Measurement–model comparison of stabilized Criegee intermediate&nbsp;and highly oxygenated molecule production&nbsp;in&nbsp;the&nbsp;CLOUD&nbsp;chamber

Sarnela, Nina; Jokinen, Tuija; Duplissy, Jonathan; Yan, Chao; Nieminen, Tuomo; Ehn, Mikael; Schobesberger, Siegfried; Heinritzi, Martin; Ehrhart, Sebastian; Lehtipalo, Katrianne; Tröstl, Jasmin; Simon, Mario; Kürten, Andreas; Leiminger, Markus; Lawler, Michael J.; Rissanen, Matti P.; Bianchi, Federico; Praplan, Arnaud P.; Hakala, Jani; Amorim, Antonio; Gonin, Marc; Hansel, Armin; Kirkby, Jasper; Dommen, Josef; Curtius, Joachim; Smith, James N.; Petäjä, Tuukka; Worsnop, Douglas R.; Kulmala, Markku; Donahue, Neil M.; Sipilä, Mikko

doi:10.5194/acp-18-2363-2018

Measurement–model comparison of stabilized Criegee intermediate and highly oxygenated molecule production in the CLOUD chamber

Journal Article · Mon Feb 19 00:00:00 EST 2018 · Atmospheric Chemistry and Physics (Online)

DOI:https://doi.org/10.5194/acp-18-2363-2018· OSTI ID:1505587

Sarnela, Nina ^[1]; ^[2]; Duplissy, Jonathan ^[2]; ^[2]; ^[3]; ^[2]; ^[4]; Heinritzi, Martin ^[5]; Ehrhart, Sebastian ^[6]; ^[7]; Tröstl, Jasmin ^[8]; Simon, Mario ^[5]; Kürten, Andreas ^[5]; Leiminger, Markus ^[9]; Lawler, Michael J. ^[10]; ^[2]; ^[2]; Praplan, Arnaud P. ^[11]; Hakala, Jani ^[2]; Amorim, Antonio ^[12] more »

Univ. of Helsinki, Helsinki (Finland); University of Helsinki, Finland
Univ. of Helsinki, Helsinki (Finland)
Univ. of Eastern Finland, Kuopio (Finland)
Univ. of Helsinki, Helsinki (Finland); Univ. of Eastern Finland, Kuopio (Finland); Univ. of Washington, Seattle, WA (United States)
Goethe Univ. Frankfurt, Frankfurt am Main (Germany)
Goethe Univ. Frankfurt, Frankfurt am Main (Germany); Max-Planck Institute of Chemistry, Mainz (Germany)
Univ. of Helsinki, Helsinki (Finland); Paul Scherrer Inst. (PSI), Villigen (Switzerland)
Paul Scherrer Inst. (PSI), Villigen (Switzerland)
Univ. of Innsbruck, Innsbruck (Austria)
Univ. of California, Irvine, CA (United States)
Finnish Meteorological Institute, Helsinki (Finland)
CENTRA, Lisbon (Portugal)
Tofwerk AG, Thun (Switzerland)
Goethe Univ. Frankfurt, Frankfurt am Main (Germany); European Organization for Nuclear Research (CERN), Geneva (Switzerland)
Univ. of Helsinki, Helsinki (Finland); Aerodyne Research Inc., Billerica, MA (United States)
Univ. of Helsinki, Helsinki (Finland); Carnegie Mellon Univ., Pittsburgh, PA (United States)

