummelshøj, Jens S. Journal of Catalysis, Vol. 328 https://doi.org/10.1016/j.jcat.2014.12.033	journal	August 2015
Metalloenzymes of the denitrification pathway Tavares, P.; Pereira, A. S.; Moura, J. J. G. Journal of Inorganic Biochemistry, Vol. 100, Issue 12 https://doi.org/10.1016/j.jinorgbio.2006.09.003	journal	December 2006
Progress in Chemical-Looping Combustion and Reforming technologies Adanez, Juan; Abad, Alberto; Garcia-Labiano, Francisco Progress in Energy and Combustion Science, Vol. 38, Issue 2, p. 215-282 https://doi.org/10.1016/j.pecs.2011.09.001	journal	April 2012
Plasma Chemistry Fridman, Alexander Cambridge University Press https://doi.org/10.1017/CBO9780511546075	book	January 2008
Plasma Catalysis: Synergistic Effects at the Nanoscale Neyts, Erik C.; Ostrikov, Kostya (Ken); Sunkara, Mahendra K. Chemical Reviews, Vol. 115, Issue 24 https://doi.org/10.1021/acs.chemrev.5b00362	journal	November 2015
Photon-Driven Nitrogen Fixation: Current Progress, Thermodynamic Considerations, and Future Outlook Medford, Andrew J.; Hatzell, Marta C. ACS Catalysis, Vol. 7, Issue 4 https://doi.org/10.1021/acscatal.7b00439	journal	March 2017
Catalytic N ₂ -to-NH ₃ Conversion by Fe at Lower Driving Force: A Proposed Role for Metallocene-Mediated PCET Chalkley, Matthew J.; Del Castillo, Trevor J.; Matson, Benjamin D. ACS Central Science, Vol. 3, Issue 3 https://doi.org/10.1021/acscentsci.7b00014	journal	February 2017
Plasma Catalysis as an Alternative Route for Ammonia Production: Status, Mechanisms, and Prospects for Progress Hong, Jungmi; Prawer, Steven; Murphy, Anthony B. ACS Sustainable Chemistry & Engineering, Vol. 6, Issue 1 https://doi.org/10.1021/acssuschemeng.7b02381	journal	November 2017
Catalytic Reduction of Dinitrogen to Ammonia at a Single Molybdenum Center Schrock, Richard R. Accounts of Chemical Research, Vol. 38, Issue 12 https://doi.org/10.1021/ar0501121	journal	December 2005
Catalytic Reduction of Dinitrogen to Ammonia at a Single Molybdenum Center Schrock, Richard R. Accounts of Chemical Research, Vol. 39, Issue 2 https://doi.org/10.1021/ar068000c	journal	January 2006
Mechanism of Nitrogen Fixation by Nitrogenase: The Next Stage Hoffman, Brian M.; Lukoyanov, Dmitriy; Yang, Zhi-Yong Chemical Reviews, Vol. 114, Issue 8 https://doi.org/10.1021/cr400641x	journal	January 2014
Recent advances in the chemistry of nitrogen fixation Chatt, Joseph.; Dilworth, Jonathan R.; Richards, Raymond L. Chemical Reviews, Vol. 78, Issue 6 https://doi.org/10.1021/cr60316a001	journal	December 1978
Nitrogen Cycle Electrocatalysis Rosca, Victor; Duca, Matteo; de Groot, Matheus T. Chemical Reviews, Vol. 109, Issue 6 https://doi.org/10.1021/cr8003696	journal	June 2009
Critical Review of Pd-Based Catalytic Treatment of Priority Contaminants in Water Chaplin, Brian P.; Reinhard, Martin; Schneider, William F. Environmental Science & Technology, Vol. 46, Issue 7 https://doi.org/10.1021/es204087q	journal	March 2012
Ammonia Production via a Two-Step Al ₂ O ₃ /AlN Thermochemical Cycle. 1. Thermodynamic, Environmental, and Economic Analyses Gálvez, M. E.; Halmann, M.; Steinfeld, A. Industrial & Engineering Chemistry Research, Vol. 46, Issue 7 https://doi.org/10.1021/ie061550u	journal	March 2007
Catalyst Design by Interpolation in the Periodic Table: Bimetallic Ammonia Synthesis Catalysts Jacobsen, Claus J. H.; Dahl, Søren; Clausen, Bjerne S. Journal of the American Chemical Society, Vol. 123, Issue 34 https://doi.org/10.1021/ja010963d	journal	August 2001
Bis(μ-oxo)dicopper in Cu-ZSM-5 and Its Role in the Decomposition of NO: A Combined in Situ XAFS, UV−Vis−Near-IR, and Kinetic Study Groothaert, Marijke H.; van Bokhoven, Jeroen A.; Battiston, Andrea A. Journal of the American Chemical Society, Vol. 125, Issue 25 https://doi.org/10.1021/ja029684w	journal	June 2003
Uncoupling Nitrogenase: Catalytic Reduction of Hydrazine to Ammonia by a MoFe Protein in the Absence of Fe Protein-ATP Danyal, Karamatullah; Inglet, Boyd S.; Vincent, Kylie A. Journal of the American Chemical Society, Vol. 132, Issue 38 https://doi.org/10.1021/ja1067178	journal	September 2010
Catalytic Reduction of Dinitrogen to Ammonia by Use of Molybdenum–Nitride Complexes Bearing a Tridentate Triphosphine as Catalysts Arashiba, Kazuya; Kinoshita, Eriko; Kuriyama, Shogo Journal of the American Chemical Society, Vol. 137, Issue 17 https://doi.org/10.1021/jacs.5b02579	journal	April 2015
