Unraveling the Interfacial Structure–Performance Correlation of Flexible Metal–Organic Framework Membranes on Polymeric Substrates

Hou, Jingwei; Sutrisna, Putu D.; Wang, Tiesheng; Gao, Song; Li, Qi; Zhou, Chao; Sun, Shijing; Yang, Hao-Cheng; Wei, Fengxia; Ruggiero, Michael T.; Zeitler, J. Axel; Cheetham, Anthony K.; Liang, Kang; Chen, Vicki

doi:10.1021/acsami.8b20570

Unraveling the Interfacial Structure–Performance Correlation of Flexible Metal–Organic Framework Membranes on Polymeric Substrates

Journal Article · Thu Jan 10 00:00:00 EST 2019 · ACS Applied Materials and Interfaces

DOI:https://doi.org/10.1021/acsami.8b20570· OSTI ID:1499805

; Sutrisna, Putu D.; ; Gao, Song; Li, Qi; ; Sun, Shijing ^[1]; Yang, Hao-Cheng ^[2]; Wei, Fengxia; ^[3]; ; ; ; Chen, Vicki ^[4]

Department of Mechanical Engineering, Massachusetts Institute of Technology, Cambridge 02139, Massachusetts, United States
School of Chemical Engineering and Technology, Sun Yat-Sen University, Zhuhai 519082, China
Department of Chemistry, University of Vermont, Burlington 05405, United States
School of Chemical Engineering, University of Queensland, St Lucia 4072, Australia

Pure metal–organic framework (MOF) layers deposited on porous supports are important candidates for molecular sieving membranes, but their performance usually deviates from theoretical estimations. Here, we combine stepwise scanning electron microscopy imaging, time-resolved synchrotron X-ray scattering, terahertz infrared spectroscopy, and density functional theory calculation to investigate the ZIF-8 membrane formation on two types (polydopamine and TiO2) of functionalized porous supports. Though molecular sieving of ZIF-8 membranes for smaller gases (He, H₂, and CO₂) can be achieved with both types of functionalized supports, we unravel that the strong interaction between MOF and polydopamine can disrupt the formation of “perfect” MOF crystals at the interface, leading to a “contracted” MOF structure with partially uncoordinated imidazolate ligands. This further affects the low-frequency dynamical parameters of the framework and inhibits the effective seeded growth. Eventually, it leads to an unexpected loss of selectivity for the bulkier gases (N₂ and CH₄) for ZIF-8 on polydopamine-functionalized supports. This work links the dynamical aspects of MOFs with their gas transport behavior and highlights the importance of regulating the interfacial weak forces to preserve the ideal molecular sieving efficiency of MOF membranes, which a

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: Australian Research Council (ARC); China Scholarship Council (CSC); Engineering and Physical Sciences Research Council (EPSRC); UNSW Scientia Fellowship

OSTI ID:: 1499805

Journal Information:: ACS Applied Materials and Interfaces, Journal Name: ACS Applied Materials and Interfaces Journal Issue: 5 Vol. 11; ISSN 1944-8244

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: ENGLISH

References (66)