Abstract. Atmospheric oxidation is an important phenomenon which produces large quantities of low-volatility compounds such as sulfuric acid and oxidized organic compounds. Such species may be involved in the nucleation of particles and enhance their subsequent growth to reach the size of cloud condensation nuclei (CCN). In this study, we investigate α-pinene, the most abundant monoterpene globally, and its oxidation products formed through ozonolysis in the Cosmic Leaving Outdoor Droplets (CLOUD) chamber at CERN(the European Organization for Nuclear Research). By scavenging hydroxyl radicals (OH) with hydrogen (H₂), we were able to investigate the formation of highly oxygenated molecules (HOMs) purely driven by ozonolysis and study the oxidation of sulfur dioxide (SO₂) driven by stabilized Criegee intermediates (sCIs). We measured the concentrations of HOM and sulfuric acid with a chemical ionization atmospheric-pressure interface time-of-flight (CI-APi-TOF) mass spectrometer and compared the measured concentrations with simulated concentrations calculated with a kinetic model.We found molar yields in the range of 3.5–6.5% for HOM formation and 22–32% for the formation of stabilized Criegee intermediates by fitting our model to the measured sulfuric acid concentrations. The simulated time evolution of the ozonolysis products was in good agreement with measured concentrations except that in some of the experiments sulfuric acid formation was faster than simulated. In those experiments the simulated and measured concentrations met when the concentration reached a plateau but the plateau was reached 20–50min later in the simulations. The results shown here are consistent with the recently published yields for HOM formation from different laboratory experiments. Together with the sCI yields, these results help us to understand atmospheric oxidation processes better and make there action parameters more comprehensive for broader use.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of California, Irvine, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: SC0014469

OSTI ID:: 1505587

Journal Information:: Atmospheric Chemistry and Physics (Online), Journal Name: Atmospheric Chemistry and Physics (Online) Journal Issue: 4 Vol. 18; ISSN 1680-7324

Publisher:: European Geosciences UnionCopyright Statement

Country of Publication:: United States

Language:: English

References (92)