Insight into the Iron–Molybdenum Cofactor of Nitrogenase from Synthetic Iron Complexes with Sulfur, Carbon, and Hydride Ligands Čorić, Ilija; Holland, Patrick L. Journal of the American Chemical Society, Vol. 138, Issue 23 https://doi.org/10.1021/jacs.6b00747	journal	June 2016
A trans -Hyponitrite Intermediate in the Reductive Coupling and Deoxygenation of Nitric Oxide by a Tricopper–Lewis Acid Complex Lionetti, Davide; de Ruiter, Graham; Agapie, Theodor Journal of the American Chemical Society, Vol. 138, Issue 15 https://doi.org/10.1021/jacs.6b01083	journal	April 2016
The In Vivo Potential-Regulated Protective Protein of Nitrogenase in Azotobacter vinelandii Supports Aerobic Bioelectrochemical Dinitrogen Reduction In Vitro Milton, Ross D.; Cai, Rong; Sahin, Selmihan Journal of the American Chemical Society, Vol. 139, Issue 26 https://doi.org/10.1021/jacs.7b04893	journal	June 2017
Mechanism of Nitrogenase H ₂ Formation by Metal-Hydride Protonation Probed by Mediated Electrocatalysis and H/D Isotope Effects Khadka, Nimesh; Milton, Ross D.; Shaw, Sudipta Journal of the American Chemical Society, Vol. 139, Issue 38 https://doi.org/10.1021/jacs.7b07311	journal	September 2017
An Ionicity Rationale to Design Solid phase Metal Nitride Reactants for Solar Ammonia Production Michalsky, Ronald; Pfromm, Peter H. The Journal of Physical Chemistry C, Vol. 116, Issue 44 https://doi.org/10.1021/jp307382r	journal	October 2012
Detonator of the population explosion Smil, Vaclav Nature, Vol. 400, Issue 6743 https://doi.org/10.1038/22672	journal	July 1999
Electrosynthesis of ammonia Pickett, Christopher J.; Talarmin, Jean Nature, Vol. 317, Issue 6038 https://doi.org/10.1038/317652a0	journal	October 1985
Isolation of an autotrophic ammonia-oxidizing marine archaeon Könneke, Martin; Bernhard, Anne E.; de la Torre, José R. Nature, Vol. 437, Issue 7058 https://doi.org/10.1038/nature03911	journal	September 2005
Catalytic conversion of nitrogen to ammonia by an iron model complex Anderson, John S.; Rittle, Jonathan; Peters, Jonas C. Nature, Vol. 501, Issue 7465 https://doi.org/10.1038/nature12435	journal	September 2013
Complete nitrification by Nitrospira bacteria Daims, Holger; Lebedeva, Elena V.; Pjevac, Petra Nature, Vol. 528, Issue 7583 https://doi.org/10.1038/nature16461	journal	November 2015
A molybdenum complex bearing PNP-type pincer ligands leads to the catalytic reduction of dinitrogen into ammonia Arashiba, Kazuya; Miyake, Yoshihiro; Nishibayashi, Yoshiaki Nature Chemistry, Vol. 3, Issue 2 https://doi.org/10.1038/nchem.906	journal	December 2010
How a century of ammonia synthesis changed the world Erisman, Jan Willem; Sutton, Mark A.; Galloway, James Nature Geoscience, Vol. 1, Issue 10 https://doi.org/10.1038/ngeo325	journal	September 2008
Overcoming ammonia synthesis scaling relations with plasma-enabled catalysis Mehta, Prateek; Barboun, Patrick; Herrera, Francisco A. Nature Catalysis, Vol. 1, Issue 4 https://doi.org/10.1038/s41929-018-0045-1	journal	April 2018
Photoemission from diamond films and substrates into water: dynamics of solvated electrons and implications for diamond photoelectrochemistry Hamers, R. J.; Bandy, J. A.; Zhu, D. Faraday Discuss., Vol. 172 https://doi.org/10.1039/C4FD00039K	journal	January 2014
Chemical looping of metal nitride catalysts: low-pressure ammonia synthesis for energy storage Michalsky, R.; Avram, A. M.; Peterson, B. A. Chemical Science, Vol. 6, Issue 7 https://doi.org/10.1039/C5SC00789E	journal	January 2015
Infrared spectroscopy of the nitrogenase MoFe protein under electrochemical control: potential-triggered CO binding Paengnakorn, P.; Ash, P. A.; Shaw, S. Chemical Science, Vol. 8, Issue 2 https://doi.org/10.1039/C6SC02860H	journal	January 2017
Ammonia synthesis from N ₂ and H ₂ O using a lithium cycling electrification strategy at atmospheric pressure McEnaney, Joshua M.; Singh, Aayush R.; Schwalbe, Jay A. Energy & Environmental Science, Vol. 10, Issue 7 https://doi.org/10.1039/C7EE01126A	journal	January 2017
Rational design of electrocatalysts and photo(electro)catalysts for nitrogen reduction to ammonia (NH ₃ ) under ambient conditions Guo, Chunxian; Ran, Jingrun; Vasileff, Anthony Energy & Environmental Science, Vol. 11, Issue 1 https://doi.org/10.1039/C7EE02220D	journal	January 2018
Electro-synthesis of ammonia from nitrogen at ambient temperature and pressure in ionic liquids Zhou, Fengling; Azofra, Luis Miguel; Ali, Muataz Energy & Environmental Science, Vol. 10, Issue 12 https://doi.org/10.1039/C7EE02716H	journal	January 2017
