skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Magnetostructural transitions and magnetocaloric effects in Ni 50Mn 35In 14.25B 0.75 ribbons

Abstract

The structural, thermal, and magnetic behaviors, as well as the martensitic phase transformation and related magnetocaloric response of Ni 50Mn 35In 14.25B 0.75 annealed ribbons have been investigated using room-temperature X-ray diffraction (XRD), differential scanning calorimetry (DSC), and magnetization measurements. Ni 50Mn 35In 14.25B 0.75 annealed ribbons show a sharper change in magnetization at the martensitic transition, resulting in larger magnetic entropy changes in comparison to bulk Ni 50Mn 35In 14.25B 0.75. A drastic shift in the martensitic transformation temperature (T M) of 70 K to higher temperature was observed for the annealed ribbons relative to that of the bulk (T M = 240 K). Furthermore, the results obtained for magnetic, thermal, structural, and magnetocaloric properties of annealed ribbons have been compared to those of the corresponding bulk alloys.

Authors:
ORCiD logo [1]; ORCiD logo [1];  [2]; ORCiD logo [3];  [1];  [1]; ORCiD logo [2];  [4];  [1]
  1. Southern Illinois Univ., Carbondale, IL (United States)
  2. Instituto Potosino de Investigación Cientıfica y Tecnológica A.C., San Luis Potosı (Mexico)
  3. Univ. Autónoma de Ciudad Juárez (UACJ), Chihuahua (Mexico)
  4. Louisiana State Univ., Baton Rouge, LA (United States)
Publication Date:
Research Org.:
Southern Illinois Univ., Carbondale, IL (United States); Louisiana State Univ., Baton Rouge, LA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Material Science Division; USDOE
OSTI Identifier:
1499671
Alternate Identifier(s):
OSTI ID: 1416857
Grant/Contract Number:  
FG02-06ER46291; SC0010521; FG02-13ER46946
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
AIP Advances
Additional Journal Information:
Journal Volume: 8; Journal Issue: 5; Journal ID: ISSN 2158-3226
Publisher:
American Institute of Physics (AIP)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Pandey, Sudip, Quetz, Abdiel, Ibarra-Gaytan, P. J., Sánchez-Valdés, C. F., Aryal, Anil, Dubenko, Igor, Sanchez Llamazares, Jose Luis, Stadler, Shane, and Ali, Naushad. Magnetostructural transitions and magnetocaloric effects in Ni50Mn35In14.25B0.75 ribbons. United States: N. p., 2018. Web. doi:10.1063/1.5006467.
Pandey, Sudip, Quetz, Abdiel, Ibarra-Gaytan, P. J., Sánchez-Valdés, C. F., Aryal, Anil, Dubenko, Igor, Sanchez Llamazares, Jose Luis, Stadler, Shane, & Ali, Naushad. Magnetostructural transitions and magnetocaloric effects in Ni50Mn35In14.25B0.75 ribbons. United States. doi:10.1063/1.5006467.
Pandey, Sudip, Quetz, Abdiel, Ibarra-Gaytan, P. J., Sánchez-Valdés, C. F., Aryal, Anil, Dubenko, Igor, Sanchez Llamazares, Jose Luis, Stadler, Shane, and Ali, Naushad. Fri . "Magnetostructural transitions and magnetocaloric effects in Ni50Mn35In14.25B0.75 ribbons". United States. doi:10.1063/1.5006467. https://www.osti.gov/servlets/purl/1499671.
@article{osti_1499671,
title = {Magnetostructural transitions and magnetocaloric effects in Ni50Mn35In14.25B0.75 ribbons},
author = {Pandey, Sudip and Quetz, Abdiel and Ibarra-Gaytan, P. J. and Sánchez-Valdés, C. F. and Aryal, Anil and Dubenko, Igor and Sanchez Llamazares, Jose Luis and Stadler, Shane and Ali, Naushad},
abstractNote = {The structural, thermal, and magnetic behaviors, as well as the martensitic phase transformation and related magnetocaloric response of Ni50Mn35In14.25B0.75 annealed ribbons have been investigated using room-temperature X-ray diffraction (XRD), differential scanning calorimetry (DSC), and magnetization measurements. Ni50Mn35In14.25B0.75 annealed ribbons show a sharper change in magnetization at the martensitic transition, resulting in larger magnetic entropy changes in comparison to bulk Ni50Mn35In14.25B0.75. A drastic shift in the martensitic transformation temperature (TM) of 70 K to higher temperature was observed for the annealed ribbons relative to that of the bulk (TM = 240 K). Furthermore, the results obtained for magnetic, thermal, structural, and magnetocaloric properties of annealed ribbons have been compared to those of the corresponding bulk alloys.},
doi = {10.1063/1.5006467},
journal = {AIP Advances},
issn = {2158-3226},
number = 5,
volume = 8,
place = {United States},
year = {2018},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Figures / Tables:

FIG. 1. FIG. 1. : XRD pattern for a Ni50Mn35In14.25B0.75 annealed ribbons measured at room temperature.