Effect of dimethylamine on the gas phase sulfuric acid concentration measured by Chemical Ionization Mass Spectrometry Rondo, L.; Ehrhart, S.; Kürten, A. Journal of Geophysical Research: Atmospheres, Vol. 121, Issue 6 https://doi.org/10.1002/2015jd023868	journal	March 2016
Sulphuric acid and aerosol particle production in the vicinity of an oil refinery Sarnela, Nina; Jokinen, Tuija; Nieminen, Tuomo Atmospheric Environment, Vol. 119 https://doi.org/10.1016/j.atmosenv.2015.08.033	journal	October 2015
Comment on “Electrostatic Sampler for Semivolatile Aerosols: Chemical Artifacts” and “Filter and Electrostatic Samplers for Semivolatile Aerosols: Physical Artifacts” Pankow, James F. Environmental Science & Technology, Vol. 37, Issue 9 https://doi.org/10.1021/es021046q	journal	April 2003
A new atmospherically relevant oxidant of sulphur dioxide Mauldin III, R. L.; Berndt, T.; Sipilä, M. Nature, Vol. 488, Issue 7410 https://doi.org/10.1038/nature11278	journal	August 2012
A large source of low-volatility secondary organic aerosol Ehn, Mikael; Thornton, Joel A.; Kleist, Einhard Nature, Vol. 506, Issue 7489 https://doi.org/10.1038/nature13032	journal	February 2014
The role of low-volatility organic compounds in initial particle growth in the atmosphere Tröstl, Jasmin; Chuang, Wayne K.; Gordon, Hamish Nature, Vol. 533, Issue 7604 https://doi.org/10.1038/nature18271	journal	May 2016
Rapid Formation of Sulfuric Acid Particles at Near-Atmospheric Conditions Berndt, T. Science, Vol. 307, Issue 5710 https://doi.org/10.1126/science.1104054	journal	February 2005
Oxidation Products of Biogenic Emissions Contribute to Nucleation of Atmospheric Particles Riccobono, F.; Schobesberger, S.; Scott, C. E. Science, Vol. 344, Issue 6185 https://doi.org/10.1126/science.1243527	journal	May 2014
New particle formation in the free troposphere: A question of chemistry and timing Bianchi, F.; Trostl, J.; Junninen, H. Science, Vol. 352, Issue 6289 https://doi.org/10.1126/science.aad5456	journal	May 2016
Reactivity of stabilized Criegee intermediates (sCIs) from isoprene and monoterpene ozonolysis toward SO2 and organic acids Sipilä, M.; Jokinen, T.; Berndt, T. München : European Geopyhsical Union https://doi.org/10.34657/1227	text	January 2014
Enhancement of atmospheric H2SO4/H2O nucleation: Organic oxidation products versus amines Berndt, T.; Sipilä, M.; Stratmann, F. München : European Geopyhsical Union https://doi.org/10.34657/924	text	January 2014
Numerical simulations of mixing conditions and aerosol dynamics in the CERN CLOUD chamber Voigtländer, J.; Duplissy, J.; Rondo, L. Atmospheric Chemistry and Physics, Vol. 12, Issue 4 https://doi.org/10.5194/acp-12-2205-2012	journal	January 2012
On the formation of sulphuric acid – amine clusters in varying atmospheric conditions and its influence on atmospheric new particle formation Paasonen, P.; Olenius, T.; Kupiainen, O. Atmospheric Chemistry and Physics, Vol. 12, Issue 19 https://doi.org/10.5194/acp-12-9113-2012	journal	January 2012
Amines are likely to enhance neutral and ion-induced sulfuric acid-water nucleation in the atmosphere more effectively than ammonia Kurtén, T.; Loukonen, V.; Vehkamäki, H. Atmospheric Chemistry and Physics, Vol. 8, Issue 14 https://doi.org/10.5194/acp-8-4095-2008	journal	January 2008
Sulfuric acid and OH concentrations in a boreal forest site Petäjä, T.; Mauldin, III, R. L.; Kosciuch, E. Atmospheric Chemistry and Physics, Vol. 9, Issue 19 https://doi.org/10.5194/acp-9-7435-2009	journal	January 2009
Effect of ions on the measurement of sulfuric acid in the CLOUD experiment at CERN Rondo, L.; Kürten, A.; Ehrhart, S. Atmospheric Measurement Techniques, Vol. 7, Issue 11 https://doi.org/10.5194/amt-7-3849-2014	journal	January 2014
