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Deep ultraviolet emission from ultra-thin GaN/AlN heterostructures

Journal Article · · Applied Physics Letters
DOI:https://doi.org/10.1063/1.4971968· OSTI ID:1497072
We present the theoretical and experimental results for the electronic and optical properties of atomically thin (1 and 2 monolayers) GaN quantum wells with AlN barriers. Strong quantum confinement increases the gap of GaN to as high as 5.44 eV and enables light emission in the deep-UV range. Luminescence occurs from the heavy and light hole bands of GaN yielding E ⊥ c polarized light emission. Strong confinement also increases the exciton binding energy up to 230 meV, preventing a thermal dissociation of excitons at room temperature. However, we did not observe excitons experimentally due to high excited free-carrier concentrations. Monolayer-thick GaN wells also exhibit a large electron-hole wave function overlap and negligible Stark shift, which is expected to enhance the radiative recombination efficiency. Our results indicate that atomically thin GaN/AlN heterostructures are promising for efficient deep-UV optoelectronic devices.
Research Organization:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Organization:
USDOE
Grant/Contract Number:
AC02-05CH11231
OSTI ID:
1497072
Journal Information:
Applied Physics Letters, Journal Name: Applied Physics Letters Journal Issue: 24 Vol. 109; ISSN APPLAB; ISSN 0003-6951
Publisher:
American Institute of Physics (AIP)Copyright Statement
Country of Publication:
United States
Language:
English

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Cited By (14)

AlN/GaN Digital Alloy for Mid- and Deep-Ultraviolet Optoelectronics journal September 2017
Ultra-Broadband Optical Gain in III-Nitride Digital Alloys journal February 2018
Self‐Limiting Growth of Ultrathin GaN/AlN Quantum Wells for Highly Efficient Deep Ultraviolet Emitters journal August 2019
MBE-grown 232–270 nm deep-UV LEDs using monolayer thin binary GaN/AlN quantum heterostructures journal January 2017
Fundamentals, progress, and future directions of nitride-based semiconductors and their composites in two-dimensional limit: A first-principles perspective to recent synthesis journal March 2018
Deep-UV emission at 219 nm from ultrathin MBE GaN/AlN quantum heterostructures journal August 2017
Impact of carrier localization on recombination in InGaN quantum wells and the efficiency of nitride light-emitting diodes: Insights from theory and numerical simulations journal September 2017
234 nm and 246 nm AlN-Delta-GaN quantum well deep ultraviolet light-emitting diodes journal January 2018
Thermal conductivity of crystalline AlN and the influence of atomic-scale defects journal November 2019
Room-temperature stability of excitons and transverse-electric polarized deep-ultraviolet luminescence in atomically thin GaN quantum wells journal September 2019
Monolayer GaN excitonic deep ultraviolet light emitting diodes journal January 2020
Strong in- and out-of-plane excitons in two-dimensional InN nanosheets journal December 2018
MBE-grown 232-270 nm Deep-UV LEDs using Monolayer thin Binary GaN/AlN quantum heterostructures text January 2016
Impact of carrier localization on recombination in InGaN quantum wells and the efficiency of nitride light-emitting diodes: insights from theory and numerical simulations text January 2017

Figures / Tables (4)


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