Chemical synthesis of L10 Fe-Pt-Ni alloy nanoparticles
- Univ. of Delaware, Newark, DE (United States)
- Khalifa Univ. of Science and Technology, Abu Dhabi (United Arab Emirates)
This work focuses on the study of the magnetic and structural properties of chemically synthesized FePt1-xNix nanoparticles, with Ni content x in the range 0.2-0.4. We report the effect of Ni substitution on the L10 structure, on both the as-synthesized and annealed nanoparticles. A decrease in nanoparticle size as well as in chemical order is observed with an increase in Ni content, for both the as-made and annealed nanoparticles. The results also show that the post annealing procedure at 700oC significantly enhanced the L10 ordering of the nanoparticles. Substitution of nickel leads to a decrease in coercivity from 14.9 kOe in FePt to 0.8 kOe for FePt0.6Ni0.4 alloy, while the magnetization at 3 T is increased from 48 emu/g to 88 emu/g.
- Research Organization:
- Univ. of Delaware, Newark, DE (United States)
- Sponsoring Organization:
- USDOE
- Grant/Contract Number:
- FG02-90ER45413; DOE-FG02-90ER45413
- OSTI ID:
- 1499252
- Alternate ID(s):
- OSTI ID: 1414614
- Journal Information:
- AIP Advances, Vol. 8, Issue 5; ISSN 2158-3226
- Publisher:
- American Institute of Physics (AIP)Copyright Statement
- Country of Publication:
- United States
- Language:
- English
Structurally Ordered Low‐Pt Intermetallic Electrocatalysts toward Durably High Oxygen Reduction Reaction Activity
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journal | July 2019 |
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