Department of Chemistry University of California Riverside CA 92521 USA
Department of Chemistry and Biochemistry California State University Long Beach Long Beach CA 90840 USA
Department of Chemistry University of California Riverside CA 92521 USA, Shanxi Key Laboratory of Gas Energy Efficient and Clean Utilization Taiyuan University of Technology Taiyuan Shanxi 030024 China
Shanxi Key Laboratory of Gas Energy Efficient and Clean Utilization Taiyuan University of Technology Taiyuan Shanxi 030024 China
The introduction of a symmetry‐ and size‐matching pore‐partitioning agent in the form of either a molecular ligand, such as 2,4,6‐tri(4‐pyridinyl)‐1,3,5‐triazine ( tpt ), or a metal‐complex cluster, into the hexagonal channels of MIL‐88/MOF‐235‐type (the acs net) to create pacs ‐type (partitioned acs ) crystalline porous materials is an effective strategy to develop high‐performance gas adsorbents. We have developed an integrated COF–MOF coassembly strategy as a new method for pore‐space partitioning through the coassembly of [(M 3 (OH) 1− x (O) x (COO) 6 ] MOF‐type and [B 3 O 3 (py) 3 ] COF‐type trimers. With this strategy, the coordination‐driven assembly of the acs framework occurred concurrently and synergistically with the COF‐1‐type condensation of pyridine‐4‐boronic acid into a C 3 ‐symmetric trimeric boroxine molecule. The resulting boroxine‐based pacs materials exhibited dramatically enhanced gas‐sorption properties as compared to nonpartitioned acs ‐type materials and are among the most efficient NH 3 ‐sorption materials.
Wang, Yanxiang, et al. "A Tale of Two Trimers from Two Different Worlds: A COF‐Inspired Synthetic Strategy for Pore‐Space Partitioning of MOFs." Angewandte Chemie, vol. 131, no. 19, Apr. 2019. https://doi.org/10.1002/ange.201901343
Wang, Yanxiang, Zhao, Xiang, Yang, Huajun, Bu, Xianhui, Wang, Yong, Jia, Xiaoxia, Li, Jinping, & Feng, Pingyun (2019). A Tale of Two Trimers from Two Different Worlds: A COF‐Inspired Synthetic Strategy for Pore‐Space Partitioning of MOFs. Angewandte Chemie, 131(19). https://doi.org/10.1002/ange.201901343
Wang, Yanxiang, Zhao, Xiang, Yang, Huajun, et al., "A Tale of Two Trimers from Two Different Worlds: A COF‐Inspired Synthetic Strategy for Pore‐Space Partitioning of MOFs," Angewandte Chemie 131, no. 19 (2019), https://doi.org/10.1002/ange.201901343
@article{osti_1504507,
author = {Wang, Yanxiang and Zhao, Xiang and Yang, Huajun and Bu, Xianhui and Wang, Yong and Jia, Xiaoxia and Li, Jinping and Feng, Pingyun},
title = {A Tale of Two Trimers from Two Different Worlds: A COF‐Inspired Synthetic Strategy for Pore‐Space Partitioning of MOFs},
annote = {Abstract The introduction of a symmetry‐ and size‐matching pore‐partitioning agent in the form of either a molecular ligand, such as 2,4,6‐tri(4‐pyridinyl)‐1,3,5‐triazine ( tpt ), or a metal‐complex cluster, into the hexagonal channels of MIL‐88/MOF‐235‐type (the acs net) to create pacs ‐type (partitioned acs ) crystalline porous materials is an effective strategy to develop high‐performance gas adsorbents. We have developed an integrated COF–MOF coassembly strategy as a new method for pore‐space partitioning through the coassembly of [(M 3 (OH) 1− x (O) x (COO) 6 ] MOF‐type and [B 3 O 3 (py) 3 ] COF‐type trimers. With this strategy, the coordination‐driven assembly of the acs framework occurred concurrently and synergistically with the COF‐1‐type condensation of pyridine‐4‐boronic acid into a C 3 ‐symmetric trimeric boroxine molecule. The resulting boroxine‐based pacs materials exhibited dramatically enhanced gas‐sorption properties as compared to nonpartitioned acs ‐type materials and are among the most efficient NH 3 ‐sorption materials. },
doi = {10.1002/ange.201901343},
url = {https://www.osti.gov/biblio/1504507},
journal = {Angewandte Chemie},
issn = {ISSN 0044-8249},
number = {19},
volume = {131},
place = {Germany},
publisher = {Wiley Blackwell (John Wiley & Sons)},
year = {2019},
month = {04}}