Analysis of equilibrium CO 2 solubility and thermodynamic models for aqueous 1‐(2‐hydoxyethyl)‐piperidine solution

Xiao, Min; Zheng, Wenchao; Liu, Helei; Tontiwachwuthikul, Paitoon; Liang, Zhiwu

doi:10.1002/aic.16605

Title: Analysis of equilibrium CO ₂ solubility and thermodynamic models for aqueous 1‐(2‐hydoxyethyl)‐piperidine solution

Journal Article · Tue Apr 09 00:00:00 EDT 2019 · AIChE Journal

DOI:https://doi.org/10.1002/aic.16605· OSTI ID:1505877

Xiao, Min ^[1]; Zheng, Wenchao ^[1];

^[2];

^[3];

^[3]

Joint International Center for CO₂ Capture and Storage (iCCS), Hunan Provincial Key Laboratory for Cost‐effective Utilization of Fossil Fuel Aimed at Reducing CO₂ Emissions, College of Chemistry and Chemical Engineering Hunan University Changsha People's Republic of China
Faculty of Engineering and Applied Science, Clean Energy Technologies Research Institute University of Regina Regina Saskatchewan Canada
Joint International Center for CO₂ Capture and Storage (iCCS), Hunan Provincial Key Laboratory for Cost‐effective Utilization of Fossil Fuel Aimed at Reducing CO₂ Emissions, College of Chemistry and Chemical Engineering Hunan University Changsha People's Republic of China, Faculty of Engineering and Applied Science, Clean Energy Technologies Research Institute University of Regina Regina Saskatchewan Canada

Abstract 1‐(2‐Hydoxyethyl)‐piperidine (1‐(2HE)‐PP) is a new tertiary amine with desirable properties and can be potentially used to formulate superior absorbents for CO ₂ capture. The equilibrium CO ₂ solubility of 1‐(2HE)‐PP solution is measured over temperatures from 298 to 333 K, CO ₂ partial pressures from 8.1 to 101.3 kPa and initial amine concentrations from 1 to 5 M. Two thermodynamic models, namely semiempirical model and activity coefficient model are developed for the system. The activity coefficient model shows better estimation solubility with an absolute average relative deviation (AARD) of 7.6%. In the comparison between the two models, a comprehensive analysis is presented. Some suggestions are provided for the similar model development. In addition, the speciation plot of CO ₂ loaded 1‐(2HE)‐PP solution is predicted based on the activity coefficient model. The predictive pH values agree well with experimental data with AARD of 1.0%. Finally, the potential of 1‐(2‐HE)PP to be an alternative amine in CO ₂ capture is evaluated.

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Sponsoring Organization:: USDOE

OSTI ID:: 1505877

Journal Information:: AIChE Journal, Journal Name: AIChE Journal Vol. 65 Journal Issue: 6; ISSN 0001-1541

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 11 works

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