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Title: Combining X-ray Kβ1,3, valence-to-core, and X-ray Raman spectroscopy for studying Earth materials at high pressure and temperature: the case of siderite

Journal Article · · Journal of Analytical Atomic Spectrometry
DOI:https://doi.org/10.1039/c8ja00247a· OSTI ID:1503081
 [1];  [2]; ORCiD logo [1];  [3]; ORCiD logo [4];  [5]; ORCiD logo [5]; ORCiD logo [1]; ORCiD logo [1];  [6];  [7];  [8];  [9]; ORCiD logo [10];  [1];  [2]
  1. Technische Univ. Dortmund, Dortmund (Germany)
  2. Univ. Potsdam, Potsdam (Germany)
  3. Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany)
  4. Hungarian Academy Sciences, Budapest (Hungary)
  5. European Synchrotron Radiation Facility, Grenoble Cedex (France)
  6. Univ. Munster, Munster (Germany)
  7. Univ. of Bayreuth, Bayreuth (Germany)
  8. Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany); SLAC National Accelerator Lab., Menlo Park, CA (United States)
  9. European XFEL, Hamburg (Germany)
  10. European XFEL, Hamburg (Germany); Adam Mickiewicz Univ., Poznan (Poland)

The high spin to low spin transition of siderite is studied by simultaneous X-ray emission and X-ray Raman scattering spectroscopy.

Research Organization:
SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)
Sponsoring Organization:
USDOE
Grant/Contract Number:
AC02-76SF00515; VEKOP-2.3.2-16-2017-00015; EXC 1069; 05K10PEC; 05K13PE2; 05K16PE1; 2016/22/E/ST4/00543; LP2013-59
OSTI ID:
1503081
Journal Information:
Journal of Analytical Atomic Spectrometry, Vol. 34, Issue 2; ISSN 0267-9477
Publisher:
Royal Society of ChemistryCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 14 works
Citation information provided by
Web of Science

References (66)

