Stable Luminous Nanocomposites of Confined Mn2+-Doped Lead Halide Perovskite Nanocrystals in Mesoporous Silica Nanospheres as Orange Fluorophores

Pan, Aizhao; Wu, Youshen; Yan, Ke; Yu, Yun; Jurow, Matthew J.; Ren, Baoyi; Zhang, Cong; Ding, Shujiang; He, Ling; Liu, Yi

doi:10.1021/acs.inorgchem.9b00010

Title: Stable Luminous Nanocomposites of Confined Mn²⁺-Doped Lead Halide Perovskite Nanocrystals in Mesoporous Silica Nanospheres as Orange Fluorophores

Journal Article · Mon Mar 04 00:00:00 EST 2019 · Inorganic Chemistry

DOI:https://doi.org/10.1021/acs.inorgchem.9b00010· OSTI ID:1503663

^[1]; Wu, Youshen ^[1]; Yan, Ke ^[1]; Yu, Yun ^[1];

^[2]; Ren, Baoyi ^[3]; Zhang, Cong ^[2];

^[1];

^[2]

Xi'an Jiaotong Univ., Xi'an (China)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Xi'an Jiaotong Univ., Xi'an (China); Shenyang Univ. of Chemical Technology, Shenyang (China)

Creating highly stable inorganic perovskite nanocrystals (CsPbX₃, where X = Cl, Br, and I) with excellent optical performance is challenging because their optical properties depend on their ionic structure and its inherent defects. Here, we present a facile and effective synthesis using a nanoconfinement strategy to grow Mn²⁺-doped CsPbCl₃ nanocrystals embedded in dendritic mesoporous silica nanospheres (MSNs). The resulting nanocomposite is abbreviated as Cs(Pb_x/Mn_1-x)Cl₃@MSNs and can serve as the orange emitter for white light-emitting diodes (WLEDs). The MSN matrix was prepared via a templated sol-gel technique as monodispersed center-radial dendritic porous particles, with a diamater of ~105 nm and an inner pore size of ~13 nm. The MSN was then utilized as the matrix to initiate the growth of Mn-doped perovskite nanocrystals (NCs). The NCs in the resulting composite have an average diameter of 8 nm and a photoluminescence quantum yield of >30%. In addition, the optical properties of the Cs(Pb_x/Mn_1-x)Cl₃@MSNs can be tuned by varying the Mn²⁺ doping level. The resulting composites presented a significantly improved resistance to ultraviolet (UV) light, temperature, and moisture compared to that of bare Cs(Pb_0.72/Mn_0.28)Cl₃. Finally, we fabricated down-converting WLEDs by using Cs(Pb_x/Mn_1-x)Cl₃@MSNs as the orange-emitting phosphor deposited onto UV-emitting chips, demonstrating their promising applications in solid-state lighting. Furthermore this work provides a valuable approach to fabricating stable orange luminophores as replacements for traditional emitters in light-emitting diode devices.

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Research Organization:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1503663

Journal Information:: Inorganic Chemistry, Vol. 58, Issue 6; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 26 works

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Title: Stable Luminous Nanocomposites of Confined Mn2+-Doped Lead Halide Perovskite Nanocrystals in Mesoporous Silica Nanospheres as Orange Fluorophores

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Title: Stable Luminous Nanocomposites of Confined Mn²⁺-Doped Lead Halide Perovskite Nanocrystals in Mesoporous Silica Nanospheres as Orange Fluorophores