From Tb3Ni2 to Tb3CoNi : The interplay between chemistry, structure, and magnetism

Ritter, Clemens; Provino, Alessia; Fauth, Francois; Dhar, Sudesh K.; Pecharsky, Vitalij K.; Manfrinetti, Pietro

doi:10.1103/PhysRevMaterials.3.024406

From $T b_{3} N i_{2}$ to $T b_{3} CoNi$ : The interplay between chemistry, structure, and magnetism

Journal Article · Wed Feb 20 00:00:00 EST 2019 · Physical Review Materials

DOI:https://doi.org/10.1103/PhysRevMaterials.3.024406· OSTI ID:1498681

Ritter, Clemens ^[1]; Provino, Alessia ^[2]; Fauth, Francois ^[3]; Dhar, Sudesh K. ^[4]; Pecharsky, Vitalij K. ^[5]; Manfrinetti, Pietro ^[2]

Institut Laue-Langevin, Grenoble (France)
University of Genova (Italy); Ames Lab. and Iowa State Univ., Ames, IA (United States); Institute SPIN-CNR, Genova (Italy)
CELLS-ALBA Synchrotron, Barcelona (Spain)
Tata Institute of Fundamental Research, Mumbai (India)
Ames Lab. and Iowa State Univ., Ames, IA (United States)

Formation, crystal structure, and macroscopic and microscopic magnetism of the binary Tb₃Ni₂ and derivative pseudobinary Tb₃Co_xNi_2-x phases have been investigated using an array of experimental methods. While Tb₃Ni₂ crystallizes in the monoclinic Dy₃Ni₂ structure type (mS20, C2/m), the substitution of Co for Ni results in a structural transition into the rhombohedral Er₃Ni₂ type (hR45, R$$\overline{3}$$h) at x(Co) ≈ 0.34 and beyond in the Tb₃Co_xNi_2-x system. In both the monoclinic and rhombohedral phases, the addition of Co leads to an anisotropic change of lattice parameters and unexpected reduction of the cell volume. Measurements of bulk properties reveal that these compounds order ferrimagnetically or ferromagnetically at about 100 K. Complex noncollinear ferromagnetic ordering in the Tb sublattices is weakly dependent on composition. Lastly, for x > 0.34 the long-range magnetic ordering leads to a strong anisotropic magnetostriction accompanied by a symmetry reduction from rhombohedral to triclinic.

View Accepted Manuscript (DOE)

Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 1498681

Alternate ID(s):: OSTI ID: 1495238

Report Number(s):: IS-J--9900

Journal Information:: Physical Review Materials, Journal Name: Physical Review Materials Journal Issue: 2 Vol. 3; ISSN PRMHAR; ISSN 2475-9953

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

References (20)