Fluidic Processing of High-Performance ZIF-8 Membranes on Polymeric Hollow Fibers: Mechanistic Insights and Microstructure Control Eum, Kiwon; Rownaghi, Ali; Choi, Dalsu Advanced Functional Materials, Vol. 26, Issue 28 https://doi.org/10.1002/adfm.201601550	journal	June 2016
Dopamine: Just the Right Medicine for Membranes Yang, Hao-Cheng; Waldman, Ruben Z.; Wu, Ming-Bang Advanced Functional Materials, Vol. 28, Issue 8 https://doi.org/10.1002/adfm.201705327	journal	January 2018
Janus Membranes: Creating Asymmetry for Energy Efficiency Yang, Hao-Cheng; Xie, Yunsong; Hou, Jingwei Advanced Materials, Vol. 30, Issue 43 https://doi.org/10.1002/adma.201801495	journal	July 2018
Ligand-Directed Strategy for Zeolite-Type Metal–Organic Frameworks: Zinc(II) Imidazolates with Unusual Zeolitic Topologies Huang, Xiao-Chun; Lin, Yan-Yong; Zhang, Jie-Peng Angewandte Chemie International Edition, Vol. 45, Issue 10, p. 1557-1559 https://doi.org/10.1002/anie.200503778	journal	February 2006
Nanoporous Nanorods Fabricated by Coordination Modulation and Oriented Attachment Growth Tsuruoka, Takaaki; Furukawa, Shuhei; Takashima, Yohei Angewandte Chemie International Edition, Vol. 48, Issue 26 https://doi.org/10.1002/anie.200901177	journal	June 2009
Fast Nucleation and Growth of ZIF-8 Nanocrystals Monitored by Time-Resolved In Situ Small-Angle and Wide-Angle X-Ray Scattering Cravillon, Janosch; Schröder, Christian A.; Nayuk, Roman Angewandte Chemie International Edition, Vol. 50, Issue 35 https://doi.org/10.1002/anie.201102071	journal	July 2011
Defect-Engineered Metal-Organic Frameworks Fang, Zhenlan; Bueken, Bart; De Vos, Dirk E. Angewandte Chemie International Edition, Vol. 54, Issue 25 https://doi.org/10.1002/anie.201411540	journal	June 2015
Formation of Ultrathin, Continuous Metal-Organic Framework Membranes on Flexible Polymer Substrates Hou, Jingwei; Sutrisna, Putu D.; Zhang, Yatao Angewandte Chemie International Edition, Vol. 55, Issue 12 https://doi.org/10.1002/anie.201511340	journal	February 2016
Janus Membranes: Exploring Duality for Advanced Separation Yang, Hao-Cheng; Hou, Jingwei; Chen, Vicki Angewandte Chemie International Edition, Vol. 55, Issue 43 https://doi.org/10.1002/anie.201601589	journal	June 2016
Polystyrene Sulfonate Threaded through a Metal-Organic Framework Membrane for Fast and Selective Lithium-Ion Separation Guo, Yi; Ying, Yulong; Mao, Yiyin Angewandte Chemie International Edition, Vol. 55, Issue 48 https://doi.org/10.1002/anie.201607329	journal	November 2016
A Metal Chelating Porous Polymeric Support: The Missing Link for a Defect-Free Metal-Organic Framework Composite Membrane Barankova, Eva; Tan, Xiaoyu; Villalobos, Luis Francisco Angewandte Chemie International Edition, Vol. 56, Issue 11 https://doi.org/10.1002/anie.201611927	journal	February 2017
Molecular Mechanism of Swing Effect in Zeolitic Imidazolate Framework ZIF‐8: Continuous Deformation upon Adsorption Coudert, François‐Xavier ChemPhysChem, Vol. 18, Issue 19 https://doi.org/10.1002/cphc.201700463	journal	August 2017
Quantum-mechanical condensed matter simulations with CRYSTAL Dovesi, Roberto; Erba, Alessandro; Orlando, Roberto Wiley Interdisciplinary Reviews: Computational Molecular Science, Vol. 8, Issue 4 https://doi.org/10.1002/wcms.1360	journal	March 2018
The M06 suite of density functionals for main group thermochemistry, thermochemical kinetics, noncovalent interactions, excited states, and transition elements: two new functionals and systematic testing of four M06-class functionals and 12 other functionals Zhao, Yan; Truhlar, Donald G. Theoretical Chemistry Accounts, Vol. 120, Issue 1-3 https://doi.org/10.1007/s00214-007-0310-x	journal	July 2007
Metal-Organic Frameworks for Energy Applications Wang, Hailong; Zhu, Qi-Long; Zou, Ruqiang Chem, Vol. 2, Issue 1 https://doi.org/10.1016/j.chempr.2016.12.002	journal	January 2017
Numerical and experimental study on ultrasonic vibration-assisted micro-channelling of glasses using an abrasive slurry jet Qi, Huan; Wen, Donghui; Lu, Congda International Journal of Mechanical Sciences, Vol. 110 https://doi.org/10.1016/j.ijmecsci.2016.03.013	journal	May 2016
