Rhodium and cobalt carbonyl clusters Rh4(CO)12, Co2Rh2(CO)12, and Co3Rh(CO)12 as effective catalysts for hydrosilylation of isoprene, cyclohexanone, and cyclohexenone
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journal
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August 1991 |
Reactivity of Fe(CO)4(H)MPh3 (M = Si, Ge) and mechanism of substitution by two-electron-donor ligands: implications for the mechanism of hydrosilylation of olefins catalyzed by iron pentacarbonyl
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February 1989 |
Metal Silylenes Generated by Double Silicon-Hydrogen Activation: Key Intermediates in the Rhodium-Catalyzed Hydrosilylation of Ketones
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February 2009 |
Multiple Reaction Pathways in Rhodium-Catalyzed Hydrosilylations of Ketones
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October 2009 |
The action of tris(triphenylphosphine)chlororhodium on polyhydromonosilanes
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July 1973 |
Formation of Si-Si bonds from Si-H bonds in the presence of hydrosilation catalysts
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July 1987 |
Hydrosilylation of 1-hexyne catalyzed by rhodium and cobalt-rhodium mixed-metal complexes. Mechanism of apparent trans addition
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December 1990 |
Dimeric Rhodium μ-Silylene and μ-η 2 -Silyl Complexes: Catalytic Silicon−Silicon Bond Formation and X-ray Structures of [{Pr i 2 PCH 2 CH 2 PPr i 2 }Rh] 2 (μ-SiRR‘) 2 (R = R‘ = Ph and R = Me, R‘ = Ph) and [{Pr i 2 PCH 2 CH 2 PPr i 2 }Rh(H)] 2 (μ-η 2 -H−SiMe 2 ) 2 †
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March 1999 |
Catalytic Dehydrogenative Coupling of Secondary Silanes Using Wilkinson's Catalyst
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May 2001 |
Dehydrogenative coupling of primary alkyl silanes using Wilkinson's catalyst
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November 2003 |
Dehydrogenative Coupling of a Tertiary Silane Using Wilkinson's Catalyst: Dehydrogenative Coupling of a Tertiary Silane Using Wilkinson's Catalyst
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June 2016 |
The decarbonylation of aldehydes by tris(triphenylphosphine)chlororhodium(I)
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January 1968 |
Dihapto-Coordinated Amide, Ester, and Aldehyde Complexes and Their Role in Decarbonylation
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February 2005 |
Base-free nickel-catalysed decarbonylative Suzuki–Miyaura coupling of acid fluorides
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October 2018 |
Oxidative addition of aryl carboxylates to nickel(0) complexes involving cleavage of the acyl-oxygen bond
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May 1980 |
Catalytic decarbonylation of aldehydes
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October 1978 |
Acceptorless Photocatalytic Dehydrogenation for Alcohol Decarbonylation and Imine Synthesis
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July 2012 |
Extrusion of CO from Aryl Ketones: Rhodium(I)-Catalyzed CC Bond Cleavage Directed by a Pyridine Group
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February 2012 |
Rh-Catalyzed Decarbonylative Coupling with Alkynes via C–C Activation of Isatins
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January 2015 |
Decarbonylation of aromatic carbonyl compounds catalyzed by rhodium complexes
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May 1967 |
Pd-Catalyzed Decarbonylative Cross-Couplings of Aroyl Chlorides
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July 2017 |
Palladium-Catalyzed Reductive Conversion of Acyl Fluorides via Ligand-Controlled Decarbonylation
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June 2018 |
Palladium-Catalyzed Decarbonylative Trifluoromethylation of Acid Fluorides
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March 2018 |
Homogeneous decarbonylation of formate esters catalyzed by Vaska's compound
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December 1986 |
New Synthesis of Biaryls via Rh-Catalyzed Decarbonylative Suzuki-Coupling of Carboxylic Anhydrides with Arylboroxines
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December 2004 |
Decarbonylative organoboron cross-coupling of esters by nickel catalysis
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June 2015 |
Decarbonylative Cross-Couplings: Nickel Catalyzed Functional Group Interconversion Strategies for the Construction of Complex Organic Molecules
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April 2018 |
Ligand-Controlled Chemoselective C(acyl)–O Bond vs C(aryl)–C Bond Activation of Aromatic Esters in Nickel Catalyzed C(sp 2 )–C(sp 3 ) Cross-Couplings
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journal
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February 2018 |
Nickel-Catalyzed Decarbonylative Borylation of Amides: Evidence for Acyl C−N Bond Activation
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June 2016 |
Oxidative addition of the carbon-hydrogen bonds of neopentane and cyclohexane to a photochemically generated iridium(I) complex
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June 1982 |
Activation of methane by iridium complexes
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November 1983 |
Photo-activation of methane at 12 K by (η 5 -cyclopentadienyl)- and (η 5 -pentamethylcyclopentadienyl)-dicarbonyl-rhodium and -iridium complexes
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January 1984 |
Efficient and selective carbon-hydrogen activation by a tris(pyrazolylborate)rhodium complex
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July 1987 |
Understanding the factors affecting the activation of alkane by Cp'Rh(CO)2 (Cp' = Cp or Cp*)
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journal
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November 2010 |
