skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Combining X-ray Kβ 1,3, valence-to-core, and X-ray Raman spectroscopy for studying Earth materials at high pressure and temperature: the case of siderite

Abstract

The high spin to low spin transition of siderite is studied by simultaneous X-ray emission and X-ray Raman scattering spectroscopy.

Authors:
 [1];  [2]; ORCiD logo [1];  [3]; ORCiD logo [4];  [5]; ORCiD logo [5]; ORCiD logo [1]; ORCiD logo [1];  [6];  [7];  [8];  [9]; ORCiD logo [10];  [1];  [2]
  1. Technische Univ. Dortmund, Dortmund (Germany)
  2. Univ. Potsdam, Potsdam (Germany)
  3. Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany)
  4. Hungarian Academy Sciences, Budapest (Hungary)
  5. European Synchrotron Radiation Facility, Grenoble Cedex (France)
  6. Univ. Munster, Munster (Germany)
  7. Univ. of Bayreuth, Bayreuth (Germany)
  8. Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany); SLAC National Accelerator Lab., Menlo Park, CA (United States)
  9. European XFEL, Hamburg (Germany)
  10. European XFEL, Hamburg (Germany); Adam Mickiewicz Univ., Poznan (Poland)
Publication Date:
Research Org.:
SLAC National Accelerator Lab., Menlo Park, CA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1503081
Grant/Contract Number:  
AC02-76SF00515; VEKOP-2.3.2-16-2017-00015; EXC 1069; 05K10PEC; 05K13PE2; 05K16PE1; 2016/22/E/ST4/00543; LP2013-59
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Journal of Analytical Atomic Spectrometry
Additional Journal Information:
Journal Volume: 34; Journal Issue: 2; Journal ID: ISSN 0267-9477
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
74 ATOMIC AND MOLECULAR PHYSICS

Citation Formats

Weis, Christopher, Spiekermann, Georg, Sternemann, Christian, Harder, Manuel, Vankó, György, Cerantola, Valerio, Sahle, Christoph J., Forov, Yury, Sakrowski, Robin, Kupenko, Ilya, Petitgirard, Sylvain, Yavaş, Hasan, Bressler, Christian, Gawelda, Wojciech, Tolan, Metin, and Wilke, Max. Combining X-ray Kβ1,3, valence-to-core, and X-ray Raman spectroscopy for studying Earth materials at high pressure and temperature: the case of siderite. United States: N. p., 2018. Web. doi:10.1039/c8ja00247a.
Weis, Christopher, Spiekermann, Georg, Sternemann, Christian, Harder, Manuel, Vankó, György, Cerantola, Valerio, Sahle, Christoph J., Forov, Yury, Sakrowski, Robin, Kupenko, Ilya, Petitgirard, Sylvain, Yavaş, Hasan, Bressler, Christian, Gawelda, Wojciech, Tolan, Metin, & Wilke, Max. Combining X-ray Kβ1,3, valence-to-core, and X-ray Raman spectroscopy for studying Earth materials at high pressure and temperature: the case of siderite. United States. doi:10.1039/c8ja00247a.
Weis, Christopher, Spiekermann, Georg, Sternemann, Christian, Harder, Manuel, Vankó, György, Cerantola, Valerio, Sahle, Christoph J., Forov, Yury, Sakrowski, Robin, Kupenko, Ilya, Petitgirard, Sylvain, Yavaş, Hasan, Bressler, Christian, Gawelda, Wojciech, Tolan, Metin, and Wilke, Max. Tue . "Combining X-ray Kβ1,3, valence-to-core, and X-ray Raman spectroscopy for studying Earth materials at high pressure and temperature: the case of siderite". United States. doi:10.1039/c8ja00247a. https://www.osti.gov/servlets/purl/1503081.
@article{osti_1503081,
title = {Combining X-ray Kβ1,3, valence-to-core, and X-ray Raman spectroscopy for studying Earth materials at high pressure and temperature: the case of siderite},
author = {Weis, Christopher and Spiekermann, Georg and Sternemann, Christian and Harder, Manuel and Vankó, György and Cerantola, Valerio and Sahle, Christoph J. and Forov, Yury and Sakrowski, Robin and Kupenko, Ilya and Petitgirard, Sylvain and Yavaş, Hasan and Bressler, Christian and Gawelda, Wojciech and Tolan, Metin and Wilke, Max},
abstractNote = {The high spin to low spin transition of siderite is studied by simultaneous X-ray emission and X-ray Raman scattering spectroscopy.},
doi = {10.1039/c8ja00247a},
journal = {Journal of Analytical Atomic Spectrometry},
issn = {0267-9477},
number = 2,
volume = 34,
place = {United States},
year = {2018},
month = {10}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 3 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Cation Hydration in Supercritical NaOH and HCl Aqueous Solutions
journal, December 2017

