The h–SbxWO3+2x Oxygen Excess Antimony Tungsten Bronze

von Rohr, Fabian O.; Ryser, Alice; Ji, Huiwen; Stolze, Karoline; Tao, Jing; Frick, Jessica J.; Patzke, Greta R.; Cava, Robert J.

doi:10.1002/chem.201805251

Title: The h–Sb_xWO_3+2x Oxygen Excess Antimony Tungsten Bronze

Journal Article · Wed Jan 09 00:00:00 EST 2019 · Chemistry - A European Journal

DOI:https://doi.org/10.1002/chem.201805251· OSTI ID:1507113

^[1]; Ryser, Alice ^[2]; Ji, Huiwen ^[2]; Stolze, Karoline ^[2];

^[3]; Frick, Jessica J. ^[2]; Patzke, Greta R. ^[1]; Cava, Robert J. ^[2]

Univ. of Zurich, Zurich (Switzerland)
Princeton Univ., Princeton, NJ (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)

Here, we describe the previously unreported oxygen excess hexagonal antimony tungsten bronze with composition Sb_0.5W₃O₁₀, in the following denoted as h–Sb_xWO_3+2x with x = 0.167, to demonstrate its analogy to classical A_xWO₃ tungsten bronzes. This compound forms in a relatively narrow temperature range between 580 °C < T < 620 °C. It was obtained as a dark–blue polycrystalline powder, and as thin, needle–shaped, blue single crystals. h–Sb_xWO_3+2x crystallizes in the hexagonal space group P6/mmm with the cell parameters a=7.4369(4) Å and c=3.7800(2) Å. The antimony and excess oxygen occupy the hexagonal channels within the network of corner–sharing WO₆ octahedra. h–Sb_xWO_3+2x has a resistivity of ρ_{300 K}≈1.28 mΩ cm at room temperature, with little if any temperature–dependence on cooling. DFT calculations on a simplified model for this compound find a metallic–like electronic structure with the Fermi level falling within rather flat bands, especially around the Γ point.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States); Princeton Univ., NJ (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012704; FG02-98ER45706

OSTI ID:: 1507113

Alternate ID(s):: OSTI ID: 1490115; OSTI ID: 1595066

Report Number(s):: BNL-211545-2019-JAAM

Journal Information:: Chemistry - A European Journal, Vol. 25, Issue 8; ISSN 0947-6539

Publisher:: ChemPubSoc EuropeCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 6 works

Citation information provided by
Web of Science

References (28)

