Effect of pressure and impurities on oxidation in supercritical CO 2

Pint, Bruce A.; Lehmusto, Juho; Lance, Michael J.; Keiser, James R.

doi:10.1002/maco.201810652

Title: Effect of pressure and impurities on oxidation in supercritical CO ₂

Journal Article · Thu Apr 04 00:00:00 EDT 2019 · Materials and Corrosion

DOI:https://doi.org/10.1002/maco.201810652· OSTI ID:1504996

^[1]; Lehmusto, Juho ^[2]; Lance, Michael J. ^[1]; Keiser, James R. ^[1]

Materials Science and Technology Division Oak Ridge National Laboratory Oak Ridge Tennessee
Materials Science and Technology Division Oak Ridge National Laboratory Oak Ridge Tennessee, Laboratory of Inorganic Chemistry, Johan Gadolin Process Chemistry Centre, Åbo Akademi University Turku Finland

Abstract Both indirect‐ and direct‐fired supercritical CO ₂ cycles for high‐efficiency power generation are expected to have impurities that may greatly alter the compatibility of Fe‐ and Ni‐based structural alloys in these environments. Recent work has attempted to quantify reaction rates at 750°C in simulated laboratory environments with controlled impurity levels at ambient pressure, as well as under supercritical conditions (30 MPa). With low impurity levels in research and industrial‐grade CO ₂ , pressure appeared to have only a limited effect on oxide thickness and internal oxidation and reaction products were similar to those formed in laboratory air. However, a direct‐fired simulation at 750°C/30 MPa in CO ₂ + 1%O ₂ + 0.25%H ₂ O has found an increased mass gain and characterization after 2,500‐hr exposures have found thicker reaction products, especially for Fe‐based alloys. At these impurity levels, pressure may have a significant effect on the role of impurities.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: DE‐EE0001556

OSTI ID:: 1504996

Journal Information:: Materials and Corrosion, Journal Name: Materials and Corrosion Vol. 70 Journal Issue: 8; ISSN 0947-5117

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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Cited by: 24 works

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