Electrochemical synthesis of ammonia directly from air and water using a Li+/H+/NH4+ mixed conducting electrolyte Lan, Rong; Tao, Shanwen RSC Advances, Vol. 3, Issue 39 https://doi.org/10.1039/c3ra43432j	journal	January 2013
Enzymology and ecology of the nitrogen cycle Martínez-Espinosa, Rosa María; Cole, Jeffrey A.; Richardson, David J. Biochemical Society Transactions, Vol. 39, Issue 1 https://doi.org/10.1042/BST0390175	journal	January 2011
Detailed study of the plasma-activated catalytic generation of ammonia in N2-H2 plasmas van Helden, J. H.; Wagemans, W.; Yagci, G. Journal of Applied Physics, Vol. 101, Issue 4 https://doi.org/10.1063/1.2645828	journal	February 2007
The physics of a chemically active plasma with nonequilibrium vibrational excitation of molecules Rusanov, V. D.; Fridman, A. A.; Sholin, G. V. Soviet Physics Uspekhi, Vol. 24, Issue 6 https://doi.org/10.1070/PU1981v024n06ABEH004884	journal	June 1981
Nitrosopumilus maritimus genome reveals unique mechanisms for nitrification and autotrophy in globally distributed marine crenarchaea Walker, C. B.; de la Torre, J. R.; Klotz, M. G. Proceedings of the National Academy of Sciences, Vol. 107, Issue 19 https://doi.org/10.1073/pnas.0913533107	journal	April 2010
Hydroxylamine as an intermediate in ammonia oxidation by globally abundant marine archaea Vajrala, N.; Martens-Habbena, W.; Sayavedra-Soto, L. A. Proceedings of the National Academy of Sciences, Vol. 110, Issue 3 https://doi.org/10.1073/pnas.1214272110	journal	December 2012
Nitrogenase-mimic iron-containing chalcogels for photochemical reduction of dinitrogen to ammonia Liu, Jian; Kelley, Matthew S.; Wu, Weiqiang Proceedings of the National Academy of Sciences, Vol. 113, Issue 20 https://doi.org/10.1073/pnas.1605512113	journal	May 2016
Nitrosomonas europaea cytochrome P460 is a direct link between nitrification and nitrous oxide emission Caranto, Jonathan D.; Vilbert, Avery C.; Lancaster, Kyle M. Proceedings of the National Academy of Sciences, Vol. 113, Issue 51 https://doi.org/10.1073/pnas.1611051113	journal	November 2016
Keeping the nitrogen-fixation dream alive Vicente, Emilio Jimenez; Dean, Dennis R. Proceedings of the National Academy of Sciences, Vol. 114, Issue 12 https://doi.org/10.1073/pnas.1701560114	journal	March 2017
Nitric oxide is an obligate bacterial nitrification intermediate produced by hydroxylamine oxidoreductase Caranto, Jonathan D.; Lancaster, Kyle M. Proceedings of the National Academy of Sciences, Vol. 114, Issue 31 https://doi.org/10.1073/pnas.1704504114	journal	July 2017
Plasma–catalysis: the known knowns, the known unknowns and the unknown unknowns Whitehead, J. Christopher Journal of Physics D: Applied Physics, Vol. 49, Issue 24 https://doi.org/10.1088/0022-3727/49/24/243001	journal	May 2016
Catalytic Reduction of Dinitrogen to Ammonia at a Single Molybdenum Center Yandulov, D. V. Science, Vol. 301, Issue 5629 https://doi.org/10.1126/science.1085326	journal	July 2003
Ammonia synthesis by N2 and steam electrolysis in molten hydroxide suspensions of nanoscale Fe2O3 Licht, S.; Cui, B.; Wang, B. Science, Vol. 345, Issue 6197 https://doi.org/10.1126/science.1254234	journal	August 2014
Light-driven dinitrogen reduction catalyzed by a CdS:nitrogenase MoFe protein biohybrid Brown, K. A.; Harris, D. F.; Wilker, M. B. Science, Vol. 352, Issue 6284 https://doi.org/10.1126/science.aaf2091	journal	April 2016
Dynamic multinuclear sites formed by mobilized copper ions in NO _x selective catalytic reduction Paolucci, Christopher; Khurana, Ishant; Parekh, Atish A. Science, Vol. 357, Issue 6354 https://doi.org/10.1126/science.aan5630	journal	August 2017
Standard electrode potentials involving radicals in aqueous solution: inorganic radicals (IUPAC Technical Report) Armstrong, David A.; Huie, Robert E.; Koppenol, Willem H. Pure and Applied Chemistry, Vol. 87, Issue 11-12 https://doi.org/10.1515/pac-2014-0502	journal	December 2015
Future Automotive Aftertreatment Solutions: The 150?C Challenge Workshop Report Zammit, Michael; DiMaggio, Craig L.; Kim, Chang H. https://doi.org/10.2172/1097340	report	October 2013
The physics of a chemically active plasma with nonequilibrium vibrational excitation of molecules [Fizika khimicheski aktivnoi plazmy s neravnovesnym kolebatel'nym vozbuzhdeniem molekul] Rusanov, V. D.; Fridman, A. A.; Sholin, G. V. Uspekhi Fizicheskih Nauk, Vol. 134, Issue 6 https://doi.org/10.3367/ufnr.0134.198106a.0185	journal	January 1981

