Effect of an external field on capillary waves in a dipolar fluid

Koski, Jason P.; Moore, Stan Gerald; Grest, Gary S.; Stevens, Mark J.

doi:10.1103/PhysRevE.96.063106

Title: Effect of an external field on capillary waves in a dipolar fluid

Journal Article · Wed Dec 06 00:00:00 EST 2017 · Physical Review E

DOI:https://doi.org/10.1103/PhysRevE.96.063106· OSTI ID:1499036

Koski, Jason P. ^[1]; Moore, Stan Gerald ^[1]; Grest, Gary S. ^[1]; Stevens, Mark J. ^[1]

Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

The role of an external field on capillary waves at the liquid-vapor interface of a dipolar fluid is investigated using molecular dynamics simulations. For fields parallel to the interface, the interfacial width squared increases linearly with respect to the logarithm of the size of the interface across all field strengths tested. Here, the value of the slope decreases with increasing field strength, indicating that the field dampens the capillary waves. With the inclusion of the parallel field, the surface stiffness increases with increasing field strength faster than the surface tension. For fields perpendicular to the interface, the interfacial width squared is linear with respect to the logarithm of the size of the interface for small field strengths, and the surface stiffness is less than the surface tension. Above a critical field strength that decreases as the size of the interface increases, the interface becomes unstable due to the increased amplitude of the capillary waves.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: AC04-94AL85000; NA0003525

OSTI ID:: 1499036

Alternate ID(s):: OSTI ID: 1411483

Report Number(s):: SAND-2019-2233J; PLEEE8; 672999

Journal Information:: Physical Review E, Vol. 96, Issue 6; ISSN 2470-0045

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 5 works

Citation information provided by
Web of Science

References (39)

