Chalcogenide nanowires by evaporation-condensation

Journal Article · Wed Feb 02 04:00:00 EST 2005 · Journal of Non-crystalline Solids, 351 :1410–1416

DOI:https://doi.org/10.1016/j.jnoncrysol.2005.02.018· OSTI ID:15020669

Johnson, Bradley R; Schweiger, Michael J; Sundaram, S K

Chalcogenide (arsenic sulfide) nanowires have been successfully synthesized from As2S3 under near-equilibrium conditions via evaporation-condensation process in evacuated glass ampoules. The as-synthesized nanowires were pure, nearly stoichiometric, and amorphous. The nanowires had diameters ranging from 40 to 140 nm and lengths up to a few millimeters. Distinct joints of the crisscrossing nanowires indicate potential for forming structural networks. They have been characterized using scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive spectroscopy (EDS), Raman spectroscopy, and X-ray diffraction (XRD) to determine their structure, composition, and morphology. Selected area diffraction (SAD) in the TEM and XRD confirmed their amorphous nature. The As-S nanowires could make an ideal system for understanding the carrier transport and photonic properties in nanoscale for this family of materials (IV-V compounds). Chalcogenide nanowires show promise for integrated nanoelectronics and biophotonics.

• Research Organization: Pacific Northwest National Laboratory (PNNL), Richland, WA (US), Environmental Molecular Sciences Laboratory (EMSL)
• Sponsoring Organization: USDOE
• DOE Contract Number: AC05-76RL01830
• OSTI ID: 15020669
• Report Number(s): PNNL-SA-45846; 2526; NN2001000
• Journal Information: Journal of Non-crystalline Solids, 351 :1410–1416, Journal Name: Journal of Non-crystalline Solids, 351 :1410–1416
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
ARSENIC SULFIDES
CHALCOGENIDES
Chalcogenide
EVAPORATION
Environmental Molecular Sciences Laboratory
FABRICATION
NANOSTRUCTURES
VAPOR CONDENSATION
WIRES
nanowires