Save / Share:

Works referenced in this record:

Multifunctional properties related to magnetostructural transitions in ternary and quaternary Heusler alloys
journal, June 2015

  • Dubenko, Igor; Quetz, Abdiel; Pandey, Sudip
  • Journal of Magnetism and Magnetic Materials, Vol. 383
  • DOI: 10.1016/j.jmmm.2014.10.083

Microstructure and magnetocaloric effect of melt-spun Ni 52 Mn 26 Ga 22 ribbon
journal, April 2012

  • Li, Z. B.; Sánchez Llamazares, J. L.; Sánchez-Valdés, C. F.
  • Applied Physics Letters, Vol. 100, Issue 17
  • DOI: 10.1063/1.4704780

Martensitic transformation in rapidly solidified Heusler Ni49Mn39Sn12 ribbons
journal, August 2011


Giant Hall effect in Ni-Mn-In Heusler alloys
journal, September 2009


Refrigerant capacity of austenite in as-quenched and annealed Ni 51.1 Mn 31.2 In 17.7 melt spun ribbons
journal, April 2012

  • Sánchez Llamazares, J. L.; Flores-Zuñiga, H.; Sánchez-Valdes, C.
  • Journal of Applied Physics, Vol. 111, Issue 7
  • DOI: 10.1063/1.3676606

On the correct estimation of the magnetic entropy change across the magneto-structural transition from the Maxwell relation: Study of MnCoGeBx alloy ribbons
journal, February 2017

  • Quintana-Nedelcos, A.; Sánchez Llamazares, J. L.; Sánchez-Valdés, C. F.
  • Journal of Alloys and Compounds, Vol. 694
  • DOI: 10.1016/j.jallcom.2016.10.116

Large magnetic‐field‐induced strains in Ni 2 MnGa single crystals
journal, September 1996

  • Ullakko, K.; Huang, J. K.; Kantner, C.
  • Applied Physics Letters, Vol. 69, Issue 13
  • DOI: 10.1063/1.117637

Large magnetoresistance in single-crystalline Ni50Mn50−xInx alloys (x=14–16) upon martensitic transformation
journal, October 2006

  • Yu, S. Y.; Liu, Z. H.; Liu, G. D.
  • Applied Physics Letters, Vol. 89, Issue 16
  • DOI: 10.1063/1.2362581

Transition-metal-based magnetic refrigerants for room-temperature applications
journal, January 2002

  • Tegus, O.; Brück, E.; Buschow, K. H. J.
  • Nature, Vol. 415, Issue 6868
  • DOI: 10.1038/415150a

Magnetoresistance and field-induced structural transitions in Ni50Mn50−xSnx Heusler alloys
journal, February 2008

  • Khan, Mahmud; Pathak, Arjun K.; Paudel, Moti R.
  • Journal of Magnetism and Magnetic Materials, Vol. 320, Issue 3-4
  • DOI: 10.1016/j.jmmm.2007.06.016

Large magnetic entropy change in Ni50Mn50−xInx Heusler alloys
journal, June 2007

  • Pathak, Arjun Kumar; Khan, Mahmud; Dubenko, Igor
  • Applied Physics Letters, Vol. 90, Issue 26
  • DOI: 10.1063/1.2752720

Texture-induced enhancement of the magnetocaloric response in melt-spun DyNi 2 ribbons
journal, October 2013

  • Ibarra-Gaytan, P. J.; Sánchez-Valdes, C. F.; Sánchez Llamazares, J. L.
  • Applied Physics Letters, Vol. 103, Issue 15
  • DOI: 10.1063/1.4824073

Enhanced refrigerant capacity in two-phase nanocrystalline/amorphous NdPrFe 17 melt-spun ribbons
journal, May 2014

  • Sánchez-Valdés, C. F.; Ibarra-Gaytán, P. J.; Llamazares, J. L. Sánchez
  • Applied Physics Letters, Vol. 104, Issue 21
  • DOI: 10.1063/1.4879544

Magnetocaloric, thermal, and magnetotransport properties of Ni50Mn35In13.9B1.1 Heusler alloy
journal, December 2017


Giant field-induced adiabatic temperature changes in In-based off-stoichiometric Heusler alloys
journal, April 2017

  • Pandey, Sudip; Quetz, Abdiel; Aryal, Anil
  • Journal of Applied Physics, Vol. 121, Issue 13
  • DOI: 10.1063/1.4979475

Magnetocaloric effect in melt-spun MnCoGe ribbons
journal, August 2013


Magnetocaloric effect in ribbon samples of Heusler alloys Ni–Mn–M (M=In,Sn)
journal, November 2010

  • Aliev, A. M.; Batdalov, A. B.; Kamilov, I. K.
  • Applied Physics Letters, Vol. 97, Issue 21
  • DOI: 10.1063/1.3521261

Martensitic transformation in Ni 50.4 Mn 34.9 In 14.7 melt spun ribbons
journal, January 2009

  • Sánchez Llamazares, J. L.; Hernando, B.; García, C.
  • Journal of Physics D: Applied Physics, Vol. 42, Issue 4
  • DOI: 10.1088/0022-3727/42/4/045002

The giant magnetocaloric effect of optimally prepared Gd5Si2Ge2
journal, April 2003

  • Pecharsky, A. O.; Gschneidner, K. A.; Pecharsky, V. K.
  • Journal of Applied Physics, Vol. 93, Issue 8
  • DOI: 10.1063/1.1558210

Magnetic, transport, and magnetocaloric properties of boron doped Ni-Mn-In alloys
journal, May 2015

  • Pandey, S.; Quetz, A.; Rodionov, I. D.
  • Journal of Applied Physics, Vol. 117, Issue 18
  • DOI: 10.1063/1.4921052

Inverse magnetocaloric effect in ferromagnetic Ni–Mn–Sn alloys
journal, May 2005

  • Krenke, Thorsten; Duman, Eyüp; Acet, Mehmet
  • Nature Materials, Vol. 4, Issue 6
  • DOI: 10.1038/nmat1395

The effects of substituting Ag for In on the magnetoresistance and magnetocaloric properties of Ni-Mn-In Heusler alloys
journal, May 2016

  • Pandey, Sudip; Quetz, Abdiel; Aryal, Anil
  • AIP Advances, Vol. 6, Issue 5
  • DOI: 10.1063/1.4943763

    Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.