  • Sahle, Christoph J.; Niskanen, Johannes; Schmidt, Christian
  • The Journal of Physical Chemistry B, Vol. 121, Issue 50
  • DOI: 10.1021/acs.jpcb.7b09688

Pressure-Induced High-Spin to Low-Spin Transition in FeS Evidenced by X-Ray Emission Spectroscopy
journal, April 1999


Probing the 3d Spin Momentum with X-ray Emission Spectroscopy:  The Case of Molecular-Spin Transitions
journal, June 2006

  • Vankó, György; Neisius, Thomas; Molnár, Gábor
  • The Journal of Physical Chemistry B, Vol. 110, Issue 24
  • DOI: 10.1021/jp0615961

Iron speciation in minerals and glasses probed by $$\hbox{M}_{2/3}$$ M 2 / 3 -edge X-ray Raman scattering spectroscopy
journal, May 2014

  • Nyrow, A.; Sternemann, C.; Wilke, M.
  • Contributions to Mineralogy and Petrology, Vol. 167, Issue 5
  • DOI: 10.1007/s00410-014-1012-8

Direct tomography imaging for inelastic X-ray scattering experiments at high pressure
journal, January 2017


Spin crossover in ( Mg , Fe ) O : A Mössbauer effect study with an alternative interpretation of x-ray emission spectroscopy data
journal, March 2006


X-ray Raman spectroscopy of lithium-ion battery electrolyte solutions in a flow cell
journal, February 2018

  • Ketenoglu, Didem; Spiekermann, Georg; Harder, Manuel
  • Journal of Synchrotron Radiation, Vol. 25, Issue 2
  • DOI: 10.1107/S1600577518001662

Spin Transition Zone in Earth's Lower Mantle
journal, September 2007


Probing of Pressure-Induced Bonding Transitions in Crystalline and Amorphous Earth Materials: Insights from X-ray Raman Scattering at High Pressure
journal, January 2014

  • Lee, S. K.; Eng, P. J.; Mao, H. -k.
  • Reviews in Mineralogy and Geochemistry, Vol. 78, Issue 1
  • DOI: 10.2138/rmg.2014.78.4

The high-pressure electronic structure of magnesiowustite (Mg, Fe)O: Applications to the physics and chemistry of the lower mantle
journal, August 1991

  • Sherman, David M.
  • Journal of Geophysical Research: Solid Earth, Vol. 96, Issue B9
  • DOI: 10.1029/91JB01202

Spin Transitions in Mantle Minerals
journal, May 2014


Valence to Core X-ray Emission Spectroscopy
journal, May 2014


Nearest-neighbor oxygen distances in liquid water and ice observed by x-ray Raman based extended x-ray absorption fine structure
journal, November 2007

  • Bergmann, Uwe; Di Cicco, Andrea; Wernet, Philippe
  • The Journal of Chemical Physics, Vol. 127, Issue 17
  • DOI: 10.1063/1.2784123

High resolution 1s core hole X-ray spectroscopy in 3d transition metal complexes—electronic and structural information
journal, January 2005


An extraction algorithm for core-level excitations in non-resonant inelastic X-ray scattering spectra
journal, February 2008

  • Sternemann, H.; Sternemann, C.; Seidler, G. T.
  • Journal of Synchrotron Radiation, Vol. 15, Issue 2
  • DOI: 10.1107/S0909049508001696

Microscopic structure of water at elevated pressures and temperatures
journal, March 2013

  • Sahle, C. J.; Sternemann, C.; Schmidt, C.
  • Proceedings of the National Academy of Sciences, Vol. 110, Issue 16
  • DOI: 10.1073/pnas.1220301110

Direct Evidence from Gas-Phase Atomic Spectra for an Unscreened Intra-Atomic Origin of Outer-Core Multiplet Splittings in Solid Manganese Compounds
journal, November 1988


Carbonates from the lower part of transition zone or even the lower mantle
journal, August 2007

  • Brenker, Frank E.; Vollmer, Christian; Vincze, Laszlo
  • Earth and Planetary Science Letters, Vol. 260, Issue 1-2
  • DOI: 10.1016/j.epsl.2007.02.038

