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Oligomerization of ethanol-derived propene and isobutene mixtures to transportation fuels: catalyst and process considerations

Journal Article · · Catalysis Science and Technology
DOI:https://doi.org/10.1039/C8CY02297F· OSTI ID:1507371

An important activity/selectivity trade-off occurs at increased olefin oligomerization temperatures. Jet-range product decreases and paraffin formation increases at high oligomerization temperatures.

Research Organization:
Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
DOE Contract Number:
AC05-76RL01830
OSTI ID:
1507371
Report Number(s):
PNNL-SA-135575
Journal Information:
Catalysis Science and Technology, Journal Name: Catalysis Science and Technology Journal Issue: 5 Vol. 9; ISSN CSTAGD; ISSN 2044-4753
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

References (38)

Oligomerization of Biomass-Derived Light Olefins to Liquid Fuel: Effect of Alkali Treatment on the HZSM-5 Catalyst journal October 2017
Oligomerization of isobutene over dealuminated Y zeolite catalysts journal March 2008
Bio-jet fuel conversion technologies journal January 2016
Polystyrene sulphonic acid resins with enhanced acid strength via macromolecular self-assembly within confined nanospace journal January 2014
Trimerization of isobutene over a zeolite beta catalyst journal January 2007
Tailored Catalytic Propene Trimerization over Acidic Zeolites with Tubular Pores journal September 2005
Production of liquid hydrocarbon transportation fuels by oligomerization of biomass-derived C9 alkenes journal January 2010
A study of ZnxZryOz mixed oxides for direct conversion of ethanol to isobutene journal October 2013
Comparative techno‐economic analysis and process design for indirect liquefaction pathways to distillate‐range fuels via biomass‐derived oxygenated intermediates upgrading journal September 2016
Oligomerization of isobutene over solid acid catalysts journal February 2005
Effect of the Acidity of HZSM-5 Zeolite and the Binder in the DME Transformation to Olefins journal February 2016
Conversion of syngas-derived C2+ mixed oxygenates to C3–C5 olefins over ZnxZryOz mixed oxide catalysts journal January 2016
1-Butene oligomerization over ZSM-5 zeolite: Part 1 – Effect of reaction conditions journal September 2013
Chemistry of olefin oligomerization over ZSM-5 catalyst journal April 1988
Tailored Alkene Oligomerization with H-ZSM-57 Zeolite journal December 2000
Recent Advances in Catalytic Conversion of Ethanol to Chemicals journal March 2014
Conversion of Isobutylene to Octane-Booster Compounds after Methyl tert -Butyl Ether Phaseout: The Role of Heterogeneous Catalysis journal October 2016
Catalysis on solid acids: Mechanism and catalyst descriptors in oligomerization reactions of light alkenes journal December 2016
Reaction of small olefins on zeolite H-ZSM-5. A thermogravimetric study at low and intermediate temperatures journal March 1983
Ethanol transformation into hydrocarbons on ZSM-5 zeolites: Influence of Si/Al ratio on catalytic performances and deactivation rate. Study of the radical species role journal November 2012
Direct Conversion of Bio-ethanol to Isobutene on Nanosized Zn x Zr y O z Mixed Oxides with Balanced Acid–Base Sites journal July 2011
Study of the oligomerization of 1-octene catalyzed by macroreticular ion-exchange resins journal October 2012
Oligomerization of 1-Hexene and 1-Octene over Solid Acid Catalysts journal May 2005
Effects of Void Environment and Acid Strength on Alkene Oligomerization Selectivity journal September 2016
Synthesis of Transportation Fuels from Biomass: Chemistry, Catalysts, and Engineering journal September 2006
Low-temperature oligomerization of 1-butene with H-ferrierite journal March 2015
The conversion of ethene and propene to higher hydrocarbons over ZSM-5 journal May 1987
Oligomerization of Light Olefins to Gasoline: An Advanced NMR Characterization of Liquid Products journal August 2016
Assessment of mass transfer limitations in oligomerization of butene at high pressure on H-beta journal September 2015
Properties of Synthetic Fuels from H-ZSM-5 Oligomerization of Fischer–Tropsch Type Feed Materials journal November 2007
Integrated process for the catalytic conversion of biomass-derived syngas into transportation fuels journal January 2016
Effects of Brønsted-acid site proximity on the oligomerization of propene in H-MFI journal April 2012
Key Roles of Lewis Acid–Base Pairs on Zn x Zr y O z in Direct Ethanol/Acetone to Isobutene Conversion journal December 2015
Integrated Catalytic Conversion of γ-Valerolactone to Liquid Alkenes for Transportation Fuels journal February 2010
An integrated process for production of jet-fuel range olefins from ethylene using Ni-AlSBA-15 and Amberlyst-35 catalysts journal January 2017
Catalytic Consequences of Spatial Constraints and Acid Site Location for Monomolecular Alkane Activation on Zeolites journal February 2009
Zeolite catalysts in upgrading of bioethanol to fuels range hydrocarbons: A review journal November 2015
β-Scission of Olefins on Acidic Zeolites: A Periodic PBE-D Study in H-ZSM-5 journal October 2013

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