Graphene aerogels

Pauzauskie, Peter J.; Worsley, Marcus A.; Baumann, Theodore F.; Satcher, Jr., Joe H.; Biener, Juergen

Graphene aerogels

Patent · Tue Oct 23 04:00:00 EDT 2018

OSTI ID:1496865

Pauzauskie, Peter J.; Worsley, Marcus A.; Baumann, Theodore F.; Satcher, Jr., Joe H.; Biener, Juergen

Graphene aerogels with high conductivity and surface areas including a method for making a graphene aerogel, including the following steps: (1) preparing a reaction mixture comprising a graphene oxide suspension and at least one catalyst; (2) curing the reaction mixture to produce a wet gel; (3) drying the wet gel to produce a dry gel; and (4) pyrolyzing the dry gel to produce a graphene aerogel. Applications include electrical energy storage including batteries and supercapacitors.

View Patent

Research Organization:: Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC52-07NA27344

Assignee:: Lawrence Livermore National Security, LLC (Livermore, CA)

Patent Number(s):: 10,106,418

Application Number:: 14/606,894

OSTI ID:: 1496865

Country of Publication:: United States

Language:: English

References (77)

Raman validity for crystallite size L_a determination on reticulated vitreous carbon with different graphitization index Baldan, M. R.; Almeida, E. C.; Azevedo, A. F. Applied Surface Science, Vol. 254, Issue 2, p. 600-603 https://doi.org/10.1016/j.apsusc.2007.06.038	journal	November 2007
Extremely high thermal conductivity of graphene: Prospects for thermal management applications in nanoelectronic circuits Ghosh, S.; Calizo, I.; Teweldebrhan, D. Applied Physics Letters, Vol. 92, Issue 15, Article No. 151911 https://doi.org/10.1063/1.2907977	journal	April 2008
Highly conducting graphene sheets and Langmuir–Blodgett films Li, Xiaolin; Zhang, Guangyu; Bai, Xuedong Nature Nanotechnology, Vol. 3, Issue 9, p. 538-542 https://doi.org/10.1038/nnano.2008.210	journal	August 2008
High Surface Area, sp²-Cross-Linked Three-Dimensional Graphene Monoliths Worsley, Marcus A.; Olson, Tammy Y.; Lee, Jonathan R. I. The Journal of Physical Chemistry Letters, Vol. 2, Issue 8, p. 921-925 https://doi.org/10.1021/jz200223x	journal	April 2011
Binder-Free and Carbon-Free Nanoparticle Batteries: A Method for Nanoparticle Electrodes without Polymeric Binders or Carbon Black Ha, Don-Hyung; Islam, Mohammad A.; Robinson, Richard D. Nano Letters, Vol. 12, Issue 10, p. 5122-5130 https://doi.org/10.1021/nl3019559	journal	September 2012
Assembly of Graphene Sheets into 3D Macroscopic Structures Yin, Shengyan; Niu, Zhiqiang; Chen, Xiaodong Small, Vol. 8, Issue 16, p. 2458-2463 https://doi.org/10.1002/smll.201102614	journal	May 2012
Transparent, Conductive Graphene Electrodes for Dye-Sensitized Solar Cells Wang, Xuan; Zhi, Linjie; Müllen, Klaus Nano Letters, Vol. 8, Issue 1, p. 323-327 https://doi.org/10.1021/nl072838r	journal	January 2008
Noble-Metal-Promoted Three-Dimensional Macroassembly of Single-Layered Graphene Oxide Tang, Zhihong; Shen, Shuling; Zhuang, Jing Angewandte Chemie International Edition, Vol. 49, Issue 27, p. 4603-4607 https://doi.org/10.1002/anie.201000270	journal	May 2010
Preparation of Graphitic Oxide Hummers, William S.; Offeman, Richard E. Journal of the American Chemical Society, Vol. 80, Issue 6, p. 1339-1339 https://doi.org/10.1021/ja01539a017	journal	March 1958
Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries Poizot, P.; Laruelle, S.; Grugeon, S. Nature, Vol. 407, Issue 6803, p. 496-499 https://doi.org/10.1038/35035045	journal	September 2000
NEXAFS Spectroscopy Stöhr, Joachim Springer Series in Surface Sciences https://doi.org/10.1007/978-3-662-02853-7	book	January 1992
Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene Lee, C.; Wei, X.; Kysar, J. W. Science, Vol. 321, Issue 5887, p. 385-388 https://doi.org/10.1126/science.1157996	journal	July 2008
Electrocapillary maximum and potential of zero charge of carbon aerogel Shao, Li-Hua; Biener, Jürgen; Kramer, Dominik Physical Chemistry Chemical Physics, Vol. 12, Issue 27 https://doi.org/10.1039/B916331J	journal	January 2010
Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition Chen, Zongping; Ren, Wencai; Gao, Libo Nature Materials, Vol. 10, Issue 6, p. 424-428 https://doi.org/10.1038/nmat3001	journal	April 2011
An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments Oliver, W. C.; Pharr, G. M. Journal of Materials Research, Vol. 7, Issue 06, p. 1564-1583 https://doi.org/10.1557/JMR.1992.1564	journal	June 1992
Raman Spectrum of Graphene and Graphene Layers Ferrari, A. C.; Meyer, J. C.; Scardaci, V. Physical Review Letters, Vol. 97, Issue 18, Article No. 187401 https://doi.org/10.1103/PhysRevLett.97.187401	journal	October 2006
Graphene-based composite materials Stankovich, Sasha; Dikin, Dmitriy A.; Dommett, Geoffrey H. B. Nature, Vol. 442, Issue 7100, p. 282-286 https://doi.org/10.1038/nature04969	journal	July 2006
Mn₃O₄−Graphene Hybrid as a High-Capacity Anode Material for Lithium Ion Batteries Wang, Hailiang; Cui, Li-Feng; Yang, Yuan Journal of the American Chemical Society, Vol. 132, Issue 40, p. 13978-13980 https://doi.org/10.1021/ja105296a	journal	October 2010
Interpretation of Raman spectra of disordered and amorphous carbon Ferrari, A. C.; Robertson, J. Physical Review B, Vol. 61, Issue 20, p. 14095-14107 https://doi.org/10.1103/PhysRevB.61.14095	journal	May 2000
Detection of individual gas molecules adsorbed on graphene Schedin, F.; Geim, A. K.; Morozov, S. V. Nature Materials, Vol. 6, Issue 9, p. 652-655 https://doi.org/10.1038/nmat1967	journal	July 2007
Near-Edge X-Ray Absorption Fine-Structure Investigation of Graphene Pacile, D.; Papagno, M.; Rodríguez, A. Fraile Physical Review Letters, Vol. 101, Issue 6, Article No. 066806 https://doi.org/10.1103/PhysRevLett.101.066806	journal	August 2008
Synthesis and Characterization of Monolithic Carbon Aerogel Nanocomposites Containing Double-Walled Carbon Nanotubes Worsley, Marcus A.; Satcher, Joe H.; Baumann, Theodore F. Langmuir, Vol. 24, Issue 17, p. 9763-9766 https://doi.org/10.1021/la8011684	journal	September 2008
Electric Field Effect in Atomically Thin Carbon Films Novoselov, K. S. Science, Vol. 306, Issue 5696, p. 666-669 https://doi.org/10.1126/science.1102896	journal	October 2004
Functionalized graphene sheet filled silicone foam nanocomposites Verdejo, Raquel; Barroso-Bujans, Fabienne; Rodriguez-Perez, Miguel Angel Journal of Materials Chemistry, Vol. 18, Issue 19, p. 2221-2226 https://doi.org/10.1039/b718289a	journal	January 2008
Epitaxial graphene on ruthenium Sutter, Peter W.; Flege, Jan-Ingo; Sutter, Eli A. Nature Materials, Vol. 7, Issue 5, p. 406-411 https://doi.org/10.1038/nmat2166	journal	April 2008
In Situ Observation of the Electrochemical Lithiation of a Single SnO₂ Nanowire Electrode Huang, J. Y.; Zhong, L.; Wang, C. M. Science, Vol. 330, Issue 6010, p. 1515-1520 https://doi.org/10.1126/science.1195628	journal	December 2010
Carrier Transport in Two-Dimensional Graphene Layers Hwang, E. H.; Adam, S.; Sarma, S. Das Physical Review Letters, Vol. 98, Issue 18, Article No. 186806 https://doi.org/10.1103/PhysRevLett.98.186806	journal	May 2007
Single Sheet Functionalized Graphene by Oxidation and Thermal Expansion of Graphite McAllister, Michael J.; Li, Je-Luen; Adamson, Douglas H. Chemistry of Materials, Vol. 19, Issue 18, p. 4396-4404 https://doi.org/10.1021/cm0630800	journal	September 2007
