Experimental Studies of Light-Induced Changes in Long-Ranged Disorder in Amorphous Silicon: Final Subcontract Report, 14 May 1999--31 August 2003

Technical Report · Tue Jun 01 00:00:00 EDT 2004

DOI:https://doi.org/10.2172/15007848· OSTI ID:15007848

Kakalios, J

The principal objective of the proposed research is the experimental study and elucidation of the role that long-ranged disorder plays in the light-induced metastable conductance changes in hydrogenated amorphous silicon (a-Si:H). The development of sources of low-cost renewable electrical energy is a high national priority. A consensus has developed that a-Si:H is the material of choice for large-area photovoltaic devices. However, the efficiency of a-Si:H-based solar cells decreases by nearly a factor of two following extended illumination, owing to the creation of light-induced defects resulting from the recombination of photo-excited charge carriers. If this light-induced defect formation could be reduced or eliminated, the practical conversion-efficiency of a-Si:H-based solar cells would effectively double, yielding cost per kilowatt-hour values comparable to that of conventional fossil fuel generation of electricity. Recent experimental results and theoretical calculations indicate that associated with light-induced dangling-bond creation, there are alterations in the medium- and long-ranged disorder in the a-Si:H films. A determination of whether or not the long-ranged disorder is affected in the Staebler-Wronski effect is important, for if so, then even when local defect generation is prevented, there could still remain metastable conductance changes that would affect photovoltaic device performance. Alternatively, if experimental studies clearly rule out light-induced changes in the long-ranged order in the a-Si:H film, then entire classes of models for the Staebler-Wronski effect can be eliminated from consideration. The results from this project indicate that the metastable conductance changes associated with the Staebler-Wronski effect can be understood solely in terms of models that involve only local changes in bonding coordination. Attempts to understand or control this phenomenon by altering the long-ranged disorder will not be fruitful.

• Research Organization: National Renewable Energy Lab., Golden, CO (US)
• Sponsoring Organization: US Department of Energy (US)
• DOE Contract Number: AC36-99GO10337
• OSTI ID: 15007848
• Report Number(s): NREL/SR-520-36095; AAD-9-18668-13
• Country of Publication: United States
• Language: English

Related Subjects

14 SOLAR ENERGY
29 ENERGY PLANNING, POLICY, AND ECONOMY
36 MATERIALS SCIENCE
BONDING
CHARGE CARRIERS
DEFECTS
DEVICE
EFFICIENCY
ELECTRICITY
FOSSIL FUELS
HYDROGENATED AMORPHOUS SILICON (A-SI:H)
ILLUMINANCE
LIGHT-INDUCED
METASTABLE CONDUCTANCE
PERFORMANCE
PHOTOCONDUCTIVITY
PV
RECOMBINATION
SILICON
SILICON MATERIALS AND DEVICES
SOLAR CELLS
STAEBLER-WRONSKI EFFECT
THERMOPOWER ACTIVATION ENERGY
THIN FILM
TRANSMISSION ELECTRON MICROGRAPH