Inelastic neutron scattering studies of TbNiAlH1.4and UNiAlH2.0hydrides

Bordallo, H. N.; Kolesnikov, A. I.; Kolomiets, A. V.; Kalceff, W.; Nakotte, H.; Eckert, J.

doi:10.1088/0953-8984/15/17/310

Title: Inelastic neutron scattering studies of TbNiAlH_1.4and UNiAlH_2.0hydrides

Journal Article · Tue Apr 22 00:00:00 EDT 2003 · Journal of Physics. Condensed Matter

DOI:https://doi.org/10.1088/0953-8984/15/17/310· OSTI ID:15004071

Bordallo, H. N.; Kolesnikov, A. I.; Kolomiets, A. V.; Kalceff, W.; Nakotte, H.; Eckert, J.

The optical vibrations of hydrogen in TbNiAlH{sub 1.4} and UNiAlH{sub 2.0} were investigated by means of inelastic neutron scattering. The experimental data were analysed, including multiphonon neutron scattering contributions, calculated in an isotropic harmonic approximation. At least two fundamental H optical peaks were observed in TbNiAlH{sub 1.4}, and were assigned to the vibrational modes of hydrogen atoms occupying different interstitial sites in the metal sublattice. The high-energy part of the UNiAlH{sub 2.0} spectra is characterized by strong anharmonicity, and a broad fundamental band. The latter can be accounted for by a large dispersion of phonon modes due to the strong H-H interactions, and/or different metal-hydrogen force constants, which may originate from different metal atoms surrounding the H atoms in the unit cell.

Cite

Export

Save

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: W-31-109-ENG-38

OSTI ID:: 15004071

Journal Information:: Journal of Physics. Condensed Matter, Vol. 15, Issue 17; ISSN 0953-8984

Publisher:: IOP Publishing

Country of Publication:: United States

Language:: English

References (21)

