Diffusion-free Grotthuss topochemistry for high-rate and long-life proton batteries

Wu, Xianyong; Hong, Jessica J.; Shin, Woochul; Ma, Lu; Liu, Tongchao; Bi, Xuanxuan; Yuan, Yifei; Qi, Yitong; Surta, T. Wesley; Huang, Wenxi; Neuefeind, Joerg; Wu, Tianpin; Greaney, P. Alex; Lu, Jun; Ji, Xiulei

doi:10.1038/s41560-018-0309-7

Diffusion-free Grotthuss topochemistry for high-rate and long-life proton batteries

Journal Article · Mon Jan 28 00:00:00 EST 2019 · Nature Energy

DOI:https://doi.org/10.1038/s41560-018-0309-7· OSTI ID:1504249

Wu, Xianyong ^[1]; Hong, Jessica J. ^[1]; Shin, Woochul ^[1]; ^[2]; Liu, Tongchao ^[2]; Bi, Xuanxuan ^[2]; ^[2]; Qi, Yitong ^[1]; Surta, T. Wesley ^[1]; Huang, Wenxi ^[3]; ^[4]; Wu, Tianpin ^[2]; ^[3]; ^[2]; ^[1]

Oregon State Univ., Corvallis, OR (United States)
Argonne National Lab. (ANL), Lemont, IL (United States)
Univ. of California, Riverside, CA (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

The design of Faradaic battery electrodes that exhibit high rate capability and long cycle life equivalent to those of the electrodes of electrical double-layer capacitors is a big challenge. Here we report a strategy to fill this performance gap using the concept of Grotthuss proton conduction, in which proton transfer takes place by means of concerted cleavage and formation of O-H bonds in a hydrogen-bonding network. We show that in a hydrated Prussian blue analogue (Turnbull's blue) the abundant lattice water molecules with a contiguous hydrogen-bonding network facilitate Grotthuss proton conduction during redox reactions. When using it as a battery electrode, we find high-rate behaviours at 4,000 C (380 Ag^-1, 508 mA cm^-2), and a long cycling life of 0.73 million cycles. Furthermore these results for diffusion-free Grotthuss topochemistry of protons, in contrast to orthodox battery electrochemistry, which requires ion diffusion inside electrodes, indicate a potential direction to revolutionize electrochemical energy storage for high-power applications.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE Office of Science (SC)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1504249

Journal Information:: Nature Energy, Journal Name: Nature Energy Journal Issue: 2 Vol. 4; ISSN 2058-7546

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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