Cited By (80)

Atomic Modulation, Structural Design, and Systematic Optimization for Efficient Electrochemical Nitrogen Reduction Huang, Yiyin; Babu, Dickson D.; Peng, Zhen Advanced Science, Vol. 7, Issue 4 https://doi.org/10.1002/advs.201902390	journal	January 2020
Facilitating nitrogen accessibility to boron-rich covalent organic frameworks via electrochemical excitation for efficient nitrogen fixation Liu, Sisi; Wang, Mengfan; Qian, Tao Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-11846-x	journal	August 2019
Steric Switching From Photochemical to Thermal N2 Splitting: A Computational Analysis of the Isomerization Reaction {(Cp)(Am)Mo}2(μ-η1:η1-N2) → {(Cp)(Am)Mo}2(μ-N)2 Krewald, Vera Frontiers in Chemistry, Vol. 7 https://doi.org/10.3389/fchem.2019.00352	journal	May 2019
Omeprazole Treatment Enhances Nitrogen Use Efficiency Through Increased Nitrogen Uptake and Assimilation in Corn Van Oosten, Michael James; Dell’Aversana, Emilia; Ruggiero, Alessandra Frontiers in Plant Science, Vol. 10 https://doi.org/10.3389/fpls.2019.01507	journal	December 2019
Selective Electrochemical Reduction of Nitrogen to Ammonia by Adjusting the Three-Phase Interface Wang, Haiyan; Chen, Yuzhuo; Fan, Ruxue Research, Vol. 2019 https://doi.org/10.34133/2019/1401209	journal	November 2019
Tuning the Catalytic Preference of Ruthenium Catalysts for Nitrogen Reduction by Atomic Dispersion Yu, Bing; Li, Hao; White, Jai Advanced Functional Materials, Vol. 30, Issue 6 https://doi.org/10.1002/adfm.201905665	journal	November 2019
Molybdenum Carbide Nanodots Enable Efficient Electrocatalytic Nitrogen Fixation under Ambient Conditions Cheng, Hui; Ding, Liang-Xin; Chen, Gao-Feng Advanced Materials, Vol. 30, Issue 46 https://doi.org/10.1002/adma.201803694	journal	October 2018
Nitrogen Vacancies on 2D Layered W ₂ N ₃ : A Stable and Efficient Active Site for Nitrogen Reduction Reaction Jin, Huanyu; Li, Laiquan; Liu, Xin Advanced Materials https://doi.org/10.1002/adma.201902709	journal	June 2019
2D Electrocatalysts for Converting Earth‐Abundant Simple Molecules into Value‐Added Commodity Chemicals: Recent Progress and Perspectives Yin, Huajie; Dou, Yuhai; Chen, Shan Advanced Materials https://doi.org/10.1002/adma.201904870	journal	October 2019
A General Strategy to Glassy M‐Te (M = Ru, Rh, Ir) Porous Nanorods for Efficient Electrochemical N ₂ Fixation Wang, Juan; Huang, Bolong; Ji, Yujin Advanced Materials, Vol. 32, Issue 11 https://doi.org/10.1002/adma.201907112	journal	February 2020
Atomic Nb Anchoring on Graphdiyne as a New Potential Electrocatalyst for Nitrogen Fixation: A Computational View Han, Xing‐Qi; Lang, Zhong‐Ling; Yan, Li‐Kai Advanced Theory and Simulations, Vol. 2, Issue 12 https://doi.org/10.1002/adts.201900132	journal	September 2019
Aryldiazonium Salts as Nitrogen-Based Lewis Acids: Facile Synthesis of Tuneable Azophosphonium Salts Habraken, Evi R. M.; van Leest, Nicolaas P.; Hooijschuur, Pim Angewandte Chemie, Vol. 130, Issue 37 https://doi.org/10.1002/ange.201806913	journal	August 2018
Atomically Dispersed Molybdenum Catalysts for Efficient Ambient Nitrogen Fixation Han, Lili; Liu, Xijun; Chen, Jinping Angewandte Chemie, Vol. 131, Issue 8 https://doi.org/10.1002/ange.201811728	journal	January 2019
Ammonia Synthesis Under Ambient Conditions: Selective Electroreduction of Dinitrogen to Ammonia on Black Phosphorus Nanosheets Zhang, Lili; Ding, Liang‐Xin; Chen, Gao‐Feng Angewandte Chemie, Vol. 131, Issue 9 https://doi.org/10.1002/ange.201813174	journal	January 2019
Electrochemical Hydrogenation with Gaseous Ammonia Li, Jin; He, Lingfeng; Liu, Xu Angewandte Chemie, Vol. 131, Issue 6 https://doi.org/10.1002/ange.201813464	journal	January 2019
Catalytic Ammonia Oxidation to Dinitrogen by Hydrogen Atom Abstraction Bhattacharya, Papri; Heiden, Zachariah M.; Chambers, Geoffrey M. Angewandte Chemie, Vol. 131, Issue 34 https://doi.org/10.1002/ange.201903221	journal	June 2019
High Efficiency Electrochemical Nitrogen Fixation Achieved with a Lower Pressure Reaction System by Changing the Chemical Equilibrium Cheng, Hui; Cui, Peixin; Wang, Fangrui Angewandte Chemie, Vol. 131, Issue 43 https://doi.org/10.1002/ange.201910658	journal	September 2019