The roughening transition of crystal surfaces. I. static and dynamic renormalization theory, crystal shape and facet growth Nozières, P.; Gallet, F. Journal de Physique, Vol. 48, Issue 3 https://doi.org/10.1051/jphys:01987004803035300	journal	January 1987
Electrohydrodynamic instabilities in polymer films Schäffer, E.; Thurn-Albrecht, T.; Russell, T. P. Europhysics Letters (EPL), Vol. 53, Issue 4 https://doi.org/10.1209/epl/i2001-00183-2	journal	February 2001
Second Virial Coefficients of Polar Gases Stockmayer, W. H. The Journal of Chemical Physics, Vol. 9, Issue 5 https://doi.org/10.1063/1.1750922	journal	May 1941
Effects of external electric field on the interfacial properties of weakly dipolar fluid Warshavsky, V. B.; Bykov, T. V.; Zeng, X. C. The Journal of Chemical Physics, Vol. 114, Issue 1 https://doi.org/10.1063/1.1329345	journal	January 2001
Effect of external electric field on the bulk and interfacial properties of weakly dipolar fluid in slab-shaped and sphere-shaped systems Warshavsky, V. B.; Zeng, X. C. Physical Review E, Vol. 68, Issue 5 https://doi.org/10.1103/PhysRevE.68.051203	journal	November 2003
Electric field effects on the structure and dynamics at a liquid \| liquid interface Schweighofer, Karl J.; Benjamin, Ilan Journal of Electroanalytical Chemistry, Vol. 391, Issue 1-2 https://doi.org/10.1016/0022-0728(95)03929-B	journal	July 1995
Capillary waves at liquid-vapor interfaces: A molecular dynamics simulation Sides, Scott W.; Grest, Gary S.; Lacasse, Martin-D. Physical Review E, Vol. 60, Issue 6 https://doi.org/10.1103/PhysRevE.60.6708	journal	December 1999
Phase coexistence of a Stockmayer fluid in an applied field Stevens, Mark J.; Grest, Gary S. Physical Review E, Vol. 51, Issue 6 https://doi.org/10.1103/PhysRevE.51.5976	journal	June 1995
X-ray-scattering study of capillary-wave fluctuations at a liquid surface Sanyal, M. K.; Sinha, S. K.; Huang, K. G. Physical Review Letters, Vol. 66, Issue 5 https://doi.org/10.1103/PhysRevLett.66.628	journal	February 1991
Density-functional theory for the interfacial properties of a dipolar fluid Teixeira, P. I.; Gama, M. M. Telo da Journal of Physics: Condensed Matter, Vol. 3, Issue 1 https://doi.org/10.1088/0953-8984/3/1/009	journal	January 1991
The interfacial stability of a ferromagnetic fluid Cowley, M. D.; Rosensweig, R. E. Journal of Fluid Mechanics, Vol. 30, Issue 4 https://doi.org/10.1017/S0022112067001697	journal	December 1967
Vapour-liquid equilibria of stockmayer fluids: Computer simulations and perturbation theory Van Leeuwen, M. E.; Smit, B.; Hendriks, E. M. Molecular Physics, Vol. 78, Issue 2 https://doi.org/10.1080/00268979300100231	journal	February 1993
Dipolar particles in an external field: Molecular dynamics simulation and mean field theory Jia, Ran; Hentschke, Reinhard Physical Review E, Vol. 80, Issue 5 https://doi.org/10.1103/PhysRevE.80.051502	journal	November 2009
Effect of an electric field on an interfacial profile Rodriguez, Robert; Antoniewicz, Peter R. Chemical Physics Letters, Vol. 66, Issue 2 https://doi.org/10.1016/0009-2614(79)85044-7	journal	October 1979
Magnetization and susceptibility of ferrofluids Szalai, I.; Dietrich, S. Journal of Physics: Condensed Matter, Vol. 20, Issue 20 https://doi.org/10.1088/0953-8984/20/20/204122	journal	May 2008
Capillary-Wave and Chain-Length Effects at Polymer/Polymer Interfaces Lacasse, Martin-D.; Grest, Gary S.; Levine, Alex J. Physical Review Letters, Vol. 80, Issue 2 https://doi.org/10.1103/PhysRevLett.80.309	journal	January 1998
A critical binary liquid in an electric field Beaglehole, D. The Journal of Chemical Physics, Vol. 74, Issue 9 https://doi.org/10.1063/1.441688	journal	May 1981
Surface tension, surface stiffness, and surface width of the 3-dimensional Ising model on a cubic lattice Hasenbusch, Martin; Pinn, Klaus Physica A: Statistical Mechanics and its Applications, Vol. 192, Issue 3 https://doi.org/10.1016/0378-4371(93)90043-4	journal	January 1993
Capillary waves at the liquid-vapor interface and the surface tension of water Ismail, Ahmed E.; Grest, Gary S.; Stevens, Mark J. The Journal of Chemical Physics, Vol. 125, Issue 1 https://doi.org/10.1063/1.2209240	journal	July 2006
Diffuse Interface in a Critical Fluid Mixture Huang, J. S.; Webb, W. W. The Journal of Chemical Physics, Vol. 50, Issue 9 https://doi.org/10.1063/1.1671613	journal	May 1969
Interface instability induced by an electric field in fluids Onuki, Akira Physica A: Statistical Mechanics and its Applications, Vol. 217, Issue 1-2 https://doi.org/10.1016/0378-4371(94)00024-N	journal	July 1995
Vapor−Liquid Equilibrium in Electric Field Gradients Samin, Sela; Tsori, Yoav The Journal of Physical Chemistry B, Vol. 115, Issue 1 https://doi.org/10.1021/jp107529n	journal	January 2011
Phase coexistence properties of polarizable Stockmayer fluids Kiyohara, Kenji; Gubbins, Keith E.; Panagiotopoulos, Athanassios Z. The Journal of Chemical Physics, Vol. 106, Issue 8 https://doi.org/10.1063/1.473082	journal	February 1997
Liquid-vapor interface of the Stockmayer fluid in a uniform external field Moore, Stan G.; Stevens, Mark J.; Grest, Gary S. Physical Review E, Vol. 91, Issue 2 https://doi.org/10.1103/PhysRevE.91.022309	journal	February 2015
Fluctuating Interfaces, Surface Tension, and Capillary Waves: an Introduction Privman, Vladimir International Journal of Modern Physics C, Vol. 03, Issue 05 https://doi.org/10.1142/S0129183192000531	journal	October 1992
Interfacial Density Profile for Fluids in the Critical Region Buff, F. P.; Lovett, R. A.; Stillinger, F. H. Physical Review Letters, Vol. 15, Issue 15 https://doi.org/10.1103/PhysRevLett.15.621	journal	October 1965
Capillary waves at soft electrified interfaces Daikhin, L. I.; Kornyshev, A. A.; Urbakh, M. Journal of Electroanalytical Chemistry, Vol. 483, Issue 1-2 https://doi.org/10.1016/S0022-0728(00)00054-1	journal	March 2000
The local structure factor near an interface; beyond extended capillary-wave models Parry, A. O.; Rascón, C.; Evans, R. Journal of Physics: Condensed Matter, Vol. 28, Issue 24 https://doi.org/10.1088/0953-8984/28/24/244013	journal	April 2016
Capillary wave Hamiltonian for the Landau–Ginzburg–Wilson density functional Chacón, Enrique; Tarazona, Pedro Journal of Physics: Condensed Matter, Vol. 28, Issue 24 https://doi.org/10.1088/0953-8984/28/24/244014	journal	April 2016
Anisotropic interfacial tension, contact angles, and line tensions: A graphics-processing-unit-based Monte Carlo study of the Ising model Block, Benjamin J.; Kim, Suam; Virnau, Peter Physical Review E, Vol. 90, Issue 6 https://doi.org/10.1103/PhysRevE.90.062106	journal	December 2014
Flory-Huggins Model of Equilibrium Polymerization and Phase Separation in the Stockmayer Fluid Dudowicz, Jacek; Freed, Karl F.; Douglas, Jack F. Physical Review Letters, Vol. 92, Issue 4 https://doi.org/10.1103/PhysRevLett.92.045502	journal	January 2004
Effective Hamiltonian for liquid-vapor interfaces Mecke, K. R.; Dietrich, S. Physical Review E, Vol. 59, Issue 6 https://doi.org/10.1103/PhysRevE.59.6766	journal	June 1999
Electrical Field Effect on the Critical Opalescence Debye, P.; Kleboth, K. The Journal of Chemical Physics, Vol. 42, Issue 9 https://doi.org/10.1063/1.1696394	journal	May 1965
Statistical mechanical description of liquid systems in an electric field Stepanow, Semjon; Thurn-Albrecht, Thomas Physical Review E, Vol. 79, Issue 4 https://doi.org/10.1103/PhysRevE.79.041104	journal	April 2009
The Boundary Condition in the Gibbs Ensemble Simulation of a Stockmayer Fluid under an Applied Field Kiyohara, Kenji; Oh, K. J.; Zeng, X. C. Molecular Simulation, Vol. 23, Issue 1 https://doi.org/10.1080/08927029908022114	journal	October 1999
Critical Temperature Shift in Pure Fluid ${S F}_{6}$ Caused by an Electric Field Hegseth, John; Amara, Kamel Physical Review Letters, Vol. 93, Issue 5 https://doi.org/10.1103/PhysRevLett.93.057402	journal	July 2004
High-resolution x-ray scattering measurements: I. Surfaces Daillant, J.; Alba, M. Reports on Progress in Physics, Vol. 63, Issue 10 https://doi.org/10.1088/0034-4885/63/10/203	journal	September 2000
Surface tension of a charged and polarized system Goodisman, Jerry The Journal of Physical Chemistry, Vol. 96, Issue 15 https://doi.org/10.1021/j100194a046	journal	July 1992
Nanoscale Structure of the Oil-Water Interface Fukuto, M.; Ocko, B. M.; Bonthuis, D. J. Physical Review Letters, Vol. 117, Issue 25 https://doi.org/10.1103/PhysRevLett.117.256102	journal	December 2016