Effect of ions on sulfuric acid-water binary particle formation: 2. Experimental data and comparison with QC-normalized classical nucleation theory: BINARY PARTICLE FORMATION EXPERIMENTS Duplissy, J.; Merikanto, J.; Franchin, A. Journal of Geophysical Research: Atmospheres, Vol. 121, Issue 4 https://doi.org/10.1002/2015JD023539	journal	February 2016
Effect of dimethylamine on the gas phase sulfuric acid concentration measured by Chemical Ionization Mass Spectrometry Rondo, L.; Ehrhart, S.; Kürten, A. Journal of Geophysical Research: Atmospheres, Vol. 121, Issue 6 https://doi.org/10.1002/2015JD023868	journal	March 2016
Mechanism of Ozonolysis Criegee, Rudolf Angewandte Chemie International Edition in English, Vol. 14, Issue 11 https://doi.org/10.1002/anie.197507451	journal	November 1975
Rapid Autoxidation Forms Highly Oxidized RO ₂ Radicals in the Atmosphere Jokinen, Tuija; Sipilä, Mikko; Richters, Stefanie Angewandte Chemie International Edition, Vol. 53, Issue 52 https://doi.org/10.1002/anie.201408566	journal	October 2014
Kinetics and energetics of the criegee intermediate in the gas phase. I. The criegee intermediate in ozone-alkene reactions Herron, John T.; Martinez, Richard I.; Huie, Robert E. International Journal of Chemical Kinetics, Vol. 14, Issue 3 https://doi.org/10.1002/kin.550140302	journal	March 1982
On-line monitoring of volatile organic compounds at pptv levels by means of proton-transfer-reaction mass spectrometry (PTR-MS) medical applications, food control and environmental research Lindinger, W.; Hansel, A.; Jordan, A. International Journal of Mass Spectrometry and Ion Processes, Vol. 173, Issue 3 https://doi.org/10.1016/S0168-1176(97)00281-4	journal	February 1998
H2SO4 formation from the gas-phase reaction of stabilized Criegee Intermediates with SO2: Influence of water vapour content and temperature Berndt, Torsten; Jokinen, Tuija; Sipilä, Mikko Atmospheric Environment, Vol. 89 https://doi.org/10.1016/j.atmosenv.2014.02.062	journal	June 2014
Role of stabilized Criegee Intermediate in secondary organic aerosol formation from the ozonolysis of α-cedrene Yao, Lei; Ma, Yan; Wang, Lin Atmospheric Environment, Vol. 94 https://doi.org/10.1016/j.atmosenv.2014.05.063	journal	September 2014
Formation and growth rates of ultrafine atmospheric particles: a review of observations Kulmala, M.; Vehkamäki, H.; Petäjä, T. Journal of Aerosol Science, Vol. 35, Issue 2 https://doi.org/10.1016/j.jaerosci.2003.10.003	journal	March 2004
Modeling the Charging of Highly Oxidized Cyclohexene Ozonolysis Products Using Nitrate-Based Chemical Ionization Hyttinen, Noora; Kupiainen-Määttä, Oona; Rissanen, Matti P. The Journal of Physical Chemistry A, Vol. 119, Issue 24 https://doi.org/10.1021/acs.jpca.5b01818	journal	May 2015
Mechanism of ozonolysis Murray, Robert W. Accounts of Chemical Research, Vol. 1, Issue 10 https://doi.org/10.1021/ar50010a004	journal	October 1968
Ion-polar molecule collisions. Effect of molecular size on ion-polar molecule rate constants Su, Timothy.; Bowers, Michael T. Journal of the American Chemical Society, Vol. 95, Issue 23 https://doi.org/10.1021/ja00804a011	journal	November 1973
Cycloalkene Ozonolysis: Collisionally Mediated Mechanistic Branching Chuong, Bao; Zhang, Jieyuan; Donahue, Neil M. Journal of the American Chemical Society, Vol. 126, Issue 39 https://doi.org/10.1021/ja0485412	journal	October 2004
The Formation of Highly Oxidized Multifunctional Products in the Ozonolysis of Cyclohexene Rissanen, Matti P.; Kurtén, Theo; Sipilä, Mikko Journal of the American Chemical Society, Vol. 136, Issue 44 https://doi.org/10.1021/ja507146s	journal	October 2014