Metal-Organic-Framework-Based Materials as Platforms for Renewable Energy and Environmental Applications Zhang, Huabin; Nai, Jianwei; Yu, Le Joule, Vol. 1, Issue 1 https://doi.org/10.1016/j.joule.2017.08.008	journal	September 2017
The upper bound revisited Robeson, Lloyd M. Journal of Membrane Science, Vol. 320, Issue 1-2, p. 390-400 https://doi.org/10.1016/j.memsci.2008.04.030	journal	July 2008
Interfacial synthesis of ZIF-8 membranes with improved nanofiltration performance Li, Yanbo; Wee, Lik H.; Martens, Johan A. Journal of Membrane Science, Vol. 523 https://doi.org/10.1016/j.memsci.2016.09.065	journal	February 2017
Improved operational stability of Pebax-based gas separation membranes with ZIF-8: A comparative study of flat sheet and composite hollow fibre membranes Sutrisna, Putu Doddy; Hou, Jingwei; Li, Hongyu Journal of Membrane Science, Vol. 524 https://doi.org/10.1016/j.memsci.2016.11.048	journal	February 2017
Colloidal heterostructured nanocrystals: Synthesis and growth mechanisms Carbone, Luigi; Cozzoli, P. Davide Nano Today, Vol. 5, Issue 5 https://doi.org/10.1016/j.nantod.2010.08.006	journal	January 2010
Numerical investigation on particle impact erosion in ultrasonic-assisted abrasive slurry jet micro-machining of glasses Qi, Huan; Wen, Donghui; Yuan, Qiaoling Powder Technology, Vol. 314 https://doi.org/10.1016/j.powtec.2016.08.057	journal	June 2017
How Reproducible Are Isotherm Measurements in Metal–Organic Frameworks? Park, Jongwoo; Howe, Joshua D.; Sholl, David S. Chemistry of Materials, Vol. 29, Issue 24 https://doi.org/10.1021/acs.chemmater.7b04287	journal	November 2017
Ionic Current Rectification in a Conical Nanopore: Influences of Electroosmotic Flow and Type of Salt Hsu, Jyh-Ping; Yang, Shu-Tuan; Lin, Chih-Yuan The Journal of Physical Chemistry C, Vol. 121, Issue 8 https://doi.org/10.1021/acs.jpcc.6b09907	journal	February 2017
In Situ Observation of Gas Adsorption onto ZIF-8 Using Terahertz Waves Tanno, Takenori; Watanabe, Yutaro; Umeno, Kyoko The Journal of Physical Chemistry C, Vol. 121, Issue 33 https://doi.org/10.1021/acs.jpcc.7b04833	journal	August 2017
Effect of Solvent and Substrate on the Surface Binding Mode of Carboxylate-Functionalized Aromatic Molecules Domenico, Janna; Foster, Michael E.; Spoerke, Erik D. The Journal of Physical Chemistry C, Vol. 122, Issue 20 https://doi.org/10.1021/acs.jpcc.8b01526	journal	April 2018
Structural Contraction of Zeolitic Imidazolate Frameworks: Membrane Application on Porous Metallic Hollow Fibers for Gas Separation Cacho-Bailo, Fernando; Etxeberría-Benavides, Miren; David, Oana ACS Applied Materials & Interfaces, Vol. 9, Issue 24 https://doi.org/10.1021/acsami.7b05497	journal	June 2017
Hydrogen Bonding and π-Stacking: How Reliable are Force Fields? A Critical Evaluation of Force Field Descriptions of Nonbonded Interactions Paton, Robert S.; Goodman, Jonathan M. Journal of Chemical Information and Modeling, Vol. 49, Issue 4 https://doi.org/10.1021/ci900009f	journal	March 2009
Controlling Zeolitic Imidazolate Framework Nano- and Microcrystal Formation: Insight into Crystal Growth by Time-Resolved In Situ Static Light Scattering Cravillon, Janosch; Nayuk, Roman; Springer, Sergej Chemistry of Materials, Vol. 23, Issue 8 https://doi.org/10.1021/cm103571y	journal	April 2011
Oriented Zeolitic Imidazolate Framework-8 Membrane with Sharp H ₂ /C ₃ H ₈ Molecular Sieve Separation Bux, Helge; Feldhoff, Armin; Cravillon, Janosch Chemistry of Materials, Vol. 23, Issue 8 https://doi.org/10.1021/cm200555s	journal	April 2011
Supramolecular Coordination: Self-Assembly of Finite Two- and Three-Dimensional Ensembles Chakrabarty, Rajesh; Mukherjee, Partha Sarathi; Stang, Peter J. Chemical Reviews, Vol. 111, Issue 11, p. 6810-6918 https://doi.org/10.1021/cr200077m	journal	November 2011
Structural Evolution of Zeolitic Imidazolate Framework-8 Venna, Surendar R.; Jasinski, Jacek B.; Carreon, Moises A. Journal of the American Chemical Society, Vol. 132, Issue 51 https://doi.org/10.1021/ja109268m	journal	December 2010
