Influence of cobalt substitution on the magnetism of NiBr2

Rai, Binod K.; Christianson, Andrew D.; Mandrus, David; May, Andrew F.

doi:10.1103/PhysRevMaterials.3.034005

Title: Influence of cobalt substitution on the magnetism of ${NiBr}_{2}$

Journal Article · Mon Mar 25 00:00:00 EDT 2019 · Physical Review Materials

DOI:https://doi.org/10.1103/PhysRevMaterials.3.034005· OSTI ID:1503988

^[1];

^[1]; Mandrus, David ^[2];

^[1]

Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)

Co-substituted Ni_1-xCo_xBr₂ (0≤x≤1) single crystals were synthesized using vapor transport. As a result, the physical properties of the crystals were characterized by x-ray powder diffraction, magnetization, and specific-heat measurements. Room-temperature x-ray powder diffraction data indicate that a change from the CdCl₂ structure type to the CdI₂ structure type occurs within 0.56<0.76. NiBr₂ has a commensurate antiferromagnetic phase below T_N ≈ 46 K and an incommensurate magnetic ground state below T_IC ≈ 20 K. Both magnetic transitions are affected by cobalt substitution, and the incommensurate phase transition is present up to at least x=0.56. Here, the evolution of magnetism has been studied as a function of cobalt content and is summarized in the temperature-composition phase diagram.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725; AC05- 00OR22725

OSTI ID:: 1503988

Alternate ID(s):: OSTI ID: 1546353

Journal Information:: Physical Review Materials, Vol. 3, Issue 3; ISSN 2475-9953

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 5 works

Citation information provided by
Web of Science

References (38)

