Modern Processing and Insights on Selenium Solar Cells: The World's First Photovoltaic Device

Hadar, Ido; Song, Tze‐Bin; Ke, Weijun; Kanatzidis, Mercouri G.

doi:10.1002/aenm.201802766

Modern Processing and Insights on Selenium Solar Cells: The World's First Photovoltaic Device

Journal Article · Tue Feb 26 23:00:00 EST 2019 · Advanced Energy Materials

DOI:https://doi.org/10.1002/aenm.201802766· OSTI ID:1497217

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Department of Chemistry Northwestern University Evanston IL 60208 USA

Abstract

The first solid‐state solar cells, fabricated ≈140 years ago, were based on selenium; these early studies initiated the modern research on photovoltaic materials. Selenium shows high absorption coefficient and mobility, making it an attractive absorber for high bandgap thin film solar cells. Moreover, the simplicity of a single element absorber, its low‐temperature processing, and intrinsic environmental stability enable the utilization of selenium in extremely cheap and scalable solar cells. In this paper, a detailed study of selenium solar cell fabrication is presented, and the key factors that affect the selenium film morphology and the resulting device efficiency are presented. Specifically, the crystallization process from amorphous film into functional crystalline device is studied. The importance of controlling the process is shown, and methods to align the growth orientation are suggested. Finally, the crystallization process under illumination, which has general importance for the fabrication of thin film photovoltaics, is investigated. Specifically for selenium, the illumination significantly improves the film morphology and leads to device efficiency of 5.2%, with open‐circuit voltage of 0.911 V, short‐circuit current density of 10.2 mA cm ⁻² , and fill factor of 55.0%. These findings form a solid foundation for future improvements of the photovoltaic material and device architecture.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0001059

OSTI ID:: 1497217

Alternate ID(s):: OSTI ID: 1610501

Journal Information:: Advanced Energy Materials, Journal Name: Advanced Energy Materials Journal Issue: 16 Vol. 9; ISSN 1614-6832

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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