Magnetic structure study of ErCuAl and ErNiAl Javorský, P.; Burlet, P.; Ressouche, E. Physica B: Condensed Matter, Vol. 225, Issue 3-4 https://doi.org/10.1016/0921-4526(96)00269-4	journal	July 1996
Neutron diffraction study of magnetic structures in TbNiAl Javorský, P.; Burlet, P.; Sechovský, V. Journal of Magnetism and Magnetic Materials, Vol. 166, Issue 1-2 https://doi.org/10.1016/S0304-8853(96)00434-9	journal	February 1997
Electronic properties of UNiAl in high magnetic fields Brück, E.; Nakotte, H.; de Boer, F. R. Physical Review B, Vol. 49, Issue 13 https://doi.org/10.1103/PhysRevB.49.8852	journal	April 1994
Hydrogen absorption–desorption, crystal structure and magnetism in RENiAl intermetallic compounds and their hydrides Kolomiets, A. V.; Havela, L.; Yartys, V. A. Journal of Alloys and Compounds, Vol. 253-254 https://doi.org/10.1016/S0925-8388(97)02982-4	journal	May 1997
H1NMR and magnetic susceptibility study ofThNiAlHxandUNiAlHx Zogal, O. J.; Lam, D. J.; Zygmunt, A. Physical Review B, Vol. 29, Issue 9 https://doi.org/10.1103/PhysRevB.29.4837	journal	May 1984
Magnetic properties and crystal structure of HoNiAl and UNiAl hydrides Kolomiets, A. V.; Havela, L.; Rafaja, D. Journal of Applied Physics, Vol. 87, Issue 9 https://doi.org/10.1063/1.372851	journal	May 2000
Structure and magnetic properties of TbNiAl-based deuterides Brinks, H. W.; Yartys, V. A.; Hauback, B. C. Journal of Alloys and Compounds, Vol. 330-332 https://doi.org/10.1016/S0925-8388(01)01644-9	journal	January 2002
Hydride phases, structure, and magnetic properties of theUNiAlHysystem Raj, P.; Shashikala, K.; Sathyamoorthy, A. Physical Review B, Vol. 63, Issue 9 https://doi.org/10.1103/PhysRevB.63.094414	journal	February 2001
Neutron scattering lengths and cross sections Sears, Varley F. Neutron News, Vol. 3, Issue 3 https://doi.org/10.1080/10448639208218770	journal	January 1992
Properties of UNiAlD2.1 and UNiAlH2.3 Bordallo, H. N.; Nakotte, H.; Kolomiets, A. V. Physica B: Condensed Matter, Vol. 276-278 https://doi.org/10.1016/S0921-4526(99)01810-4	journal	March 2000
Deuterium absorption properties and crystal structure of UNiAl Yamamoto, T.; Ishii, Y.; Kayano, H. Journal of Alloys and Compounds, Vol. 269, Issue 1-2 https://doi.org/10.1016/S0925-8388(98)00221-7	journal	May 1998
Structure and magnetic studies on UNiAlD2.2 Raj, P.; Shashikala, K.; Sathyamoorthy, A. Journal of Applied Physics, Vol. 89, Issue 11 https://doi.org/10.1063/1.1361262	journal	June 2001
Deconvolution of data from the filter difference spectrometer: from hardware to maximum entropy Sivia, D. S.; Vorderwisch, P.; Silver, R. N. Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 290, Issue 2-3 https://doi.org/10.1016/0168-9002(90)90568-Q	journal	May 1990
Hydrogen sorption properties of intermetallic TbNiAl and crystal structure of TbNiAlD1.1 Yartys, V. A.; Gingl, F.; Yvon, K. Journal of Alloys and Compounds, Vol. 279, Issue 2 https://doi.org/10.1016/S0925-8388(97)00610-5	journal	October 1998
Crystal and magnetic structure of TbNiAl-based deuterides, TbNiAlD0.30 and TbNiAlD1.04, studied by neutron diffraction and synchrotron radiation Hauback, B. C.; Fjellvåg, H.; Pålhaugen, L. Journal of Alloys and Compounds, Vol. 293-295 https://doi.org/10.1016/S0925-8388(99)00417-X	journal	December 1999
Hydrogen-induced changes in TbNiAl Bordallo, H. N.; Nakotte, H.; Eckert, J. Journal of Applied Physics, Vol. 83, Issue 11 https://doi.org/10.1063/1.367693	journal	June 1998
Structure and lattice dynamics of titanium hydrides due to thermobaric treatment Bashkin, I. O.; Kolesnikov, A. I.; Ponyatovsky, E. G. High Pressure Research, Vol. 14, Issue 1-3 https://doi.org/10.1080/08957959508200907	journal	October 1995
A new type of three-phonon complexes (triphonons) Agranovich, V. M.; Dubovskii, O. A.; Orlov, A. V. Physics Letters A, Vol. 119, Issue 2 https://doi.org/10.1016/0375-9601(86)90419-6	journal	December 1986
Strong anharmonicity effects for vibrations in crystals with impurities: local biphonons and triphonons Agranovich, V. M.; Dubovsky, O. A. International Reviews in Physical Chemistry, Vol. 5, Issue 2-3 https://doi.org/10.1080/01442358609353368	journal	January 1986
Dispersion of excited triphonons in crystals of various types Agranovich, V. M.; Dubovsky, O. A.; Orlov, A. V. Solid State Communications, Vol. 70, Issue 6 https://doi.org/10.1016/0038-1098(89)90371-2	journal	May 1989
Strong anisotropy in the inelastic neutron scattering from PdH at high energy transfer Ross, D. K.; Antonov, V. E.; Bokhenkov, E. L. Physical Review B, Vol. 58, Issue 5 https://doi.org/10.1103/PhysRevB.58.2591	journal	August 1998

Similar Records

Neutron vibrational spectroscopic evidence for short H∙∙∙H contacts in the RNiInH_{1.4; 1.6} (R = Ce, La) metal hydride

Journal Article · Tue Feb 15 00:00:00 EST 2022 · Journal of Alloys and Compounds · OSTI ID:15004071

Klein, Ryan A.; Balderas-Xicohténcatl, Rafael; Maehlen, Jan Petter; +7 more

Isotopic dependence of the frequency of optical vibrations in molybdenum monohydride

Journal Article · Sun Oct 10 00:00:00 EDT 2021 · Journal of Alloys and Compounds · OSTI ID:15004071

Kuzovnikov, Mikhail A.; Antonov, Vladimir E.; Hansen, Thomas; +6 more

Crystal chemistry and thermodynamic properties of anisotropic Ce{sub 2}Ni{sub 7}H{sub 4.7} hydride

Journal Article · Sat Sep 15 00:00:00 EDT 2007 · Journal of Solid State Chemistry · OSTI ID:15004071

Denys, R V; Sato, Masashi; Riabov, A B; +1 more

Related Subjects

08 HYDROGEN
ATOMS
HARMONICS
HYDRIDES
HYDROGEN
INTERSTITIALS
NEUTRONS
PHONONS
SCATTERING
SPECTRA
intense pulsed neutron source

Title: Inelastic neutron scattering studies of TbNiAlH1.4and UNiAlH2.0hydrides

Citation Formats

References (21)

Similar Records

Related Subjects

Title: Inelastic neutron scattering studies of TbNiAlH_1.4and UNiAlH_2.0hydrides