Miniature diamond anvils for X-ray Raman scattering spectroscopy experiments at high pressure
journal, January 2017

  • Petitgirard, Sylvain; Spiekermann, Georg; Weis, Christopher
  • Journal of Synchrotron Radiation, Vol. 24, Issue 1
  • DOI: 10.1107/S1600577516017112

Structure of siderite FeCO 3 to 56 GPa and hysteresis of its spin-pairing transition
journal, August 2010


Local Structures around Si, Al and Na in Hydrated Silicate Glasses
conference, January 2007

  • Farges, François; de Wispelaere, Sidoine; Rossano, Stéphanie
  • X-RAY ABSORPTION FINE STRUCTURE - XAFS13: 13th International Conference, AIP Conference Proceedings
  • DOI: 10.1063/1.2644478

Iron spin state in silicate perovskite at conditions of the Earth's deep interior
journal, August 2013


Lithium borate crystals and glasses: How similar are they? A non-resonant inelastic X-ray scattering study around the B and O K -edges
journal, September 2017


Phase separation and Si nanocrystal formation in bulk SiO studied by x-ray scattering
journal, February 2010

  • Feroughi, O. M.; Sternemann, C.; Sahle, Ch. J.
  • Applied Physics Letters, Vol. 96, Issue 8
  • DOI: 10.1063/1.3323106

Calibration of the ruby pressure gauge to 800 kbar under quasi-hydrostatic conditions
journal, January 1986

  • Mao, H. K.; Xu, J.; Bell, P. M.
  • Journal of Geophysical Research, Vol. 91, Issue B5, p. 4673-4676
  • DOI: 10.1029/JB091iB05p04673

Pressure driven spin transition in siderite and magnesiosiderite single crystals
journal, November 2017

  • Weis, Christopher; Sternemann, Christian; Cerantola, Valerio
  • Scientific Reports, Vol. 7, Issue 1
  • DOI: 10.1038/s41598-017-16733-3

Magnetism in FeO at Megabar Pressures from X-Ray Emission Spectroscopy
journal, November 1999


Intermediate-spin ferrous iron in lowermost mantle post-perovskite and perovskite
journal, September 2008

  • Lin, Jung-Fu; Watson, Heather; Vankó, György
  • Nature Geoscience, Vol. 1, Issue 10
  • DOI: 10.1038/ngeo310

Simulating the core-mantle boundary: An experimental study of high-pressure reactions between silicates and liquid iron
journal, July 1989


Spin transition of iron in magnesiowüstite in the Earth's lower mantle
journal, July 2005

  • Lin, Jung-Fu; Struzhkin, Viktor V.; Jacobsen, Steven D.
  • Nature, Vol. 436, Issue 7049
  • DOI: 10.1038/nature03825

Compression of single-crystal magnesium oxide to 118 GPa and a ruby pressure gauge for helium pressure media
journal, November 2008

  • Jacobsen, S. D.; Holl, C. M.; Adams, K. A.
  • American Mineralogist, Vol. 93, Issue 11-12
  • DOI: 10.2138/am.2008.2988

Stability of iron-bearing carbonates in the deep Earth’s interior
journal, July 2017

  • Cerantola, Valerio; Bykova, Elena; Kupenko, Ilya
  • Nature Communications, Vol. 8, Issue 1
  • DOI: 10.1038/ncomms15960

Valence-to-Core X-Ray Emission Spectroscopy of Iron-Carbonyl Complexes: Implications for the Examination of Catalytic Intermediates
journal, October 2013

  • Delgado-Jaime, Mario Ulises; DeBeer , Serena; Bauer, Matthias
  • Chemistry - A European Journal, Vol. 19, Issue 47
  • DOI: 10.1002/chem.201301913

HERFD-XAS and valence-to-core-XES: new tools to push the limits in research with hard X-rays?
journal, January 2014


Thermal equation of state and spin transition of magnesiosiderite at high pressure and temperature
journal, January 2014


Diamond formation in the deep lower mantle: a high-pressure reaction of MgCO3 and SiO2
journal, January 2017

  • Maeda, Fumiya; Ohtani, Eiji; Kamada, Seiji
  • Scientific Reports, Vol. 7, Issue 1
  • DOI: 10.1038/srep40602

Planning, performing and analyzing X-ray Raman scattering experiments
journal, February 2015


