Thermodynamic coarsening arrested by viscous fingering in partially miscible binary mixtures

Fu, Xiaojing; Cueto-Felgueroso, Luis; Juanes, Ruben

doi:10.1103/physreve.94.033111

Thermodynamic coarsening arrested by viscous fingering in partially miscible binary mixtures

Journal Article · Tue Sep 20 00:00:00 EDT 2016 · Physical Review E

DOI:https://doi.org/10.1103/physreve.94.033111· OSTI ID:1505596

Fu, Xiaojing ^[1]; Cueto-Felgueroso, Luis ^[2]; Juanes, Ruben ^[3]

Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); none
Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Technical Univ. of Madrid, Madrid (Spain)
Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)

We view the evolution of binary mixtures far from equilibrium, and demonstrate that the interplay between phase separation and hydrodynamic instability can arrest the Ostwald ripening process characteristic of nonflowing mixtures. We describe a model binary system in a Hele-Shaw cell using a phase-field approach with explicit dependence of both phase fraction and mass concentration. When the viscosity contrast between phases is large (as is the case for gas and liquid phases), an imposed background flow leads to viscous fingering, phase branching, and pinch off. This dynamic flow disorder limits phase growth and arrests thermodynamic coarsening. Because of this, the system reaches a regime of statistical steady state in which the binary mixture is permanently driven away from equilibrium.

View Accepted Manuscript (DOE)

Research Organization:: Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Univ. of Texas, Austin, TX (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Advanced Scientific Computing Research (ASCR) (SC-21); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: FE0013999; SC0009286

OSTI ID:: 1505596

Alternate ID(s):: OSTI ID: 1325613

Journal Information:: Physical Review E, Journal Name: Physical Review E Journal Issue: 3 Vol. 94; ISSN PLEEE8; ISSN 2470-0045

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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