Cation Hydration in Supercritical NaOH and HCl Aqueous Solutions journal December 2017
Pressure-Induced High-Spin to Low-Spin Transition in FeS Evidenced by X-Ray Emission Spectroscopy journal April 1999
Probing the 3d Spin Momentum with X-ray Emission Spectroscopy:  The Case of Molecular-Spin Transitions journal June 2006
Iron speciation in minerals and glasses probed by $$\hbox{M}_{2/3}$$ M 2 / 3 -edge X-ray Raman scattering spectroscopy journal May 2014
Direct tomography imaging for inelastic X-ray scattering experiments at high pressure journal January 2017
Spin crossover in ( Mg , Fe ) O : A Mössbauer effect study with an alternative interpretation of x-ray emission spectroscopy data journal March 2006
X-ray Raman spectroscopy of lithium-ion battery electrolyte solutions in a flow cell journal February 2018
Spin Transition Zone in Earth's Lower Mantle journal September 2007
Probing of Pressure-Induced Bonding Transitions in Crystalline and Amorphous Earth Materials: Insights from X-ray Raman Scattering at High Pressure journal January 2014
The high-pressure electronic structure of magnesiowustite (Mg, Fe)O: Applications to the physics and chemistry of the lower mantle journal August 1991
Spin and valence states of iron in Al-bearing silicate glass at high pressures studied by synchrotron Mossbauer and X-ray emission spectroscopy journal February 2014
Spin Transitions in Mantle Minerals journal May 2014
Valence to Core X-ray Emission Spectroscopy journal May 2014
Nearest-neighbor oxygen distances in liquid water and ice observed by x-ray Raman based extended x-ray absorption fine structure journal November 2007
Electronic Transitions in Perovskite: Possible Nonconvecting Layers in the Lower Mantle journal July 2004
High resolution 1s core hole X-ray spectroscopy in 3d transition metal complexes—electronic and structural information journal January 2005
An extraction algorithm for core-level excitations in non-resonant inelastic X-ray scattering spectra journal February 2008
Microscopic structure of water at elevated pressures and temperatures journal March 2013
A von Hamos x-ray spectrometer based on a segmented-type diffraction crystal for single-shot x-ray emission spectroscopy and time-resolved resonant inelastic x-ray scattering studies journal October 2012
Direct Evidence from Gas-Phase Atomic Spectra for an Unscreened Intra-Atomic Origin of Outer-Core Multiplet Splittings in Solid Manganese Compounds journal November 1988
Spectroscopy of low and intermediate Z elements at extreme conditions: in situ studies of Earth materials at pressure and temperature via X-ray Raman scattering journal July 2016
Carbonates from the lower part of transition zone or even the lower mantle journal August 2007
Miniature diamond anvils for X-ray Raman scattering spectroscopy experiments at high pressure journal January 2017
Structure of siderite FeCO 3 to 56 GPa and hysteresis of its spin-pairing transition journal August 2010
Local Structures around Si, Al and Na in Hydrated Silicate Glasses
  • Farges, François; de Wispelaere, Sidoine; Rossano, Stéphanie
  • X-RAY ABSORPTION FINE STRUCTURE - XAFS13: 13th International Conference, AIP Conference Proceedings https://doi.org/10.1063/1.2644478
conference January 2007
Iron spin state in silicate perovskite at conditions of the Earth's deep interior journal August 2013
Lithium borate crystals and glasses: How similar are they? A non-resonant inelastic X-ray scattering study around the B and O K -edges journal September 2017
Phase separation and Si nanocrystal formation in bulk SiO studied by x-ray scattering journal February 2010
Effects of the Electronic spin Transitions of iron in Lower Mantle Minerals: Implications for deep Mantle Geophysics and Geochemistry: spin Transition in Lower Mantle journal April 2013
Calibration of the ruby pressure gauge to 800 kbar under quasi-hydrostatic conditions journal January 1986
Pressure driven spin transition in siderite and magnesiosiderite single crystals journal November 2017
Magnetism in FeO at Megabar Pressures from X-Ray Emission Spectroscopy journal November 1999
Intermediate-spin ferrous iron in lowermost mantle post-perovskite and perovskite journal September 2008
Simulating the core-mantle boundary: An experimental study of high-pressure reactions between silicates and liquid iron journal July 1989
Spin transition of iron in magnesiowüstite in the Earth's lower mantle journal July 2005
Compression of single-crystal magnesium oxide to 118 GPa and a ruby pressure gauge for helium pressure media journal November 2008
Stability of iron-bearing carbonates in the deep Earth’s interior journal July 2017
Valence-to-Core X-Ray Emission Spectroscopy of Iron-Carbonyl Complexes: Implications for the Examination of Catalytic Intermediates journal October 2013
HERFD-XAS and valence-to-core-XES: new tools to push the limits in research with hard X-rays? journal January 2014
Thermal equation of state and spin transition of magnesiosiderite at high pressure and temperature journal January 2014
Diamond formation in the deep lower mantle: a high-pressure reaction of MgCO3 and SiO2 journal January 2017
Planning, performing and analyzing X-ray Raman scattering experiments journal February 2015
Mineralogy at the extremes journal January 2008
A high resolution and large solid angle x-ray Raman spectroscopy end-station at the Stanford Synchrotron Radiation Lightsource journal April 2012
A multi-crystal wavelength dispersive x-ray spectrometer journal July 2012
High-pressure spectroscopic study of siderite (FeCO 3 ) with a focus on spin crossover journal November 2015
The deep carbon cycle and melting in Earth's interior journal September 2010
X-ray Raman scattering study of MgSiO3 glass at high pressure: Implication for triclustered MgSiO3 melt in Earth's mantle journal June 2008
LAMBDA — Large Area Medipix3-Based Detector Array journal November 2012
A diamond anvil cell for x-ray fluorescence measurements of trace elements in fluids at high pressure and high temperature journal March 2009
Pressure induced spin transition revealed by iron M 2,3 -edge spectroscopy journal June 2014
Effect of temperature on the pressure-induced spin transition in siderite and iron-bearing magnesite: a Raman spectroscopy study [Effect of temperature on the pressure-induced spin transition in siderite and iron-bearing magnesite: a Raman spectroscopy study] journal December 2017
Multiple-element spectrometer for non-resonant inelastic X-ray spectroscopy of electronic excitations journal June 2009
Silicate Perovskite journal May 1992
Spin-polarized photoelectron diffraction journal April 1985
Bulk sensitive determination of the Fe 3+ /Fe Tot -ratio in minerals by Fe L 2/3 -edge X-ray Raman scattering journal January 2016
Chemical dependence of interatomic X-ray transition energies and intensities – a study of Mn Kβ″ and Kβ2,5 spectra journal March 1999
Chemical mass transfer in magmatic processes IV. A revised and internally consistent thermodynamic model for the interpolation and extrapolation of liquid-solid equilibria in magmatic systems at elevated temperatures and pressures journal March 1995
Direct tomography with chemical-bond contrast journal May 2011
High-resolution manganese x-ray fluorescence spectroscopy. Oxidation-state and spin-state sensitivity journal April 1994
EXAFS studies under high pressure by X-ray Raman scattering journal July 2016
Stability of iron-bearing carbonates in the deep Earth’s interior text January 2017
Chemical mass transfer in magmatic processes IV. A revised and internally consistent thermodynamic model for the interpolation and extrapolation of liquid-solid equilibria in magmatic systems at elevated temperatures and pressures journal March 1995
Pressure driven spin transition in siderite and magnesiosiderite single crystals text January 2017
Disentangling Structural Information From Core-level Excitation Spectra text January 2017
Pressure induced high-spin to low-spin transition in FeS evidenced by x-ray emission spectroscopy text January 1998

Cited By (2)

A von Hamos-type hard X-ray spectrometer at the PETRA III beamline P64 journal January 2020
A von Hamos-type hard X-ray spectrometer at the PETRA III beamline P64 text January 2020