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Title: Chemical Processing in High-Pressure Aqueous Environments. 7. Process Development for Catalytic Gasification of Wet Biomass Feedstocks

Journal Article · · Industrial and Engineering Chemistry Research
DOI:https://doi.org/10.1021/ie034303o· OSTI ID:15007897

Through the use of a metal catalyst, gasification of wet biomass can be accomplished with high levels of carbon conversion to gas at relatively low temperature (350 C). In the pressurized-water environment (20 MPa) near-total conversion of the organic structure of biomass to gases has been accomplished in the presence of a ruthenium metal catalyst. The process is essentially steam reforming as there is no added oxidizer or reagent other than water. In addition, the gas produced is a medium-heating value gas due to the synthesis of high-levels of methane, as dictated by thermodynamic equilibrium. Biomass trace components cause processing difficulties using the fixed catalyst bed tubular reactor system. Results are described for both bench-scale and scaled-up reactor systems.

Research Organization:
Pacific Northwest National Lab., Richland, WA (US), Environmental Molecular Sciences Lab. (US)
Sponsoring Organization:
US Department of Energy (US)
DOE Contract Number:
AC06-76RL01830
OSTI ID:
15007897
Report Number(s):
PNNL-SA-40279; 5894; BM0101010; TRN: US200423%%97
Journal Information:
Industrial and Engineering Chemistry Research, Vol. 43, Issue 9; Other Information: PBD: 1 Jul 2004
Country of Publication:
United States
Language:
English