Pressure Dependence of Stabilized Criegee Intermediate Formation from a Sequence of Alkenes Drozd, Greg T.; Donahue, Neil M. The Journal of Physical Chemistry A, Vol. 115, Issue 17 https://doi.org/10.1021/jp2001089	journal	May 2011
Calibration of a Chemical Ionization Mass Spectrometer for the Measurement of Gaseous Sulfuric Acid Kürten, Andreas; Rondo, Linda; Ehrhart, Sebastian The Journal of Physical Chemistry A, Vol. 116, Issue 24 https://doi.org/10.1021/jp212123n	journal	February 2012
Gas-Phase Ozonolysis of Selected Olefins: The Yield of Stabilized Criegee Intermediate and the Reactivity toward SO ₂ Berndt, Torsten; Jokinen, Tuija; Mauldin, Roy L. The Journal of Physical Chemistry Letters, Vol. 3, Issue 19 https://doi.org/10.1021/jz301158u	journal	September 2012
Organic aerosol formation from the oxidation of biogenic hydrocarbons Griffin, Robert J.; Cocker, David R.; Flagan, Richard C. Journal of Geophysical Research: Atmospheres, Vol. 104, Issue D3 https://doi.org/10.1029/1998JD100049	journal	February 1999
Laboratory studies of particle nucleation: Initial results for H ₂ SO ₄ , H ₂ O, and NH ₃ vapors Ball, S. M.; Hanson, D. R.; Eisele, F. L. Journal of Geophysical Research: Atmospheres, Vol. 104, Issue D19 https://doi.org/10.1029/1999JD900411	journal	October 1999
The contribution of sulfuric acid and non-volatile compounds on the growth of freshly formed atmospheric aerosols: GROWTH OF FRESHLY FORMED AEROSOLS Wehner, B.; Petäjä, T.; Boy, M. Geophysical Research Letters, Vol. 32, Issue 17 https://doi.org/10.1029/2005GL023827	journal	September 2005
Measurement of the gas phase concentration of H ₂ SO ₄ and methane sulfonic acid and estimates of H ₂ SO ₄ production and loss in the atmosphere Eisele, F. L.; Tanner, D. J. Journal of Geophysical Research: Atmospheres, Vol. 98, Issue D5 https://doi.org/10.1029/93JD00031	journal	May 1993
A global model of natural volatile organic compound emissions Guenther, Alex; Hewitt, C. Nicholas; Erickson, David Journal of Geophysical Research, Vol. 100, Issue D5 https://doi.org/10.1029/94JD02950	journal	January 1995
Measurements of new particle formation and ultrafine particle growth rates at a clean continental site Weber, R. J.; Marti, J. J.; McMurry, P. H. Journal of Geophysical Research: Atmospheres, Vol. 102, Issue D4 https://doi.org/10.1029/96JD03656	journal	February 1997
On the formation, growth and composition of nucleation mode particles Kulmala, M.; Maso, M. Dal; MÄKelÄ, J. M. Tellus B, Vol. 53, Issue 4 https://doi.org/10.1034/j.1600-0889.2001.d01-33.x	journal	September 2001
Oxidation of Atmospheric SO2 by Products of the Ozone–Olefin Reaction Cox, R. A.; Penkett, S. A. Nature, Vol. 230, Issue 5292 https://doi.org/10.1038/230321a0	journal	April 1971
Marine aerosol formation from biogenic iodine emissions O'Dowd, Colin D.; Jimenez, Jose L.; Bahreini, Roya Nature, Vol. 417, Issue 6889 https://doi.org/10.1038/nature00775	journal	June 2002
Role of sulphuric acid, ammonia and galactic cosmic rays in atmospheric aerosol nucleation Kirkby, Jasper; Curtius, Joachim; Almeida, João Nature, Vol. 476, Issue 7361 https://doi.org/10.1038/nature10343	journal	August 2011
Molecular understanding of sulphuric acid–amine particle nucleation in the atmosphere Almeida, João; Schobesberger, Siegfried; Kürten, Andreas Nature, Vol. 502, Issue 7471 https://doi.org/10.1038/nature12663	journal	October 2013
Ion-induced nucleation of pure biogenic particles Kirkby, Jasper; Duplissy, Jonathan; Sengupta, Kamalika Nature, Vol. 533, Issue 7604 https://doi.org/10.1038/nature17953	journal	May 2016
Molecular-scale evidence of aerosol particle formation via sequential addition of HIO3 Sipilä, Mikko; Sarnela, Nina; Jokinen, Tuija Nature, Vol. 537, Issue 7621 https://doi.org/10.1038/nature19314	journal	August 2016