Pressure dependence of the incommensurate magnetic phase of NiBr ₂ and Ni _0.92 Zn _0.08 Br ₂ Day, P.; Vettier, C. Journal of Physics C: Solid State Physics, Vol. 14, Issue 8 https://doi.org/10.1088/0022-3719/14/8/006	journal	March 1981
The Magnetic Properties of the Iron Group Anhydrous Chlorides at Low Temperatures. I. Experimental Starr, C.; Bitter, F.; Kaufmann, A. R. Physical Review, Vol. 58, Issue 11 https://doi.org/10.1103/PhysRev.58.977	journal	December 1940
Neutron Diffraction Investigations of the Magnetic Ordering in Fe ${Br}_{2}$ , Co ${Br}_{2}$ , Fe ${Cl}_{2}$ , and Co ${Cl}_{2}$ Wilkinson, M. K.; Cable, J. W.; Wollan, E. O. Physical Review, Vol. 113, Issue 2 https://doi.org/10.1103/PhysRev.113.497	journal	January 1959
Optical and neutron diffraction study of the magnetic phase diagram of NiBr ₂ Day, P.; Dinsdale, A.; Krausz, E. R. Journal of Physics C: Solid State Physics, Vol. 9, Issue 13 https://doi.org/10.1088/0022-3719/9/13/008	journal	July 1976
Theory of field- and temperature-induced helix-antiferro transition: Application to NiBr2 Yoshiyama, H.; Suzuki, N.; Motizuki, K. Journal of Magnetism and Magnetic Materials, Vol. 54-57 https://doi.org/10.1016/0304-8853(86)90850-4	journal	February 1986
Inelastic neutron scattering investigation of the magnetic excitations in the helimagnetic state of NiBr2 Régnault, L. P.; Rossat-Mignod, J.; Adam, A. Journal de Physique, Vol. 43, Issue 8 https://doi.org/10.1051/jphys:019820043080128300	journal	January 1982
NiX ₂ (X = Cl and Br) sheets as promising spin materials: a first-principles study Mushtaq, Muhammad; Zhou, Yungang; Xiang, Xia RSC Advances, Vol. 7, Issue 36 https://doi.org/10.1039/C7RA02218B	journal	January 2017
Magnetic phase diagrams and helical magnetic phases inMxNi1−xBr2 (M =Fe, Mn): A neutron diffraction and magneto-optical study Moore, Martin W.; Day, Peter Journal of Solid State Chemistry, Vol. 59, Issue 1 https://doi.org/10.1016/0022-4596(85)90347-0	journal	August 1985
Bubble and skyrmion crystals in frustrated magnets with easy-axis anisotropy Hayami, Satoru; Lin, Shi-Zeng; Batista, Cristian D. Physical Review B, Vol. 93, Issue 18 https://doi.org/10.1103/PhysRevB.93.184413	journal	May 2016
Magnetoelectric responses induced by domain rearrangement and spin structural change in triangular-lattice helimagnets NiI $_{2}$ and CoI $_{2}$ Kurumaji, T.; Seki, S.; Ishiwata, S. Physical Review B, Vol. 87, Issue 1 https://doi.org/10.1103/PhysRevB.87.014429	journal	January 2013
Multiferroicity in NiBr $_{2}$ with long-wavelength cycloidal spin structure on a triangular lattice Tokunaga, Y.; Okuyama, D.; Kurumaji, T. Physical Review B, Vol. 84, Issue 6 https://doi.org/10.1103/PhysRevB.84.060406	journal	August 2011
Magnetic phase transitions in a random mixture with competing Ising and $XY$ spin anisotropies Katsumata, K.; Tuchendler, J.; Legrand, S. Physical Review B, Vol. 30, Issue 3 https://doi.org/10.1103/PhysRevB.30.1377	journal	August 1984
Frustration and chiral orderings in correlated electron systems Batista, Cristian D.; Lin, Shi-Zeng; Hayami, Satoru Reports on Progress in Physics, Vol. 79, Issue 8 https://doi.org/10.1088/0034-4885/79/8/084504	journal	July 2016
Magnetic ordering and multiferroicity in MnI $_{2}$ Wu, Xianxin; Cai, Yingxiang; Xie, Qing Physical Review B, Vol. 86, Issue 13 https://doi.org/10.1103/PhysRevB.86.134413	journal	October 2012
Hydrostatic pressure effect on the commensurate—incommensurate phase transition of NiBr2 Adam, A.; Billerey, D.; Terrier, C. Physics Letters A, Vol. 84, Issue 1 https://doi.org/10.1016/0375-9601(81)90008-6	journal	July 1981
Recent advances in magnetic structure determination by neutron powder diffraction Rodríguez-Carvajal, Juan Physica B: Condensed Matter, Vol. 192, Issue 1-2 https://doi.org/10.1016/0921-4526(93)90108-I	journal	October 1993
Magnetic satellites in the incommensurate phase of pure and doped NiBr ₂ Odisho, I. H.; Al-Dorry, H. M. Journal of Physics: Condensed Matter, Vol. 1, Issue 37 https://doi.org/10.1088/0953-8984/1/37/004	journal	September 1989
Magnetic and structural investigations on NiI2 and CoI2 Kuindersma, S. R.; Sanchez, J. P.; Haas, C. Physica B+C, Vol. 111, Issue 2-3 https://doi.org/10.1016/0378-4363(81)90100-5	journal	November 1981
Neutron diffraction study of the commensurate and incommensurate magnetic structures of NiBr2 Adam, A.; Billerey, D.; Terrier, C. Solid State Communications, Vol. 35, Issue 1 https://doi.org/10.1016/0038-1098(80)90757-7	journal	July 1980
Magnetic-Field Induced Competition of Two Multiferroic Orders in a Triangular-Lattice Helimagnet ${MnI}_{2}$ Kurumaji, T.; Seki, S.; Ishiwata, S. Physical Review Letters, Vol. 106, Issue 16 https://doi.org/10.1103/PhysRevLett.106.167206	journal	April 2011
Neutron diffraction study of the incommensurate magnetic phase of Ni _0.92 Zn _0.08 Br ₂ Day, P.; Moore, M. W.; Wilkinson, C. Journal of Physics C: Solid State Physics, Vol. 14, Issue 23 https://doi.org/10.1088/0022-3719/14/23/018	journal	August 1981
Multiply periodic states and isolated skyrmions in an anisotropic frustrated magnet Leonov, A. O.; Mostovoy, M. Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9275	journal	September 2015
Crystal and Magnetic Structures in Layered, Transition Metal Dihalides and Trihalides McGuire, Michael Crystals, Vol. 7, Issue 5 https://doi.org/10.3390/cryst7050121	journal	April 2017
Successive phase transitions in manganese helimagnets MnX2 (X = I, Br) observed by symmetry breaking birefringence Iio, K.; Masuda, H.; Tanaka, H. Journal of Magnetism and Magnetic Materials, Vol. 90-91 https://doi.org/10.1016/S0304-8853(10)80092-7	journal	December 1990
Helimagnetic resonance experiments in NiBr2 at millimetre wavelengths Tuchendler, J.; Katsumata, K. Solid State Communications, Vol. 55, Issue 8 https://doi.org/10.1016/0038-1098(85)90253-4	journal	August 1985
Intrinsic ferromagnetism and quantum anomalous Hall effect in a CoBr ₂ monolayer Chen, Peng; Zou, Jin-Yu; Liu, Bang-Gui Physical Chemistry Chemical Physics, Vol. 19, Issue 21 https://doi.org/10.1039/C7CP02158E	journal	January 2017
Multiple- $q$ States and the Skyrmion Lattice of the Triangular-Lattice Heisenberg Antiferromagnet under Magnetic Fields Okubo, Tsuyoshi; Chung, Sungki; Kawamura, Hikaru Physical Review Letters, Vol. 108, Issue 1 https://doi.org/10.1103/PhysRevLett.108.017206	journal	January 2012
X‐Ray Interference in Partially Ordered Layer Lattices Hendricks, Sterling; Teller, Edward The Journal of Chemical Physics, Vol. 10, Issue 3 https://doi.org/10.1063/1.1723678	journal	March 1942
Optical and magneto-optical study of the magnetic phase diagram and incommensurate magnetic phase of NiBr ₂ and Ni _1–x Zn _x Br ₂ Moore, Martin W.; Wood, Terence E.; Day, Peter J. Chem. Soc., Faraday Trans. 2, Vol. 77, Issue 9 https://doi.org/10.1039/F29817701611	journal	January 1981
Nickel dibromide: a magnetic detective story Day, Peter Accounts of Chemical Research, Vol. 21, Issue 6 https://doi.org/10.1021/ar00150a006	journal	June 1988
Experimental Observation of the Antiferro-Fan Transition in NiBr ₂ Katsumata, Koichi; Sugiyama, Kiyohiro; Date, Muneyuki Journal of the Physical Society of Japan, Vol. 52, Issue 10 https://doi.org/10.1143/JPSJ.52.3312	journal	October 1983
Helix-antiferro-fan transition in NiBr ₂ under an in-plane magnetic field Yoshiyama, H.; Suzuki, N.; Motizuki, K. Journal of Physics C: Solid State Physics, Vol. 17, Issue 4 https://doi.org/10.1088/0022-3719/17/4/013	journal	February 1984
Magnetic-field-induced incommensurate to collinear spin order transition in NiBr 2 Babu, S.; Prokeš, K.; Huang, Y. K. Journal of Applied Physics, Vol. 125, Issue 9 https://doi.org/10.1063/1.5066625	journal	March 2019
Non-simple magnetic order for simple Hamiltonians Rastelli, E.; Tassi, A.; Reatto, L. Physica B+C, Vol. 97, Issue 1 https://doi.org/10.1016/0378-4363(79)90002-0	journal	July 1979
Magnetic Vortex Induced by Nonmagnetic Impurity in Frustrated Magnets Lin, Shi-Zeng; Hayami, Satoru; Batista, Cristian D. Physical Review Letters, Vol. 116, Issue 18 https://doi.org/10.1103/PhysRevLett.116.187202	journal	May 2016
Disorder in Layered Hydroxides: Diffax Simulation of the X-ray Powder Diffraction Patterns of Nickel Hydroxide Ramesh, T. N.; Jayashree, R. S.; Kamath, P. Vishnu Clays and Clay Minerals, Vol. 51, Issue 5 https://doi.org/10.1346/CCMN.2003.0510511	journal	October 2003
Influence of uniaxial single-ion anisotropy on the magnetic and thermal properties of Heisenberg antiferromagnets within unified molecular field theory Johnston, David C. Physical Review B, Vol. 95, Issue 9 https://doi.org/10.1103/PhysRevB.95.094421	journal	March 2017
Relation between the specific heat and susceptibility of an antiferromagnet Fisher, Michael E. Philosophical Magazine, Vol. 7, Issue 82 https://doi.org/10.1080/14786436208213705	journal	October 1962