Crystal‐Phase‐Engineered PdCu Electrocatalyst for Enhanced Ammonia Synthesis Tong, Wu; Huang, Bolong; Wang, Pengtang Angewandte Chemie, Vol. 132, Issue 7 https://doi.org/10.1002/ange.201913122	journal	January 2020
The Crucial Role of Charge Accumulation and Spin Polarization in Activating Carbon‐Based Catalysts for Electrocatalytic Nitrogen Reduction Yang, Yuanyuan; Zhang, Lifu; Hu, Zhenpeng Angewandte Chemie, Vol. 132, Issue 11 https://doi.org/10.1002/ange.201915001	journal	March 2020
Transition‐Metal–Boron Intermetallics with Strong Interatomic d–sp Orbital Hybridization for High‐Performance Electrocatalysis Ai, Xuan; Zou, Xu; Chen, Hui Angewandte Chemie, Vol. 132, Issue 10 https://doi.org/10.1002/ange.201915663	journal	January 2020
Aryldiazonium Salts as Nitrogen-Based Lewis Acids: Facile Synthesis of Tuneable Azophosphonium Salts Habraken, Evi R. M.; van Leest, Nicolaas P.; Hooijschuur, Pim Angewandte Chemie International Edition, Vol. 57, Issue 37 https://doi.org/10.1002/anie.201806913	journal	August 2018
Atomically Dispersed Molybdenum Catalysts for Efficient Ambient Nitrogen Fixation Han, Lili; Liu, Xijun; Chen, Jinping Angewandte Chemie International Edition, Vol. 58, Issue 8 https://doi.org/10.1002/anie.201811728	journal	January 2019
Ammonia Synthesis Under Ambient Conditions: Selective Electroreduction of Dinitrogen to Ammonia on Black Phosphorus Nanosheets Zhang, Lili; Ding, Liang-Xin; Chen, Gao-Feng Angewandte Chemie International Edition, Vol. 58, Issue 9 https://doi.org/10.1002/anie.201813174	journal	January 2019
Electrochemical Hydrogenation with Gaseous Ammonia Li, Jin; He, Lingfeng; Liu, Xu Angewandte Chemie International Edition, Vol. 58, Issue 6 https://doi.org/10.1002/anie.201813464	journal	January 2019
Catalytic Ammonia Oxidation to Dinitrogen by Hydrogen Atom Abstraction Bhattacharya, Papri; Heiden, Zachariah M.; Chambers, Geoffrey M. Angewandte Chemie International Edition, Vol. 58, Issue 34 https://doi.org/10.1002/anie.201903221	journal	June 2019
High Efficiency Electrochemical Nitrogen Fixation Achieved with a Lower Pressure Reaction System by Changing the Chemical Equilibrium Cheng, Hui; Cui, Peixin; Wang, Fangrui Angewandte Chemie International Edition, Vol. 58, Issue 43 https://doi.org/10.1002/anie.201910658	journal	September 2019
Crystal‐Phase‐Engineered PdCu Electrocatalyst for Enhanced Ammonia Synthesis Tong, Wu; Huang, Bolong; Wang, Pengtang Angewandte Chemie International Edition, Vol. 59, Issue 7 https://doi.org/10.1002/anie.201913122	journal	February 2020
The Crucial Role of Charge Accumulation and Spin Polarization in Activating Carbon‐Based Catalysts for Electrocatalytic Nitrogen Reduction Yang, Yuanyuan; Zhang, Lifu; Hu, Zhenpeng Angewandte Chemie International Edition, Vol. 59, Issue 11 https://doi.org/10.1002/anie.201915001	journal	February 2020
Transition‐Metal–Boron Intermetallics with Strong Interatomic d–sp Orbital Hybridization for High‐Performance Electrocatalysis Ai, Xuan; Zou, Xu; Chen, Hui Angewandte Chemie International Edition, Vol. 59, Issue 10 https://doi.org/10.1002/anie.201915663	journal	January 2020
Synergistic Promotion of the Electrochemical Reduction of Nitrogen to Ammonia by Phosphorus and Potassium Zhang, Qikun; Liu, Baoliang; Yu, Liping ChemCatChem, Vol. 12, Issue 1 https://doi.org/10.1002/cctc.201901519	journal	October 2019
A Combined Theory‐Experiment Analysis of the Surface Species in Lithium‐Mediated NH ₃ Electrosynthesis Schwalbe, Jay A.; Statt, Michael J.; Chosy, Cullen ChemElectroChem, Vol. 7, Issue 7 https://doi.org/10.1002/celc.201902124	journal	January 2020
A Combined Theory‐Experiment Analysis of the Surface Species in Lithium‐Mediated NH ₃ Electrosynthesis Schwalbe, Jay A.; Statt, Michael J.; Chosy, Cullen ChemElectroChem, Vol. 7, Issue 7 https://doi.org/10.1002/celc.202000265	journal	April 2020
Ambient Electrosynthesis of Ammonia on a Core–Shell‐Structured Au@CeO ₂ Catalyst: Contribution of Oxygen Vacancies in CeO ₂ Liu, Guoqiang; Cui, Zhiqing; Han, Miaomiao Chemistry – A European Journal, Vol. 25, Issue 23 https://doi.org/10.1002/chem.201806377	journal	March 2019