Competing atmospheric reactions of CH ₂ OO with SO ₂ and water vapour Berndt, Torsten; Voigtländer, Jens; Stratmann, Frank Physical Chemistry Chemical Physics, Vol. 16, Issue 36 https://doi.org/10.1039/C4CP02345E	journal	January 2014
Thermal stability of carbonyl radicals Part I. Straight-chain and branched C4 and C5 acyl radicals Jagiella, S.; Libuda, H. G.; Zabel, F. Physical Chemistry Chemical Physics, Vol. 2, Issue 6 https://doi.org/10.1039/a909557h	journal	January 2000
The gas-phase ozonolysis of unsaturated volatile organic compounds in the troposphere Johnson, David; Marston, George Chemical Society Reviews, Vol. 37, Issue 4 https://doi.org/10.1039/b704260b	journal	January 2008
Adventures in ozoneland: down the rabbit-hole Donahue, Neil M.; Drozd, Greg T.; Epstein, Scott A. Physical Chemistry Chemical Physics, Vol. 13, Issue 23 https://doi.org/10.1039/c0cp02564j	journal	January 2011
The reaction of Criegee intermediates with NO, RO2, and SO2, and their fate in the atmosphere Vereecken, L.; Harder, H.; Novelli, A. Physical Chemistry Chemical Physics, Vol. 14, Issue 42 https://doi.org/10.1039/c2cp42300f	journal	January 2012
The reactions of Criegee intermediates with alkenes, ozone, and carbonyl oxides Vereecken, L.; Harder, H.; Novelli, A. Physical Chemistry Chemical Physics, Vol. 16, Issue 9 https://doi.org/10.1039/c3cp54514h	journal	January 2014
Neutral molecular cluster formation of sulfuric acid–dimethylamine observed in real time under atmospheric conditions Kürten, Andreas; Jokinen, Tuija; Simon, Mario Proceedings of the National Academy of Sciences, Vol. 111, Issue 42 https://doi.org/10.1073/pnas.1404853111	journal	October 2014
Production of extremely low volatile organic compounds from biogenic emissions: Measured yields and atmospheric implications Jokinen, Tuija; Berndt, Torsten; Makkonen, Risto Proceedings of the National Academy of Sciences, Vol. 112, Issue 23 https://doi.org/10.1073/pnas.1423977112	journal	May 2015
Kinetics of a Criegee intermediate that would survive high humidity and may oxidize atmospheric SO ₂ Huang, Hao-Li; Chao, Wen; Lin, Jim Jr-Min Proceedings of the National Academy of Sciences, Vol. 112, Issue 35 https://doi.org/10.1073/pnas.1513149112	journal	August 2015
Measured Atmospheric new Particle Formation Rates: Implications for Nucleation Mechanisms Weber, R. J.; Marti, J. J.; McMURRY, P. H. Chemical Engineering Communications, Vol. 151, Issue 1 https://doi.org/10.1080/00986449608936541	journal	September 1996
A Medium Flow, High-Resolution Vienna DMA Running in Recirculating Mode Steiner, G.; Attoui, M.; Wimmer, D. Aerosol Science and Technology, Vol. 44, Issue 4 https://doi.org/10.1080/02786821003636763	journal	February 2010
Toward Reconciling Measurements of Atmospherically Relevant Clusters by Chemical Ionization Mass Spectrometry and Mobility Classification/Vapor Condensation Jen, Coty N.; Hanson, David R.; McMurry, Peter H. Aerosol Science and Technology, Vol. 49, Issue 1 https://doi.org/10.1080/02786826.2014.1002602	journal	December 2014
Scanning Electrical Mobility Spectrometer Wang, Shih Chen; Flagan, Richard C. Aerosol Science and Technology, Vol. 13, Issue 2 https://doi.org/10.1080/02786829008959441	journal	January 1990
Direct Kinetic Measurements of Criegee Intermediate (CH2OO) Formed by Reaction of CH2I with O2 Welz, O.; Savee, J. D.; Osborn, D. L. Science, Vol. 335, Issue 6065 https://doi.org/10.1126/science.1213229	journal	January 2012
Direct Measurements of Conformer-Dependent Reactivity of the Criegee Intermediate CH3CHOO Taatjes, C. A.; Welz, O.; Eskola, A. J. Science, Vol. 340, Issue 6129 https://doi.org/10.1126/science.1234689	journal	April 2013
O RGANIC A TMOSPHERIC P ARTICULATE M ATERIAL Seinfeld, John H.; Pankow, James F. Annual Review of Physical Chemistry, Vol. 54, Issue 1 https://doi.org/10.1146/annurev.physchem.54.011002.103756	journal	October 2003