Cited By (4)

Electromechanics of the liquid water vapour interface Zhang, Chao; Sprik, Michiel Physical Chemistry Chemical Physics, Vol. 22, Issue 19 https://doi.org/10.1039/c9cp06901a	journal	January 2020
Experimental verification of anomalous surface tension temperature dependence at the interface between coexisting liquid-gas phases in magnetic and Stockmayer fluids Ivanov, Aleksey S. Physics of Fluids, Vol. 31, Issue 5 https://doi.org/10.1063/1.5094854	journal	May 2019
Electromechanics of the liquid water vapour interface. Zhang, Chao; Sprik, Michiel Apollo - University of Cambridge Repository https://doi.org/10.17863/cam.48749	text	January 2020
Electromechanics of the liquid water vapour interface Zhang, Chao; Sprik, Michiel arXiv https://doi.org/10.48550/arxiv.1912.10540	text	January 2019

Similar Records

Capillary Waves at Liquid/Vapor Interfaces: A Molecular Dynamics Simulation

Journal Article · Fri Jul 16 00:00:00 EDT 1999 · Physical Review E · OSTI ID:1499036

Sides, Scott W; Grest, Gary S; Lacasse, Martin-D

Generalized formula for the surface stiffness of fluid-saturated porous media containing parallel pore channels

Journal Article · Mon Sep 25 00:00:00 EDT 1995 · Applied Physics Letters · OSTI ID:1499036

Nagy, P B; Nayfeh, A H

External field effect on the critical behavior of the interface between fluid phases

Conference · Wed Mar 01 00:00:00 EST 1989 · International Journal of Thermophysics; (USA) · OSTI ID:1499036

Knackstedt, M; Robert, M

Related Subjects

74 ATOMIC AND MOLECULAR PHYSICS

Title: Effect of an external field on capillary waves in a dipolar fluid

Citation Formats

References (39)

Cited By (4)

Similar Records

Related Subjects