Advanced Non‐metallic Catalysts for Electrochemical Nitrogen Reduction under Ambient Conditions Zhang, Lili; Chen, Gao‐Feng; Ding, Liang‐Xin Chemistry – A European Journal, Vol. 25, Issue 54 https://doi.org/10.1002/chem.201901668	journal	July 2019
Ambient Electrochemical Synthesis of Ammonia from Nitrogen and Water Catalyzed by Flower-Like Gold Microstructures Wang, Ziqiang; Li, Yinghao; Yu, Hongjie ChemSusChem, Vol. 11, Issue 19 https://doi.org/10.1002/cssc.201801444	journal	September 2018
Fabrication of an Fe-Doped SrTiO ₃ Photocatalyst with Enhanced Dinitrogen Photofixation Performance: Fabrication of an Fe-Doped SrTiO ₃ Photocatalyst with Enhanced Dinitrogen Photofixation Performance Ying, Zihao; Chen, Shengtao; Peng, Tianyou European Journal of Inorganic Chemistry, Vol. 2019, Issue 16 https://doi.org/10.1002/ejic.201900098	journal	April 2019
Enhancement of Selective Fixation of Dinitrogen to Ammonia under Modal Strong Coupling Conditions: Enhancement of Selective Fixation of Dinitrogen to Ammonia under Modal Strong Coupling Conditions Oshikiri, Tomoya; Shi, Xu; Misawa, Hiroaki European Journal of Inorganic Chemistry, Vol. 2020, Issue 15-16 https://doi.org/10.1002/ejic.201901260	journal	February 2020
Enhancement of Selective Fixation of Dinitrogen to Ammonia under Modal Strong Coupling Conditions Oshikiri, Tomoya; Shi, Xu; Misawa, Hiroaki European Journal of Inorganic Chemistry, Vol. 2020, Issue 15-16 https://doi.org/10.1002/ejic.202000340	journal	April 2020
Electrochemical Fabrication of Porous Au Film on Ni Foam for Nitrogen Reduction to Ammonia Wang, Hongjing; Yu, Hongjie; Wang, Ziqiang Small, Vol. 15, Issue 6 https://doi.org/10.1002/smll.201804769	journal	January 2019
Defect Engineering Strategies for Nitrogen Reduction Reactions under Ambient Conditions Yan, Dafeng; Li, Hao; Chen, Chen Small Methods, Vol. 3, Issue 6 https://doi.org/10.1002/smtd.201800331	journal	October 2018
Computational Screening of Efficient Single‐Atom Catalysts Based on Graphitic Carbon Nitride (g‐C ₃ N ₄ ) for Nitrogen Electroreduction Chen, Zhe; Zhao, Jingxiang; Cabrera, Carlos R. Small Methods, Vol. 3, Issue 6 https://doi.org/10.1002/smtd.201800368	journal	October 2018
Recent Progress on Electrocatalyst and Photocatalyst Design for Nitrogen Reduction Li, Mengqiao; Huang, Hao; Low, Jingxiang Small Methods, Vol. 3, Issue 6 https://doi.org/10.1002/smtd.201800388	journal	October 2018
Is It Appropriate to Use the Nafion Membrane in Electrocatalytic N ₂ Reduction? Ren, Yongwen; Yu, Chang; Tan, Xinyi Small Methods, Vol. 3, Issue 12 https://doi.org/10.1002/smtd.201900474	journal	August 2019
Advances and challenges in modeling solvated reaction mechanisms for renewable fuels and chemicals Basdogan, Yasemin; Maldonado, Alex M.; Keith, John A. WIREs Computational Molecular Science, Vol. 10, Issue 2 https://doi.org/10.1002/wcms.1446	journal	August 2019
3D Hierarchical Porous Graphene-Based Energy Materials: Synthesis, Functionalization, and Application in Energy Storage and Conversion Tang, Cheng; Wang, Hao-Fan; Huang, Jia-Qi Electrochemical Energy Reviews, Vol. 2, Issue 2 https://doi.org/10.1007/s41918-019-00033-7	journal	March 2019
Formation of carbon–nitrogen bonds in carbon monoxide electrolysis Jouny, Matthew; Lv, Jing-Jing; Cheng, Tao Nature Chemistry, Vol. 11, Issue 9 https://doi.org/10.1038/s41557-019-0312-z	journal	August 2019
Capture of nitrogen dioxide and conversion to nitric acid in a porous metal–organic framework Li, Jiangnan; Han, Xue; Zhang, Xinran Nature Chemistry, Vol. 11, Issue 12 https://doi.org/10.1038/s41557-019-0356-0	journal	November 2019
The technological and economic prospects for CO2 utilization and removal Hepburn, Cameron; Adlen, Ella; Beddington, John Nature, Vol. 575, Issue 7781 https://doi.org/10.1038/s41586-019-1681-6	journal	November 2019
Promoting nitrogen electroreduction to ammonia with bismuth nanocrystals and potassium cations in water Hao, Yu-Chen; Guo, Yu; Chen, Li-Wei Nature Catalysis, Vol. 2, Issue 5 https://doi.org/10.1038/s41929-019-0241-7	journal	March 2019