A two-dimensional volatility basis set – Part 2: Diagnostics of organic-aerosol evolution Donahue, Neil; Kroll, J. H.; Pandis, Spyros N. Carnegie Mellon University https://doi.org/10.1184/r1/6466634	text	January 2012
A two-dimensional volatility basis set – Part 2: Diagnostics of organic-aerosol evolution Donahue, Neil; Kroll, J. H.; Pandis, Spyros N. Carnegie Mellon University https://doi.org/10.1184/r1/6466634.v1	text	January 2012
Organic condensation: a vital link connecting aerosol formation to cloud condensation nuclei (CCN) concentrations Riipinen, I.; Pierce, J. R.; Yli-Juuti, T. Carnegie Mellon University https://doi.org/10.1184/r1/6467339	text	January 2011
On the formation, growth and composition of nucleation mode particles Kulmala, M.; Maso, M. Dal; Mäkelä, J. M. Tellus B: Chemical and Physical Meteorology, Vol. 53, Issue 4 https://doi.org/10.3402/tellusb.v53i4.16622	journal	January 2001
Numerical simulations of mixing conditions and aerosol dynamics in the CERN CLOUD chamber Voigtländer, J.; Duplissy, J.; Rondo, L. München : European Geopyhsical Union https://doi.org/10.34657/1139	other	January 2012
Ion-induced nucleation of pure biogenic particles Kirkby, Jasper; Frege, Carla; Tröstl, Jasmin ETH Zurich https://doi.org/10.3929/ethz-b-000117259	text	January 2016
Elemental composition and clustering behaviour of α-pinene oxidation products for different oxidation conditions Praplan, Arnaud P.; Schobesberger, Siegfried; Bianchi, Frederico ETH Zurich https://doi.org/10.3929/ethz-b-000164345	text	January 2015
Laboratory study on new particle formation from the reaction OH + SO ₂ : influence of experimental conditions, H ₂ O vapour, NH ₃ and the amine tert-butylamine on the overall process Berndt, T.; Stratmann, F.; Sipilä, M. Atmospheric Chemistry and Physics, Vol. 10, Issue 15 https://doi.org/10.5194/acp-10-7101-2010	journal	January 2010
A statistical proxy for sulphuric acid concentration Mikkonen, S.; Romakkaniemi, S.; Smith, J. N. Atmospheric Chemistry and Physics, Vol. 11, Issue 21 https://doi.org/10.5194/acp-11-11319-2011	journal	January 2011
Organic condensation: a vital link connecting aerosol formation to cloud condensation nuclei (CCN) concentrations Riipinen, I.; Pierce, J. R.; Yli-Juuti, T. Atmospheric Chemistry and Physics, Vol. 11, Issue 8 https://doi.org/10.5194/acp-11-3865-2011	journal	January 2011
Atmospheric sulphuric acid and neutral cluster measurements using CI-APi-TOF Jokinen, T.; Sipilä, M.; Junninen, H. Atmospheric Chemistry and Physics, Vol. 12, Issue 9 https://doi.org/10.5194/acp-12-4117-2012	journal	January 2012
Gas phase formation of extremely oxidized pinene reaction products in chamber and ambient air Ehn, M.; Kleist, E.; Junninen, H. Atmospheric Chemistry and Physics, Vol. 12, Issue 11 https://doi.org/10.5194/acp-12-5113-2012	journal	January 2012
A two-dimensional volatility basis set – Part 2: Diagnostics of organic-aerosol evolution Donahue, N. M.; Kroll, J. H.; Pandis, S. N. Atmospheric Chemistry and Physics, Vol. 12, Issue 2 https://doi.org/10.5194/acp-12-615-2012	journal	January 2012
Oxidation of SO ₂ by stabilized Criegee intermediate (sCI) radicals as a crucial source for atmospheric sulfuric acid concentrations Boy, M.; Mogensen, D.; Smolander, S. Atmospheric Chemistry and Physics, Vol. 13, Issue 7 https://doi.org/10.5194/acp-13-3865-2013	journal	January 2013
Reactivity of stabilized Criegee intermediates (sCIs) from isoprene and monoterpene ozonolysis toward SO ₂ and organic acids Sipilä, M.; Jokinen, T.; Berndt, T. Atmospheric Chemistry and Physics, Vol. 14, Issue 22 https://doi.org/10.5194/acp-14-12143-2014	journal	January 2014
