Harnessing solvent effects to integrate alkylamine into metal–organic frameworks for exceptionally high CO 2 uptake

Li, Hao; Wang, Kecheng; Hu, Zhigang; Chen, Ying-Pin; Verdegaal, Wolfgang; Zhao, Dan; Zhou, Hong-Cai

doi:10.1039/C8TA11300A

Title: Harnessing solvent effects to integrate alkylamine into metal–organic frameworks for exceptionally high CO ₂ uptake

Journal Article · Tue Mar 26 00:00:00 EDT 2019 · Journal of Materials Chemistry. A

DOI:https://doi.org/10.1039/C8TA11300A· OSTI ID:1499827

Li, Hao ^[1]; Wang, Kecheng ^[1];

^[2]; Chen, Ying-Pin ^[3]; Verdegaal, Wolfgang ^[4];

^[2];

^[3]

Department of Chemistry, Texas A&M University, College Station, USA
Department of Chemical and Biomolecular Engineering, National University of Singapore, Singapore
Department of Chemistry, Texas A&M University, College Station, USA, Department of Materials Science and Engineering
Profusa, Inc., South San Francisco, USA

Alkylamine modified MOF prepared with a less polar solvent (cyclohexane) has a higher alkylamine loading amount and higher CO ₂ uptake than when prepared in a more polar solvent (dichloromethane).

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Sponsoring Organization:: USDOE Office of Fossil Energy and Carbon Management (FECM)

Grant/Contract Number:: FE0026472; SC0001015

OSTI ID:: 1499827

Journal Information:: Journal of Materials Chemistry. A, Journal Name: Journal of Materials Chemistry. A Vol. 7 Journal Issue: 13; ISSN 2050-7488

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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Cited by: 32 works

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