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Connecting the solution chemistry of PbI 2 and MAI: a cyclodextrin-based supramolecular approach to the formation of hybrid halide perovskites

Journal Article · · Chemical Science
DOI:https://doi.org/10.1039/C7SC05095J· OSTI ID:1499542
 [1];  [2];  [1];  [2];  [3];  [3];  [3];  [2];  [4];  [1]
  1. Istituto di Nanotecnologia CNR-Nanotec; 73100 Lecce; Italy; Dipartimento di Matematica e Fisica “E. De Giorgi”; Università del Salento
  2. Dipartimento di Chimica e Chimica Industriale; Università di Pisa; 56124 Pisa; Italy
  3. Istituto di Cristallografia; CNR-IC; 70126 Bari; Italy
  4. Istituto di Nanotecnologia CNR-Nanotec; 73100 Lecce; Italy

Cyclodextrin macrocycles are able to modify and control the solvation equilibria of hybrid perovskite components in solution by establishing supramolecular interactions.

Research Organization:
Brookhaven National Laboratory (BNL), Upton, NY (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
DOE Contract Number:
SC0012704
OSTI ID:
1499542
Report Number(s):
BNL-209546-2018-JACI
Journal Information:
Chemical Science, Journal Name: Chemical Science Journal Issue: 12 Vol. 9; ISSN 2041-6520; ISSN CSHCBM
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

References (45)

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Polymer Stabilization of Lead(II) Perovskite Cubic Nanocrystals for Semitransparent Solar Cells journal January 2016
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Triamcinolone solubilization by (2-hydroxypropyl)-β-cyclodextrin: A spectroscopic and computational approach journal October 2012
The origin of high efficiency in low-temperature solution-processable bilayer organometal halide hybrid solar cells journal January 2014
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Role of microstructure in the electron–hole interaction of hybrid lead halide perovskites journal August 2015
Metal complexes based on native cyclodextrins: Synthesis and structural diversity journal January 2016
High efficiency stable inverted perovskite solar cells without current hysteresis journal January 2015
Flexible high efficiency perovskite solar cells journal January 2014
Planar CH 3 NH 3 PbI 3 Perovskite Solar Cells with Constant 17.2% Average Power Conversion Efficiency Irrespective of the Scan Rate journal April 2015
A polymer scaffold for self-healing perovskite solar cells journal January 2016
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MAPbI3-xClx Mixed Halide Perovskite for Hybrid Solar Cells: The Role of Chloride as Dopant on the Transport and Structural Properties journal November 2013
Polysiloxane–gel matrices for ion sensitive membrane journal June 2000
Additive to regulate the perovskite crystal film growth in planar heterojunction solar cells journal January 2015
Iron-Induced Cyclodextrin Self-Assembly into Size-Controllable Nanospheres journal February 2010
Highly Reproducible Perovskite Solar Cells with Average Efficiency of 18.3% and Best Efficiency of 19.7% Fabricated via Lewis Base Adduct of Lead(II) Iodide journal July 2015
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Cyclodextrins and their applications in analytical chemistry journal September 1992
Spontaneous bidirectional ordering of CH3NH3+ in lead iodide perovskites at room temperature: The origins of the tetragonal phase journal April 2016
Bulk heterojunction perovskite–PCBM solar cells with high fill factor journal February 2016
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Review: A History of Cyclodextrins journal September 2014
Metal halide perovskites for energy applications journal May 2016
The Bright Side of Perovskites journal October 2016
Enhancement of the Performance of Perovskite Solar Cells, LEDs, and Optical Amplifiers by Anti-Solvent Additive Deposition journal December 2016
Elucidating the effect of the lead iodide complexation degree behind the morphology and performance of perovskite solar cells journal January 2017
Solution Deposition-Conversion for Planar Heterojunction Mixed Halide Perovskite Solar Cells journal May 2014
Sixteenfold Deprotonatedγ-Cyclodextrin Tori as Anions in a Hexadecanuclear Lead(II) Alkoxide journal September 1994
Solvation and Dynamic Behavior of Cyclodextrins in Dimethyl Sulfoxide Solution journal September 2006
Implications of TiO 2 surface functionalization on polycrystalline mixed halide perovskite films and photovoltaic devices journal January 2015
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Chemical Management for Colorful, Efficient, and Stable Inorganic–Organic Hybrid Nanostructured Solar Cells journal March 2013
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The Importance of Moisture in Hybrid Lead Halide Perovskite Thin Film Fabrication journal August 2015
Additive Enhanced Crystallization of Solution-Processed Perovskite for Highly Efficient Planar-Heterojunction Solar Cells journal March 2014

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