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Phase transformations of HfNbTaTiZr high-entropy alloy at intermediate temperatures

Journal Article · · Scripta Materialia
 [1];  [1];  [2];  [2];  [3];  [4];  [5];  [6];  [6];  [4];  [1];  [1];  [1]
  1. Univ. of Tennessee, Knoxville, TN (United States)
  2. National Tsing Hua University, Hsinchu (Taiwan)
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  4. Argonne National Lab. (ANL), Argonne, IL (United States)
  5. National Energy Technology Lab. (NETL), Albany, OR (United States); AECOM, South Park, PA (United States)
  6. Illinois Institute of Technology, Chicago, IL (United States)

The strong and ductile single-phase body-centered-cubic (BCC) HfNbTaTiZr refractory high-entropy alloy (RHEA) is a potential structural material for high-temperature applications. However, the BCC phase stability in the intermediate temperature range (500-900 degrees C) needs to be better understood to make this alloy applicable to industry. Here, the phase decomposition of the HfNbTaTiZr RHEA is examined at different temperatures (500-1000 degrees C). Additionally, the formation of BCC Ta-Nb-rich and hexagonal-close-packed (HCP) Hf-Zr-rich precipitates are studied as a function of annealing time at 700 degrees C using a combination of atom probe tomography, transmission electron microscopy, and X-ray diffraction. In conclusion, we found that these BCC and HCP precipitates have preferred orientations with the BCC matrix.

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Scientific User Facilities Division; USDOE Office of Fossil Energy (FE); University of Tennessee; National Science Foundation (NSF); Ministry of Education of the People's Republic of China; Ministry of Science and Technology of the Republic of China (MOST)
Grant/Contract Number:
AC02-06CH11357; FE0011194; AC02-05CH11231; FE0004000
OSTI ID:
1504430
Alternate ID(s):
OSTI ID: 1702957
OSTI ID: 1532675
OSTI ID: 1561614
OSTI ID: 22819327
Journal Information:
Scripta Materialia, Journal Name: Scripta Materialia Journal Issue: C Vol. 158; ISSN 1359-6462
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English

References (19)

Solid-Solution Phase Formation Rules for Multi-component Alloys journal June 2008
Microstructure and elevated temperature properties of a refractory TaNbHfZrTi alloy journal January 2012
Effect of Cold Deformation and Annealing on the Microstructure and Tensile Properties of a HfNbTaTiZr Refractory High Entropy Alloy journal May 2018
Physical Metallurgy of High-Entropy Alloys journal August 2015
On the process of transition of the cubic-body-centered modification into the hexagonal-close-packed modification of zirconium journal May 1934
Phase stability in high entropy alloys: Formation of solid-solution phase or amorphous phase journal December 2011
Low-density, refractory multi-principal element alloys of the Cr–Nb–Ti–V–Zr system: Microstructure and phase analysis journal March 2013
A critical review of high entropy alloys and related concepts journal January 2017
Thermodynamic instability of a nanocrystalline, single-phase TiZrNbHfTa alloy and its impact on the mechanical properties journal January 2018
Microstructure and properties of a refractory high-entropy alloy after cold working journal November 2015
Superconductivity in thermally annealed Ta-Nb-Hf-Zr-Ti high-entropy alloys journal February 2017
Microstructure and mechanical properties of a refractory HfNbTiVSi0.5 high-entropy alloy composite journal July 2016
Aging behavior of the HfNbTaTiZr high entropy alloy journal January 2018
TiZrNbTaMo high-entropy alloy designed for orthopedic implants: As-cast microstructure and mechanical properties journal April 2017
Microstructures and properties of high-entropy alloys journal April 2014
In situ site-specific specimen preparation for atom probe tomography journal February 2007
Calibration and correction of distortions in two‐dimensional detector systems a) journal March 1995
The microstructure of a multielement nanostructured (TiZrHfVNbTa)N coating and its resistance to irradiation with Au– ions journal November 2015
Classification of Bulk Metallic Glasses by Atomic Size Difference, Heat of Mixing and Period of Constituent Elements and Its Application to Characterization of the Main Alloying Element journal January 2005

Cited By (8)

The Effect of Processing Route on Properties of HfNbTaTiZr High Entropy Alloy journal December 2019
Critical Review of Chemical Complexity Effect on Local Structure of Multi-principal-Element Alloys journal August 2019
On the Room-Temperature Mechanical Properties of an Ion-Irradiated TiZrNbHfTa Refractory High Entropy Alloy journal November 2019
Peierls barrier characteristic and anomalous strain hardening provoked by dynamic-strain-aging strengthening in a body-centered-cubic high-entropy alloy journal August 2019
Additive Manufacturing of High-Entropy Alloys: A Review journal December 2018
Microstructure and Room Temperature Mechanical Properties of Different 3 and 4 Element Medium Entropy Alloys from HfNbTaTiZr System journal January 2019
Hexagonal Closed-Packed Precipitation Enhancement in a NbTiHfZr Refractory High-Entropy Alloy journal April 2019
Microstructure and Mechanical Properties of Sintered and Heat-Treated HfNbTaTiZr High Entropy Alloy journal December 2019

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