Electrochemical nitrogen reduction to ammonia at ambient conditions on nitrogen and phosphorus co-doped porous carbon Song, Pengfei; Wang, Hao; Kang, Li Chemical Communications, Vol. 55, Issue 5 https://doi.org/10.1039/c8cc09256g	journal	January 2019
One-pot synthesis of bi-metallic PdRu tripods as an efficient catalyst for electrocatalytic nitrogen reduction to ammonia Wang, Hongjing; Li, Yinghao; Li, Chunjie Journal of Materials Chemistry A, Vol. 7, Issue 2 https://doi.org/10.1039/c8ta09482a	journal	January 2019
Trimetallic PdCuIr with long-spined sea-urchin-like morphology for ambient electroreduction of nitrogen to ammonia Kumar, Rajaiah Dhilip; Wang, Ziqiang; Li, Chunjie Journal of Materials Chemistry A, Vol. 7, Issue 7 https://doi.org/10.1039/c8ta10562f	journal	January 2019
Cu doping in CeO ₂ to form multiple oxygen vacancies for dramatically enhanced ambient N ₂ reduction performance Zhang, Shengbo; Zhao, Cuijiao; Liu, Yanyan Chemical Communications, Vol. 55, Issue 20 https://doi.org/10.1039/c9cc00123a	journal	January 2019
B ₄ C nanosheets decorated with in situ -derived boron-doped graphene quantum dots for high-efficiency ambient N ₂ fixation Qiu, Wei-Bin; Luo, Yu-Xi; Liang, Ru-Ping Chemical Communications, Vol. 55, Issue 51 https://doi.org/10.1039/c9cc03413g	journal	January 2019
Morphology-dependent electrocatalytic nitrogen reduction on Ag triangular nanoplates Gao, Wen-Yan; Hao, Yu-Chen; Su, Xin Chemical Communications, Vol. 55, Issue 72 https://doi.org/10.1039/c9cc04691g	journal	January 2019
Synthesis of ammonia via electrochemical nitrogen reduction on high-index faceted Au nanoparticles with a high faradaic efficiency Tan, Lianqiao; Yang, Na; Huang, Xun Chemical Communications, Vol. 55, Issue 96 https://doi.org/10.1039/c9cc06132k	journal	January 2019
High-efficiency electrocatalyst for N ₂ conversion to NH ₃ based on Au nanoparticles loaded on defective WO _3−x Li, Youzeng; Yan, Pengfei; Chen, Jun Chemical Communications, Vol. 55, Issue 88 https://doi.org/10.1039/c9cc06550d	journal	January 2019
Triple hydrogen atom abstraction from Mn–NH 3 complexes results in cyclophosphazenium cations Cook, Brian J.; Johnson, Samantha I.; Chambers, Geoffrey M. Chemical Communications, Vol. 55, Issue 93 https://doi.org/10.1039/c9cc06915a	journal	January 2019
Tuning the catalytic activity of a single Mo atom supported on graphene for nitrogen reduction via Se atom doping Zhou, Hong Yu; Li, Jian Chen; Wen, Zi Physical Chemistry Chemical Physics, Vol. 21, Issue 27 https://doi.org/10.1039/c9cp02733e	journal	January 2019
Understanding electro-catalysis by using density functional theory Chen, Z. W.; Chen, L. X.; Wen, Z. Physical Chemistry Chemical Physics, Vol. 21, Issue 43 https://doi.org/10.1039/c9cp04430b	journal	January 2019
Electrochemical nitrogen fixation and utilization: theories, advanced catalyst materials and system design Guo, Wenhan; Zhang, Kexin; Liang, Zibin Chemical Society Reviews, Vol. 48, Issue 24 https://doi.org/10.1039/c9cs00159j	journal	January 2019
How to explore ambient electrocatalytic nitrogen reduction reliably and insightfully Tang, Cheng; Qiao, Shi-Zhang Chemical Society Reviews, Vol. 48, Issue 12 https://doi.org/10.1039/c9cs00280d	journal	January 2019
Chemical looping beyond combustion – a perspective Zhu, Xing; Imtiaz, Qasim; Donat, Felix Energy & Environmental Science, Vol. 13, Issue 3 https://doi.org/10.1039/c9ee03793d	journal	January 2020
Anion (O, N, C, and S) vacancies promoted photocatalytic nitrogen fixation Mao, Chengliang; Wang, Jiaxian; Zou, Yunjie Green Chemistry, Vol. 21, Issue 11 https://doi.org/10.1039/c9gc01010f	journal	January 2019
Single molybdenum center supported on N-doped black phosphorus as an efficient electrocatalyst for nitrogen fixation Ou, Pengfei; Zhou, Xiao; Meng, Fanchao Nanoscale, Vol. 11, Issue 28 https://doi.org/10.1039/c9nr02586c	journal	January 2019
Selective decontamination of the reactive air pollutant nitrous acid via node-linker cooperativity in a metal–organic framework McGrath, Devon T.; Ryan, Michaela D.; MacInnis, John J. Chemical Science, Vol. 10, Issue 21 https://doi.org/10.1039/c9sc01357a	journal	January 2019