Superconducting and normal state properties of Li1+x Ti2?x O4 spinel compounds. I. Preparation, crystallography, superconducting properties, electrical resistivity, dielectric behavior, and magnetic susceptibility Johnston, D. C. Journal of Low Temperature Physics, Vol. 25, Issue 1-2 https://doi.org/10.1007/BF00654827	journal	October 1976
Emergence of superconductivity in BaNi $_{2}$ (Ge $_{1 - x}$ P $_{x}$ ) $_{2}$ at a structural instability Hirai, Daigorou; von Rohr, F.; Cava, R. J. Physical Review B, Vol. 86, Issue 10 https://doi.org/10.1103/PhysRevB.86.100505	journal	September 2012
Tungsten Oxides for Photocatalysis, Electrochemistry, and Phototherapy Huang, Zhen-Feng; Song, Jiajia; Pan, Lun Advanced Materials, Vol. 27, Issue 36 https://doi.org/10.1002/adma.201501217	journal	August 2015
Structure cristalline de Sb ₂ Mo ₁₀ O ₃₁ Parmentier, M.; Gleitzer, C.; Courtois, A. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 35, Issue 9 https://doi.org/10.1107/S0567740879008256	journal	September 1979
An X-Ray and Electron Diffraction Study of the Intergrowth Tungsten Bronze Sb0.16WO3 Triantafyllou, S. T.; Christidis, P. C.; Lioutas, Ch. B. Journal of Solid State Chemistry, Vol. 134, Issue 2 https://doi.org/10.1006/jssc.1997.7577	journal	December 1997
Exit wave reconstruction from focal series of HRTEM images, single crystal XRD and total energy studies on Sb _x WO _{3+ y} ( x ∼ 0.11) Klingstedt, Miia; Sundberg, Margareta; Eriksson, Lars Zeitschrift für Kristallographie, Vol. 227, Issue 6 https://doi.org/10.1524/zkri.2012.1517	journal	June 2012
Systematic evolution of temperature-dependent resistivity in ${La}_{2 - x}$ ${Sr}_{x}$ ${CuO}_{4}$ Takagi, H.; Batlogg, B.; Kao, H. L. Physical Review Letters, Vol. 69, Issue 20 https://doi.org/10.1103/PhysRevLett.69.2975	journal	November 1992
Superconducting phase diagram of In _x WO ₃ synthesized by indium deintercalation Bocarsly, Joshua D.; Hirai, Daigorou; Ali, M. N. EPL (Europhysics Letters), Vol. 103, Issue 1 https://doi.org/10.1209/0295-5075/103/17001	journal	July 2013
Monophosphate Tungsten Bronzes. A New Family of Low-Dimensional, Charge-Density-Wave Oxides Greenblatt, Martha Accounts of Chemical Research, Vol. 29, Issue 5 https://doi.org/10.1021/ar950157	journal	January 1996
Electrochromic tungsten oxide films: Review of progress 1993–1998 Granqvist, C. G. Solar Energy Materials and Solar Cells, Vol. 60, Issue 3 https://doi.org/10.1016/S0927-0248(99)00088-4	journal	January 2000
Opportunities and challenges in science and technology of WO3 for electrochromic and related applications Deb, Satyen K. Solar Energy Materials and Solar Cells, Vol. 92, Issue 2 https://doi.org/10.1016/j.solmat.2007.01.026	journal	February 2008
An alternative way of linearizing the augmented plane-wave method Sjöstedt, E.; Nordström, L.; Singh, D. J. Solid State Communications, Vol. 114, Issue 1 https://doi.org/10.1016/S0038-1098(99)00577-3	journal	March 2000
Tungsten-based oxide semiconductors for solar hydrogen generation Janáky, C.; Rajeshwar, K.; de Tacconi, N. R. Catalysis Today, Vol. 199 https://doi.org/10.1016/j.cattod.2012.07.020	journal	January 2013
Investigation of superlattices in K _x WO ₃ in relation to electric transport properties Krause, H. B.; Moulton, W. G.; Morris, R. C. Acta Crystallographica Section B Structural Science, Vol. 41, Issue 1 https://doi.org/10.1107/S0108768185001513	journal	February 1985
High-Pressure Synthesis of Fully Occupied Tetragonal and Cubic Tungsten Bronze Oxides Ikeuchi, Yuya; Takatsu, Hiroshi; Tassel, Cédric Angewandte Chemie, Vol. 129, Issue 21 https://doi.org/10.1002/ange.201701732	journal	April 2017
Le systeme SbWO3 et les bronzes de tungstene — Antimoine Parmentier, M.; Gleitzer, C.; Courtois, A. Materials Research Bulletin, Vol. 10, Issue 5 https://doi.org/10.1016/0025-5408(75)90003-3	journal	May 1975
Spontaneous Formation of Zigzag Chains at the Metal-Insulator Transition in the $β$ -Pyrochlore ${CsW}_{2} O_{6}$ Hirai, Daigorou; Bremholm, Martin; Allred, Jared M. Physical Review Letters, Vol. 110, Issue 16 https://doi.org/10.1103/PhysRevLett.110.166402	journal	April 2013
High-Pressure Synthesis of Fully Occupied Tetragonal and Cubic Tungsten Bronze Oxides Ikeuchi, Yuya; Takatsu, Hiroshi; Tassel, Cédric Angewandte Chemie International Edition, Vol. 56, Issue 21 https://doi.org/10.1002/anie.201701732	journal	April 2017
Superconducting properties of the $K_{x} {WO}_{3}$ tetragonal tungsten bronze and the superconducting phase diagram of the tungsten bronze family Haldolaarachchige, Neel; Gibson, Quinn; Krizan, Jason Physical Review B, Vol. 89, Issue 10 https://doi.org/10.1103/PhysRevB.89.104520	journal	March 2014
Enhancement of the superconducting transition temperature near a phase instability in NaxWO3 Shanks, Howard R. Solid State Communications, Vol. 15, Issue 4 https://doi.org/10.1016/0038-1098(74)90254-3	journal	August 1974
Concentration dependence of superconductivity and the order-disorder transition in the hexagonal rubidium tungsten bronze ${Rb}_{x} {WO}_{3} :$ Interfacial and bulk properties Brusetti, R.; Haen, P.; Marcus, J. Physical Review B, Vol. 65, Issue 14 https://doi.org/10.1103/PhysRevB.65.144528	journal	April 2002
Efficient linearization of the augmented plane-wave method Madsen, Georg K. H.; Blaha, Peter; Schwarz, Karlheinz Physical Review B, Vol. 64, Issue 19 https://doi.org/10.1103/PhysRevB.64.195134	journal	October 2001
Evidence of structural phase transitions in superconducting ${Rb}_{x} W O_{3}$ Sato, M.; Grier, B. H.; Shirane, G. Physical Review B, Vol. 25, Issue 1 https://doi.org/10.1103/PhysRevB.25.501	journal	January 1982
Superconductivity in rubidium-substituted Ba $_{1 - x}$ Rb $_{x}$ Ti $_{2}$ Sb $_{2}$ O von Rohr, Fabian; Nesper, Reinhard; Schilling, Andreas Physical Review B, Vol. 89, Issue 9 https://doi.org/10.1103/PhysRevB.89.094505	journal	March 2014
High-Pressure Synthesis and Characterization of β-GeSe—A Six-Membered-Ring Semiconductor in an Uncommon Boat Conformation von Rohr, Fabian O.; Ji, Huiwen; Cevallos, F. Alexandre Journal of the American Chemical Society, Vol. 139, Issue 7 https://doi.org/10.1021/jacs.6b12828	journal	February 2017
Superconductivity in rubidium-substituted Ba${}_{1-{}x}$Rb${}_{x}$Ti${}_{2}$Sb${}_{2}$O Von Rohr, Fabian; Nesper, Reinhard; Schilling, Andreas American Physical Society https://doi.org/10.5167/uzh-106879	text	January 2014
Emergence of superconductivity in BaNi_{2}(Ge_{1−x}P_{x})_{2} at a structural instability Hirai, Daigorou; Von Rohr, F.; Cava, R. J. American Physical Society https://doi.org/10.5167/uzh-73424	text	January 2012
Concentration Dependence of Superconductivity and Order-Disorder Transition in the Hexagonal Rubidium Tungsten Bronze RbxWO3. Interfacial and bulk properties Brusetti, R.; Haen, P.; Marcus, J. arXiv https://doi.org/10.48550/arxiv.cond-mat/0203120	text	January 2002