Mineralogy at the extremes
journal, January 2008


A high resolution and large solid angle x-ray Raman spectroscopy end-station at the Stanford Synchrotron Radiation Lightsource
journal, April 2012

  • Sokaras, D.; Nordlund, D.; Weng, T. -C.
  • Review of Scientific Instruments, Vol. 83, Issue 4
  • DOI: 10.1063/1.4704458

A multi-crystal wavelength dispersive x-ray spectrometer
journal, July 2012

  • Alonso-Mori, Roberto; Kern, Jan; Sokaras, Dimosthenis
  • Review of Scientific Instruments, Vol. 83, Issue 7
  • DOI: 10.1063/1.4737630

High-pressure spectroscopic study of siderite (FeCO 3 ) with a focus on spin crossover
journal, November 2015

  • Cerantola, Valerio; McCammon, Catherine; Kupenko, Ilya
  • American Mineralogist, Vol. 100, Issue 11-12
  • DOI: 10.2138/am-2015-5319

The deep carbon cycle and melting in Earth's interior
journal, September 2010


X-ray Raman scattering study of MgSiO3 glass at high pressure: Implication for triclustered MgSiO3 melt in Earth's mantle
journal, June 2008

  • Lee, S. K.; Lin, J. -F.; Cai, Y. Q.
  • Proceedings of the National Academy of Sciences, Vol. 105, Issue 23
  • DOI: 10.1073/pnas.0802667105

LAMBDA — Large Area Medipix3-Based Detector Array
journal, November 2012


A diamond anvil cell for x-ray fluorescence measurements of trace elements in fluids at high pressure and high temperature
journal, March 2009

  • Petitgirard, Sylvain; Daniel, Isabelle; Dabin, Yves
  • Review of Scientific Instruments, Vol. 80, Issue 3
  • DOI: 10.1063/1.3100202

Pressure induced spin transition revealed by iron M 2,3 -edge spectroscopy
journal, June 2014

  • Nyrow, Alexander; Tse, John S.; Hiraoka, Nozomu
  • Applied Physics Letters, Vol. 104, Issue 26
  • DOI: 10.1063/1.4886971

Multiple-element spectrometer for non-resonant inelastic X-ray spectroscopy of electronic excitations
journal, June 2009

  • Verbeni, Roberto; Pylkkänen, Tuomas; Huotari, Simo
  • Journal of Synchrotron Radiation, Vol. 16, Issue 4
  • DOI: 10.1107/S090904950901886X

Silicate Perovskite
journal, May 1992


Spin-polarized photoelectron diffraction
journal, April 1985


Bulk sensitive determination of the Fe 3+ /Fe Tot -ratio in minerals by Fe L 2/3 -edge X-ray Raman scattering
journal, January 2016

  • Nyrow, Alexander; Sternemann, Christian; Tse, John S.
  • Journal of Analytical Atomic Spectrometry, Vol. 31, Issue 3
  • DOI: 10.1039/C5JA00261C

Chemical dependence of interatomic X-ray transition energies and intensities – a study of Mn Kβ″ and Kβ2,5 spectra
journal, March 1999


Direct tomography with chemical-bond contrast
journal, May 2011

  • Huotari, Simo; Pylkkänen, Tuomas; Verbeni, Roberto
  • Nature Materials, Vol. 10, Issue 7
  • DOI: 10.1038/nmat3031

High-resolution manganese x-ray fluorescence spectroscopy. Oxidation-state and spin-state sensitivity
journal, April 1994

  • Peng, G.; deGroot, F. M. F.; Haemaelaeinen, K.
  • Journal of the American Chemical Society, Vol. 116, Issue 7
  • DOI: 10.1021/ja00086a024

EXAFS studies under high pressure by X-ray Raman scattering
journal, July 2016


A large-solid-angle X-ray Raman scattering spectrometer at ID20 of the European Synchrotron Radiation Facility
journal, February 2017

  • Huotari, S.; Sahle, Ch. J.; Henriquet, Ch.
  • Journal of Synchrotron Radiation, Vol. 24, Issue 2
  • DOI: 10.1107/S1600577516020579

    Works referencing / citing this record:

    Persistent Octahedral Coordination in Amorphous GeO 2 Up to 100 GPa by K β X-Ray Emission Spectroscopy
    journal, February 2019


    Persistent Octahedral Coordination in Amorphous GeO 2 Up to 100 GPa by K β X-Ray Emission Spectroscopy
    journal, February 2019