Atomic-environment classification of the chemical elements Villars, P.; Daams, J. L. C. Journal of Alloys and Compounds, Vol. 197, Issue 2 https://doi.org/10.1016/0925-8388(93)90041-K	journal	June 1993
Self-assembled nano- to micron-size fibers from molten R11Ni4In9 intermetallics Provino, Alessia; Manfrinetti, Pietro; Gschneidner, Karl A. Acta Materialia, Vol. 73 https://doi.org/10.1016/j.actamat.2014.03.061	journal	July 2014
The nano-microfibrous R11Ni4In9 intermetallics: New compounds and extraordinary anisotropy in Tb11Ni4In9 and Dy11Ni4In9 Provino, A.; Gschneidner, K. A.; Dhar, S. K. Acta Materialia, Vol. 91 https://doi.org/10.1016/j.actamat.2015.03.003	journal	June 2015
Phase diagram of the Tb–Ni binary system Yao, Qingrong; Wang, Yanchun; Zhou, Huaiying Journal of Alloys and Compounds, Vol. 395, Issue 1-2 https://doi.org/10.1016/j.jallcom.2004.11.043	journal	May 2005
On the RMgSn rare earth compounds Manfrinetti, P.; Provino, A.; Gschneidner, K. A. Journal of Alloys and Compounds, Vol. 482, Issue 1-2 https://doi.org/10.1016/j.jallcom.2009.03.178	journal	August 2009
An economics strategy for criticality – Application to rare earth element Yttrium in new lighting technology and its sustainable availability Zhang, Kuangyuan; Kleit, Andrew N.; Nieto, Antonio Renewable and Sustainable Energy Reviews, Vol. 77 https://doi.org/10.1016/j.rser.2016.12.127	journal	September 2017
Non-hysteretic first-order phase transition with large latent heat and giant low-field magnetocaloric effect Guillou, F.; Pathak, A. K.; Paudyal, D. Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-05268-4	journal	July 2018
Gd ₃ Ni ₂ and Gd ₃ Co _x Ni _2−x : magnetism and unexpected Co/Ni crystallographic ordering Provino, Alessia; Smetana, Volodymyr; Paudyal, Durga Journal of Materials Chemistry C, Vol. 4, Issue 25 https://doi.org/10.1039/C6TC01035K	journal	January 2016
Magnetocaloric effect in Tb5(SixGe1−x)4 Morellon, L.; Magen, C.; Algarabel, P. A. Applied Physics Letters, Vol. 79, Issue 9 https://doi.org/10.1063/1.1399007	journal	August 2001
Magnetic properties and magnetocaloric effects in R ₃ Ni ₂ ( R = Ho and Er) compounds Dong, Q. Y.; Chen, J.; Shen, J. Applied Physics Letters, Vol. 99, Issue 13 https://doi.org/10.1063/1.3643142	journal	September 2011
Electronically- and crystal-structure-driven magnetic structures and physical properties of RScSb (R = rare earth) compounds: a neutron diffraction, magnetization and heat capacity study Ritter, C.; Dhar, S. K.; Kulkarni, R. Journal of Physics: Condensed Matter, Vol. 26, Issue 36 https://doi.org/10.1088/0953-8984/26/36/366001	journal	August 2014
Magnetic structures of R ₅ Ni ₂ In ₄ and R ₁₁ Ni ₄ In ₉ ( R = Tb and Ho): strong hierarchy in the temperature dependence of the magnetic ordering in the multiple rare-earth sublattices Ritter, C.; Provino, A.; Manfrinetti, P. Journal of Physics: Condensed Matter, Vol. 27, Issue 47 https://doi.org/10.1088/0953-8984/27/47/476001	journal	November 2015
Tetragonal to triclinic structural transition in the prototypical CeScSi induced by a two-step magnetic ordering: a temperature-dependent neutron diffraction study of CeScSi, CeScGe and LaScSi Ritter, C.; Provino, A.; Manfrinetti, P. Journal of Physics: Condensed Matter, Vol. 29, Issue 4 https://doi.org/10.1088/1361-648X/29/4/045802	journal	November 2016
Magnetoelastic coupling in the triangular lattice antiferromagnet CuCrS 2 Rasch, Julia C. E.; Boehm, Martin; Ritter, Clemens Physical Review B, Vol. 80, Issue 10 https://doi.org/10.1103/PhysRevB.80.104431	journal	September 2009
Tunable magnetism and structural transformations in mixed light- and heavy-lanthanide dialuminides Pathak, Arjun K.; Paudyal, D.; Mudryk, Y. Physical Review B, Vol. 94, Issue 22 https://doi.org/10.1103/PhysRevB.94.224406	journal	December 2016
Giant Magnetocaloric Effect in Gd5(Si2Ge2) Pecharsky, V. K.; Gschneidner, Jr., K. A. Physical Review Letters, Vol. 78, Issue 23, p. 4494-4497 https://doi.org/10.1103/PhysRevLett.78.4494	journal	June 1997
The crystal structure of Er ₃ Ni ₂ Moreau, J. M.; Paccard, D.; Gignoux, D. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 30, Issue 9 https://doi.org/10.1107/S0567740874006583	journal	September 1974
The monoclinic, CrB-related, crystal structure of Tb3Ni2, Dy3Ni2 and Ho3Ni2 Moreau, J. M.; Paccard, D.; Parthé, E. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 30, Issue 11 https://doi.org/10.1107/S0567740874007631	journal	November 1974
Y ₃ Ni ₂ : a new tetragonal phase with Ni-centred trigonal prisms Le Roy, J.; Moreau, J. -M.; Paccard, D. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 33, Issue 11 https://doi.org/10.1107/S0567740877011091	journal	November 1977
Phase equilibria in the Gd–Ni binary and Mg–Ni–Gd ternary systems Xu, Guanglong; Cui, Yu-Wen; Fei, Houjun International Journal of Materials Research (formerly Zeitschrift fuer Metallkunde), Vol. 103, Issue 10 https://doi.org/10.3139/146.110756	journal	January 2012

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