Similar Records

Conduction properties of the hexagonal tungsten bronze, Rb/sub x/WO/sub 3/

Journal Article · Sat Sep 01 00:00:00 EDT 1979 · Phys. Rev., B: Condens. Matter; (United States) · OSTI ID:1507113

Stanley, R K; Morris, R C; Moulton, W G

Na/sub x/P/sub 4/W/sub 14/O/sub 50/: the sodium m = 7 member of the monophosphate tungsten bronze series A/sub x/(PO/sub 2/)/sub 4/(WO/sub 3/)/sub 2m/

Journal Article · Thu Jan 01 00:00:00 EST 1987 · J. Solid State Chem.; (United States) · OSTI ID:1507113

Lamire, M; Goreaud, L M; Raveau, B

Crystal structure and superconductivity of rubidium tungsten bronzes Rb{sub x}WO{sub 3} prepared by a hybrid microwave method

Journal Article · Tue Apr 01 00:00:00 EDT 2008 · Materials Research Bulletin · OSTI ID:1507113

Juan, Guo; Cheng, Dong; Lihong, Yang; +1 more

Related Subjects

75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
antimony
bronze
hexagonal bipyramids
metallic oxide
tungsten

Title: The h–SbxWO3+2x Oxygen Excess Antimony Tungsten Bronze

Citation Formats

References (28)

Linked Research (1)

Similar Records

Related Subjects

Title: The h–Sb_xWO_3+2x Oxygen Excess Antimony Tungsten Bronze