Bio-Inspired Polydopamine: A Versatile and Powerful Platform for Covalent Synthesis of Molecular Sieve Membranes Liu, Qian; Wang, Nanyi; Caro, Jürgen Journal of the American Chemical Society, Vol. 135, Issue 47 https://doi.org/10.1021/ja4080562	journal	November 2013
Bicontinuous Zeolitic Imidazolate Framework ZIF-8@GO Membrane with Enhanced Hydrogen Selectivity Huang, Aisheng; Liu, Qian; Wang, Nanyi Journal of the American Chemical Society, Vol. 136, Issue 42 https://doi.org/10.1021/ja5083602	journal	October 2014
Highly Water-Stable Zirconium Metal–Organic Framework UiO-66 Membranes Supported on Alumina Hollow Fibers for Desalination Liu, Xinlei; Demir, Nilay Keser; Wu, Zhentao Journal of the American Chemical Society, Vol. 137, Issue 22 https://doi.org/10.1021/jacs.5b02276	journal	June 2015
High-Pressure Chemistry of a Zeolitic Imidazolate Framework Compound in the Presence of Different Fluids Im, Junhyuck; Yim, Narae; Kim, Jaheon Journal of the American Chemical Society, Vol. 138, Issue 36 https://doi.org/10.1021/jacs.6b07374	journal	September 2016
Elucidating Negative Thermal Expansion in MOF-5 Lock, Nina; Wu, Yue; Christensen, Mogens The Journal of Physical Chemistry C, Vol. 114, Issue 39 https://doi.org/10.1021/jp103212z	journal	September 2010
Unexpected Molecular Sieving Properties of Zeolitic Imidazolate Framework-8 Zhang, Chen; Lively, Ryan P.; Zhang, Ke The Journal of Physical Chemistry Letters, Vol. 3, Issue 16 https://doi.org/10.1021/jz300855a	journal	July 2012
Exploring the Framework Hydrophobicity and Flexibility of ZIF-8: From Biofuel Recovery to Hydrocarbon Separations Zhang, Ke; Lively, Ryan P.; Zhang, Chen The Journal of Physical Chemistry Letters, Vol. 4, Issue 21 https://doi.org/10.1021/jz402019d	journal	October 2013
Metal–organic frameworks for membrane-based separations Denny, Michael S.; Moreton, Jessica C.; Benz, Lauren Nature Reviews Materials, Vol. 1, Issue 12 https://doi.org/10.1038/natrevmats.2016.78	journal	November 2016
Interplay between defects, disorder and flexibility in metal-organic frameworks Bennett, Thomas D.; Cheetham, Anthony K.; Fuchs, Alain H. Nature Chemistry, Vol. 9, Issue 1 https://doi.org/10.1038/nchem.2691	journal	December 2016
Soft porous crystals Horike, Satoshi; Shimomura, Satoru; Kitagawa, Susumu Nature Chemistry, Vol. 1, Issue 9, p. 695-704 https://doi.org/10.1038/nchem.444	journal	November 2009
Metal–organic framework-based separator for lithium–sulfur batteries Bai, Songyan; Liu, Xizheng; Zhu, Kai Nature Energy, Vol. 1, Issue 7 https://doi.org/10.1038/nenergy.2016.94	journal	June 2016
Chemical vapour deposition of zeolitic imidazolate framework thin films Stassen, Ivo; Styles, Mark; Grenci, Gianluca Nature Materials, Vol. 15, Issue 3 https://doi.org/10.1038/nmat4509	journal	December 2015
Unravelling surface and interfacial structures of a metal–organic framework by transmission electron microscopy Zhu, Yihan; Ciston, Jim; Zheng, Bin Nature Materials, Vol. 16, Issue 5 https://doi.org/10.1038/nmat4852	journal	February 2017
Ultrathin metal–organic framework membrane production by gel–vapour deposition Li, Wanbin; Su, Pengcheng; Li, Zhanjun Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-00544-1	journal	September 2017
Mechanics of metal-catecholate complexes: The roles of coordination state and metal types Xu, Zhiping Scientific Reports, Vol. 3, Issue 1 https://doi.org/10.1038/srep02914	journal	October 2013
MOF thin films: existing and future applications Shekhah, O.; Liu, J.; Fischer, R. A. Chemical Society Reviews, Vol. 40, Issue 2 https://doi.org/10.1039/c0cs00147c	journal	January 2011
A two-dimensional zeolitic imidazolate framework with a cushion-shaped cavity for CO2 adsorption Chen, Rizhi; Yao, Jianfeng; Gu, Qinfen Chemical Communications, Vol. 49, Issue 82 https://doi.org/10.1039/c3cc44342f	journal	January 2013
Polymer supported ZIF-8 membranes prepared via an interfacial synthesis method Li, Yanbo; Wee, Lik H.; Volodin, Alexander Chemical Communications, Vol. 51, Issue 5 https://doi.org/10.1039/c4cc06699e	journal	January 2015
A high performance O ₂ selective membrane based on CAU-1-NH ₂ @polydopamine and the PMMA polymer for Li–air batteries Cao, Lujie; Lv, Fucong; Liu, Ying Chemical Communications, Vol. 51, Issue 21 https://doi.org/10.1039/c4cc09281c	journal	January 2015