Combined experimental and theoretical investigation into C–H activation of cyclic alkanes by Cp′Rh(CO)2 (Cp′ = η5-C5H5 or η5-C5Me5)
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journal
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January 2011 |
Transition Metal Mediated C–H Activation and Functionalization: The Role of Poly(pyrazolyl)borate and Poly(pyrazolyl)alkane Ligands
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journal
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February 2016 |
Probing the Carbon–Hydrogen Activation of Alkanes Following Photolysis of Tp′Rh(CNR)(carbodiimide): A Computational and Time-Resolved Infrared Spectroscopic Study
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January 2018 |
Photochemical C−H Bond Activation Reactivity of (HBPz‘ 3 )Rh(CO) 2 (Pz‘ = 3,5-Dimethylpyrazolyl) in Alkane Solutions
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journal
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January 1996 |
Photochemical carbonylation of benzene by iridium(I) and rhodium(I) square-planar complexes
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journal
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February 1986 |
Efficiently Catalytic C–H Activation. Direct and Mild Carbonylation of Benzene and Cyclohexane by RhCl(CO)(PMe 3 ) 2 under Irradiation
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journal
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February 1987 |
Gas-Phase Rates of Alkane C-H Oxidative Addition to a Transient CpRh(CO) Complex
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January 1992 |
Theoretical studies of inorganic and organometallic reaction mechanisms. 6. Methane activation on transient cyclopentadienylcarbonylrhodium
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journal
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August 1993 |
Ultrafast Infrared Studies of Bond Activation in Organometallic Complexes
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February 1999 |
Triplet Organometallic Reactivity under Ambient Conditions: An Ultrafast UV Pump/IR Probe Study
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March 2001 |
Carbon–Hydrogen Activation of Cycloalkanes by Cyclopentadienylcarbonylrhodium—A Lifetime Enigma
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journal
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June 2014 |
Prediction of the Reactive Intermediates in Alkane Activation by Tris(pyrazolyl borate)rhodium Carbonyl
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journal
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February 1998 |
Femtosecond IR Studies of Alkane C−H Bond Activation by Organometallic Compounds: Direct Observation of Reactive Intermediates in Room Temperature Solutions
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journal
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January 1996 |
The Mechanism of a C-H Bond Activation Reaction in Room-Temperature Alkane Solution
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journal
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October 1997 |
Probing the Mechanism of Carbon−Hydrogen Bond Activation by Photochemically Generated Hydridotris(pyrazolyl)borato Carbonyl Rhodium Complexes: New Experimental and Theoretical Investigations
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journal
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December 2007 |
Ultrafast UV Pump/IR Probe Studies of C−H Activation in Linear, Cyclic, and Aryl Hydrocarbons
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journal
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August 2002 |
Comparison of the Relative Electron-Donating Abilities of Hydridotris(pyrazolyl)borate and Cyclopentadienyl Ligands: Different Interactions with Different Transition Metals
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June 2000 |
Reactions of Tris(oxazolinyl)phenylborato Rhodium(I) with C−X (X = Cl, Br, OTf) Bonds: Stereoselective Intermolecular Oxidative Addition
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journal
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September 2010 |
Oxygen insertion reactions of mixed N-heterocyclic carbene–oxazolinylborato zinc alkyl complexes
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January 2014 |
Mixed N-Heterocyclic Carbene–Bis(oxazolinyl)borato Rhodium and Iridium Complexes in Photochemical and Thermal Oxidative Addition Reactions
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journal
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November 2014 |
Oxidative addition of trisubstituted silanes to photochemically generated coordinatively unsaturated species (.eta.4-C4H4)Fe(CO)2, (.eta.5-C5H5)Mn(CO)2, and (.eta.6-C6H6)Cr(CO)2 and related molecules
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journal
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March 1987 |
Temperature dependence of the oxidative addition of triethylsilane to photochemically generated (.eta.5-C5Cl5)Mn(CO)2
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journal
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April 1989 |
Temperature-Dependent Transitions Between Normal and Inverse Isotope Effects Pertaining to the Interaction of H−H and C−H Bonds with Transition Metal Centers
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journal
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February 2009 |
Transition metal–carbon bonds. Part XIII. Di-µ-chlorodicarbonyldi-(ethylene)dirhodium( I )
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journal
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January 1968 |
Carbon–Silicon Bond Formation in the Synthesis of Benzylic Silanes
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April 2016 |
The First Structural Characterisation of a Group 2 Metal Alkylperoxide Complex: Comments on the Cleavage of Dioxygen by Magnesium Alkyl Complexes
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October 2003 |