Excitonic Au ₄ Ru ₂ (PPh ₃ ) ₂ (SC ₂ H ₄ Ph) ₈ cluster for light-driven dinitrogen fixation Sun, Yongnan; Pei, Wei; Xie, Mingcai Chemical Science, Vol. 11, Issue 9 https://doi.org/10.1039/c9sc06424a	journal	January 2020
Pt-embedded in monolayer g-C ₃ N ₄ as a promising single-atom electrocatalyst for ammonia synthesis Yin, Hui; Li, Shu-Long; Gan, Li-Yong Journal of Materials Chemistry A, Vol. 7, Issue 19 https://doi.org/10.1039/c9ta01624d	journal	January 2019
Fluorine-free Ti ₃ C ₂ T _x (T = O, OH) nanosheets (∼50–100 nm) for nitrogen fixation under ambient conditions Li, Tengfei; Yan, Xudong; Huang, Lujun Journal of Materials Chemistry A, Vol. 7, Issue 24 https://doi.org/10.1039/c9ta03254a	journal	January 2019
Bimetallic Ag ₃ Cu porous networks for ambient electrolysis of nitrogen to ammonia Yu, Hongjie; Wang, Ziqiang; Yang, Dandan Journal of Materials Chemistry A, Vol. 7, Issue 20 https://doi.org/10.1039/c9ta03297e	journal	January 2019
Electron distribution tuning of fluorine-doped carbon for ammonia electrosynthesis Yuan, Di; Wei, Zengxi; Han, Peng Journal of Materials Chemistry A, Vol. 7, Issue 28 https://doi.org/10.1039/c9ta04141a	journal	January 2019
Facile, cost-effective plasma synthesis of self-supportive FeS _x on Fe foam for efficient electrochemical reduction of N ₂ under ambient conditions Xiong, Wei; Guo, Zheng; Zhao, Shijun Journal of Materials Chemistry A, Vol. 7, Issue 34 https://doi.org/10.1039/c9ta07790a	journal	January 2019
Atomically dispersed metal dimer species with selective catalytic activity for nitrogen electrochemical reduction Li, Yang; Zhang, Qi; Li, Can Journal of Materials Chemistry A, Vol. 7, Issue 39 https://doi.org/10.1039/c9ta07845b	journal	January 2019
Theoretical insights into nonprecious oxygen-evolution active sites in Ti–Ir-Based perovskite solid solution electrocatalysts Shi, Lei; Chen, Hui; Liang, Xiao Journal of Materials Chemistry A, Vol. 8, Issue 1 https://doi.org/10.1039/c9ta10059h	journal	January 2020
W supported on g-CN manifests high activity and selectivity for N ₂ electroreduction to NH ₃ Wang, Shuhua; Wei, Wei; Lv, Xingshuai Journal of Materials Chemistry A, Vol. 8, Issue 3 https://doi.org/10.1039/c9ta10935h	journal	January 2020
Complete cleavage of the N≡N triple bond by Ta ₂ N ⁺ via degenerate ligand exchange at ambient temperature: A perfect catalytic cycle Geng, Caiyun; Li, Jilai; Weiske, Thomas Proceedings of the National Academy of Sciences, Vol. 116, Issue 43 https://doi.org/10.1073/pnas.1913664116	journal	October 2019
Specific energy cost for nitrogen fixation as NO _x using DC glow discharge in air Pei, Xuekai; Gidon, Dogan; Graves, David B. Journal of Physics D: Applied Physics, Vol. 53, Issue 4 https://doi.org/10.1088/1361-6463/ab5095	journal	November 2019
Electrochemical synthesis of nitric acid from air and ammonia through waste utilization Wang, Yuting; Yu, Yifu; Jia, Ranran National Science Review, Vol. 6, Issue 4 https://doi.org/10.1093/nsr/nwz019	journal	February 2019
Dissociating stable nitrogen molecules under mild conditions by cyclic strain engineering Han, Gao-Feng; Shi, Xiang-Mei; Kim, Seok-Jin Science Advances, Vol. 5, Issue 11 https://doi.org/10.1126/sciadv.aax8275	journal	November 2019
Visible-Light Bismuth Iron Molybdate Photocatalyst for Artificial Nitrogen Fixation Liu, Botong; Yasin, Alhassan S.; Musho, Terrence Journal of The Electrochemical Society, Vol. 166, Issue 5 https://doi.org/10.1149/2.0151905jes	journal	January 2019

Similar Records

Rapid, Reversible Heterolytic Cleavage of Bound H₂

Journal Article · Fri Jul 26 00:00:00 EDT 2013 · Journal of the American Chemical Society · OSTI ID:1094910

Plasma: at the frontier of scientific discovery

Technical Report · Wed Apr 12 00:00:00 EDT 2017 · OSTI ID:1615243

Cesium Induced Changes in the Acid-Base Properties of Metal Oxides and the Consequences for Methanol Thiolation

Journal Article · Fri Oct 04 00:00:00 EDT 2019 · ACS Catalysis · OSTI ID:1577091

Beyond fossil fuel–driven nitrogen transformations

Citation Formats

References (72)

Cited By (80)

Similar Records

Related Subjects