Similar Records

Magnetic properties of Fe-substituted NiBr2 single crystals

Journal Article · Tue May 10 00:00:00 EDT 2022 · Journal of Magnetism and Magnetic Materials · OSTI ID:1503988

Rai, Binod K.; Gao, Shang; Frontzek, Matthias; +3 more

Complex magnetic order in the decorated spin-chain system

{Rb}_{2} {Mn}_{3} {({MoO}_{4})}_{3} {(OH)}_{2}

Journal Article · Mon Feb 24 00:00:00 EST 2020 · Physical Review B · OSTI ID:1503988

Liu, Yaohua; Sanjeewa, Liurukara D.; Garlea, V. Ovidiu; +3 more

Nanosized helical magnetic domains in strongly frustrated

{Fe}_{3} {PO}_{4} O_{3}

Journal Article · Mon Oct 26 00:00:00 EDT 2015 · Physical Review. B, Condensed Matter and Materials Physics · OSTI ID:1503988

Ross, K. A.; Bordelon, M. M.; Terho, G.; +1 more

Related Subjects

36 MATERIALS SCIENCE

Title: Influence of cobalt substitution on the magnetism of NiBr 2

Citation Formats

References (38)

Similar Records

Related Subjects

Title: Influence of cobalt substitution on the magnetism of ${NiBr}_{2}$