MOF-based electronic and opto-electronic devices Stavila, V.; Talin, A. A.; Allendorf, M. D. Chem. Soc. Rev., Vol. 43, Issue 16 https://doi.org/10.1039/c4cs00096j	journal	January 2014
Highly hydrogen permselective ZIF-8 membranes supported on polydopamine functionalized macroporous stainless-steel-nets Huang, Aisheng; Liu, Qian; Wang, Nanyi J. Mater. Chem. A, Vol. 2, Issue 22 https://doi.org/10.1039/c4ta00299g	journal	January 2014
Polydopamine-based synthesis of a zeolite imidazolate framework ZIF-100 membrane with high H ₂ /CO ₂ selectivity Wang, Nanyi; Liu, Yi; Qiao, Zhiwei Journal of Materials Chemistry A, Vol. 3, Issue 8 https://doi.org/10.1039/c4ta06763k	journal	January 2015
The synthesis, structure and electronic properties of a lead-free hybrid inorganic–organic double perovskite (MA) ₂ KBiCl ₆ (MA = methylammonium) Wei, Fengxia; Deng, Zeyu; Sun, Shijing Materials Horizons, Vol. 3, Issue 4 https://doi.org/10.1039/c6mh00053c	journal	January 2016
Functional conductive nanomaterials via polymerisation in nano-channels: PEDOT in a MOF Wang, Tiesheng; Farajollahi, Meisam; Henke, Sebastian Materials Horizons, Vol. 4, Issue 1 https://doi.org/10.1039/c6mh00230g	journal	January 2017
An updated roadmap for the integration of metal–organic frameworks with electronic devices and chemical sensors Stassen, Ivo; Burtch, Nicholas; Talin, Alec Chemical Society Reviews, Vol. 46, Issue 11 https://doi.org/10.1039/c7cs00122c	journal	January 2017
Thermal and mechanical stability of zeolitic imidazolate frameworks polymorphs Bouëssel du Bourg, Lila; Ortiz, Aurélie U.; Boutin, Anne APL Materials, Vol. 2, Issue 12 https://doi.org/10.1063/1.4904818	journal	December 2014
Exceptional chemical and thermal stability of zeolitic imidazolate frameworks Park, K. S.; Ni, Z.; Cote, A. P. Proceedings of the National Academy of Sciences, Vol. 103, Issue 27, p. 10186-10191 https://doi.org/10.1073/pnas.0602439103	journal	June 2006
Chemical structure, network topology, and porosity effects on the mechanical properties of Zeolitic Imidazolate Frameworks Tan, J. C.; Bennett, T. D.; Cheetham, A. K. Proceedings of the National Academy of Sciences, Vol. 107, Issue 22 https://doi.org/10.1073/pnas.1003205107	journal	May 2010
Accuracy of AH _n equilibrium geometries by single determinant molecular orbital theory Hariharan, P. C.; Pople, J. A. Molecular Physics, Vol. 27, Issue 1 https://doi.org/10.1080/00268977400100171	journal	January 1974
Composition, structure, and stability of RuO 2 ( 110 ) as a function of oxygen pressure Reuter, Karsten; Scheffler, Matthias Physical Review B, Vol. 65, Issue 3 https://doi.org/10.1103/physrevb.65.035406	journal	December 2001
Identifying the Role of Terahertz Vibrations in Metal-Organic Frameworks: From Gate-Opening Phenomenon to Shear-Driven Structural Destabilization Ryder, Matthew R.; Civalleri, Bartolomeo; Bennett, Thomas D. Physical Review Letters, Vol. 113, Issue 21 https://doi.org/10.1103/physrevlett.113.215502	journal	November 2014
The Cambridge Structural Database: a quarter of a million crystal structures and rising Allen, Frank H. Acta Crystallographica Section B Structural Science, Vol. 58, Issue 3 https://doi.org/10.1107/s0108768102003890	journal	May 2002
Nonepitaxial Growth of Hybrid Core-Shell Nanostructures with Large Lattice Mismatches Zhang, J.; Tang, Y.; Lee, K. Science, Vol. 327, Issue 5973 https://doi.org/10.1126/science.1184769	journal	March 2010
Defibrillation of soft porous metal-organic frameworks with electric fields Knebel, A.; Geppert, B.; Volgmann, K. Science, Vol. 358, Issue 6361 https://doi.org/10.1126/science.aal2456	journal	October 2017

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36 MATERIALS SCIENCE
ZIF-8 membrane
crystallization
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interfacial crystal structure
metal−organic frameworks
molecular sieving

Unraveling the Interfacial Structure–Performance Correlation of Flexible Metal–Organic Framework Membranes on Polymeric Substrates

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