Effect of A–site substitutions on energy storage properties of BaTiO3–BiScO3 weakly coupled relaxor ferroelectrics

Nayak, Sanjib; Venkateshwarlu, Sarangi; Budisuharto, Anthony Setiadi; Jørgensen, Mads Ry Vogel; Borkiewicz, Olaf; Beyer, Kevin A.; Pramanick, Abhijit

doi:10.1111/jace.16449

Title: Effect of A–site substitutions on energy storage properties of BaTiO₃–BiScO₃ weakly coupled relaxor ferroelectrics

Journal Article · Fri Mar 22 00:00:00 EDT 2019 · Journal of the American Ceramic Society

DOI:https://doi.org/10.1111/jace.16449· OSTI ID:1561219

Nayak, Sanjib ^[1]; Venkateshwarlu, Sarangi ^[1]; Budisuharto, Anthony Setiadi ^[1];

^[2]; Borkiewicz, Olaf ^[3]; Beyer, Kevin A. ^[3];

^[1]

City Univ. of Hong Kong (Hong Kong)
Aarhus Univ., Aarhus C (Denmark); Lund Univ., Lund (Sweden)
Argonne National Lab. (ANL), Argonne, IL (United States)

Abstract Weakly coupled relaxors based on compositions (1‐ x ) BaTiO ₃ ‐ x Bi Me O ₃ , where Me is a metal ion, have attracted attention as potential candidates for high‐temperature high‐energy density capacitors. However, the necessary Bi content is typically high with x = 0.3‐0.4. In order to reduce problems associated with compatibility for base metal electrodes and due to additional problems due to Bi volatility, it is desirable to lower the Bi content in the overall composition for these materials. Here, we have explored a possible way to reduce BiMeO ₃ content through additional A‐site substitutions viz. Ca and Sn. The relaxor nature and energy storage properties of Sn‐modified (Ba,Ca)(Ti)O ₃ ‐BiScO ₃ ceramics were determined from their dielectric and ferroelectric behaviors. The material showed attractive properties in terms of a frequency‐independent (200 Hz‐1 MHz) dielectric response from room temperature to 200°C, extremely low loss and high‐energy storage efficiency. The structural phenomena underlying the functional properties of Sn‐modified (Ba,Ca)TiO ₃ ‐BiScO ₃ are characterized from temperature‐dependent X‐ray diffraction and pair distribution function analysis. In broader terms, the study illustrates the potential for tailoring relaxor behavior in Pb‐free ferroelectrics by combining phenomena, such as quantum fluctuations and lone pair stereochemical effect associated with different solid‐solution substitutions.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: City University of Hong Kong; Aarhus University; Danish Ministry of Higher Education and Science - Danish Agency for Science, Technology and Innovation; Danish National Research Foundation; USDOE

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1561219

Alternate ID(s):: OSTI ID: 1506133

Journal Information:: Journal of the American Ceramic Society, Vol. 102, Issue 10; ISSN 0002-7820

Publisher:: American Ceramic SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 27 works

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Title: Effect of A–site substitutions on energy storage properties of BaTiO3–BiScO3 weakly coupled relaxor ferroelectrics

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Title: Effect of A–site substitutions on energy storage properties of BaTiO₃–BiScO₃ weakly coupled relaxor ferroelectrics