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Synthesis and Electrochemical Properties of Single-Crystal V{sub 2}O{sub 5} Nanorod Arrays by Template-Based Electrodeposition

Journal Article · · Journal of Physical Chemistry B
DOI:https://doi.org/10.1021/jp0491820· OSTI ID:15010696
This paper reports a study on template-growth and electrochemical properties of single-crystal vanadium pentoxide (V{sub 2}O{sub 5}) nanorod arrays from V{sub 2}O{sub 5} aqueous solution using electrochemical deposition. Uniformly sized vanadium oxide nanorods with a length of about 10 {micro}m with diameters ranging from 100 to 200 nm were grown over a large area with near unidirectional alignment. These nanorods have single-crystalline structure with a growth direction of [010]. Electrochemical property analysis indicates that nanorod array electrodes have significantly higher current density and energy storage density than sol-gel-derived V{sub 2}O{sub 5} films.
Research Organization:
Pacific Northwest National Lab., Richland, WA (US), Environmental Molecular Sciences Laboratory (US)
Sponsoring Organization:
US Department of Energy (US)
DOE Contract Number:
AC05-76RL01830
OSTI ID:
15010696
Report Number(s):
PNNL-SA-42877; 5120; KP1301030
Journal Information:
Journal of Physical Chemistry B, Journal Name: Journal of Physical Chemistry B Journal Issue: 28 Vol. 108
Country of Publication:
United States
Language:
English

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