Enhancement of atmospheric H ₂ SO ₄ / H ₂ O nucleation: organic oxidation products versus amines Berndt, T.; Sipilä, M.; Stratmann, F. Atmospheric Chemistry and Physics, Vol. 14, Issue 2 https://doi.org/10.5194/acp-14-751-2014	journal	January 2014
Elemental composition and clustering behaviour of α-pinene oxidation products for different oxidation conditions Praplan, A. P.; Schobesberger, S.; Bianchi, F. Atmospheric Chemistry and Physics, Vol. 15, Issue 8 https://doi.org/10.5194/acp-15-4145-2015	journal	January 2015
Source characterization of highly oxidized multifunctional compounds in a boreal forest environment using positive matrix factorization Yan, Chao; Nie, Wei; Äijälä, Mikko Atmospheric Chemistry and Physics, Vol. 16, Issue 19 https://doi.org/10.5194/acp-16-12715-2016	journal	January 2016
Parametric sensitivity and uncertainty analysis of dimethylsulfide oxidation in the clear-sky remote marine boundary layer Lucas, D. D.; Prinn, R. G. Atmospheric Chemistry and Physics, Vol. 5, Issue 6 https://doi.org/10.5194/acp-5-1505-2005	journal	January 2005
Evaluated kinetic and photochemical data for atmospheric chemistry: Volume II – gas phase reactions of organic species Atkinson, R.; Baulch, D. L.; Cox, R. A. Atmospheric Chemistry and Physics, Vol. 6, Issue 11 https://doi.org/10.5194/acp-6-3625-2006	journal	January 2006
Atmospheric sulphuric acid and aerosol formation: implications from atmospheric measurements for nucleation and early growth mechanisms Sihto, S. -L.; Kulmala, M.; Kerminen, V. -M. Atmospheric Chemistry and Physics, Vol. 6, Issue 12 https://doi.org/10.5194/acp-6-4079-2006	journal	January 2006
Secondary aerosol formation from atmospheric reactions of aliphatic amines Murphy, S. M.; Sorooshian, A.; Kroll, J. H. Atmospheric Chemistry and Physics, Vol. 7, Issue 9 https://doi.org/10.5194/acp-7-2313-2007	journal	January 2007
Photochemical production of aerosols from real plant emissions Mentel, Th. F.; Wildt, J.; Kiendler-Scharr, A. Atmospheric Chemistry and Physics, Vol. 9, Issue 13 https://doi.org/10.5194/acp-9-4387-2009	journal	January 2009
A high-resolution mass spectrometer to measure atmospheric ion composition Junninen, H.; Ehn, M.; Petäjä, T. Atmospheric Measurement Techniques, Vol. 3, Issue 4 https://doi.org/10.5194/amt-3-1039-2010	journal	January 2010
Performance of a corona ion source for measurement of sulfuric acid by chemical ionization mass spectrometry Kürten, A.; Rondo, L.; Ehrhart, S. Atmospheric Measurement Techniques, Vol. 4, Issue 3 https://doi.org/10.5194/amt-4-437-2011	journal	January 2011
The mathematical principles and design of the NAIS – a spectrometer for the measurement of cluster ion and nanometer aerosol size distributions Mirme, S.; Mirme, A. Atmospheric Measurement Techniques, Vol. 6, Issue 4 https://doi.org/10.5194/amt-6-1061-2013	journal	January 2013
Towards Reconciling Measurements of Atmospherically Relevant Clusters by Chemical Ionization Mass Spectrometry and Mobility Classification/Vapor Condensation Jen, Coty N.; Hanson, David R.; McMurry, Peter H. Taylor & Francis https://doi.org/10.6084/m9.figshare.1282572.v1	text	January 2015
Toward Reconciling Measurements of Atmospherically Relevant Clusters by Chemical Ionization Mass Spectrometry and Mobility Classification/Vapor Condensation Jen, Coty N.; Hanson, David R.; McMurry, Peter H. Taylor & Francis https://doi.org/10.6084/m9.figshare.1282572.v2	text	January 2015
Toward Reconciling Measurements of Atmospherically Relevant Clusters by Chemical Ionization Mass Spectrometry and Mobility Classification/Vapor Condensation Jen, Coty N.; Hanson, David R.; McMurry, Peter H. Taylor & Francis https://doi.org/10.6084/m9.figshare.1282572.v3	text	January 2015
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