Graphene-based electrochemical supercapacitors Vivekchand, S. R. C.; Rout, Chandra Sekhar; Subrahmanyam, K. S. Journal of Chemical Sciences, Vol. 120, Issue 1, p. 9-13 https://doi.org/10.1007/s12039-008-0002-7	journal	January 2008
Combined XRD, EXAFS, and Mossbauer Studies of the Reduction by Lithium of α-Fe₂O₃ with Various Particle Sizes Larcher, D.; Bonnin, D.; Cortes, R. Journal of The Electrochemical Society, Vol. 150, Issue 12, p. A1643-A1650 https://doi.org/10.1149/1.1622959	journal	January 2003
Ternary Self-Assembly of Ordered Metal Oxide−Graphene Nanocomposites for Electrochemical Energy Storage Wang, Donghai; Kou, Rong; Choi, Daiwon ACS Nano, Vol. 4, Issue 3, p. 1587-1595 https://doi.org/10.1021/nn901819n	journal	March 2010
Practical Chemical Sensors from Chemically Derived Graphene Fowler, Jesse D.; Allen, Matthew J.; Tung, Vincent C. ACS Nano, Vol. 3, Issue 2, p. 301-306 https://doi.org/10.1021/nn800593m	journal	February 2009
In situ infrared observation of the pyrolysis process of carbon aerogels Kuhn, J.; Brandt, R.; Mehling, H. Journal of Non-Crystalline Solids, Vol. 225, p. 58-63 https://doi.org/10.1016/S0022-3093(98)00009-X	journal	April 1998
Properties of single-walled carbon nanotube-based aerogels as a function of nanotube loading Worsley, Marcus A.; Pauzauskie, Peter J.; Kucheyev, Sergei O. Acta Materialia, Vol. 57, Issue 17, p. 5131-5136 https://doi.org/10.1016/j.actamat.2009.07.012	journal	October 2009
Preparation and Properties of Resorcinol-Formaldehyde Organic and Carbon Gels Al-Muhtaseb, S. A.; Ritter, J. A. Advanced Materials, Vol. 15, Issue 2, p. 101-114 https://doi.org/10.1002/adma.200390020	journal	January 2003
High surface area carbon nanotube-supported titanium carbonitride aerogels Worsley, Marcus A.; Kuntz, Joshua D.; Pauzauskie, Peter J. Journal of Materials Chemistry, Vol. 19, Issue 31, p. 5503-5506 https://doi.org/10.1039/b908284k	journal	January 2009
Electronic Transport Properties of Individual Chemically Reduced Graphene Oxide Sheets Gomez-Navarro, Cristina; Weitz, R. Thomas; Bittner, Alexander M. Nano Letters, Vol. 7, Issue 11, p. 3499-3503 https://doi.org/10.1021/nl072090c	journal	November 2007
Spatially Resolved Raman Spectroscopy of Single- and Few-Layer Graphene Graf, D.; Molitor, F.; Ensslin, K. Nano Letters, Vol. 7, Issue 2, p. 238-242 https://doi.org/10.1021/nl061702a	journal	February 2007
Carbon Scaffolds for Stiff and Highly Conductive Monolithic Oxide–Carbon Nanotube Composites Worsley, Marcus A.; Kucheyev, Sergei O.; Kuntz, Joshua D. Chemistry of Materials, Vol. 23, Issue 12, p. 3054-3061 https://doi.org/10.1021/cm200426k	journal	June 2011
Depth-sensing indentation of low-density brittle nanoporous solids Kucheyev, S. O.; Hamza, A. V.; Satcher Jr., J. H. Acta Materialia, Vol. 57, Issue 12, p. 3472-3480 https://doi.org/10.1016/j.actamat.2009.04.003	journal	July 2009
The rise of graphene Geim, A. K.; Novoselov, K. S. Nature Materials, Vol. 6, Issue 3, p. 183-191 https://doi.org/10.1038/nmat1849	journal	March 2007
Electronic and structural properties of graphene-based transparent and conductive thin film electrodes Vollmer, A.; Feng, X. L.; Wang, X. Applied Physics A, Vol. 94, Issue 1, p. 1-4 https://doi.org/10.1007/s00339-008-4931-2	journal	October 2008
Stiff and electrically conductive composites of carbon nanotube aerogels and polymers Worsley, Marcus A.; Kucheyev, Sergei O.; Kuntz, Joshua D. Journal of Materials Chemistry, Vol. 19, Issue 21, p. 3370-3372 https://doi.org/10.1039/b905735h	journal	January 2009
Superior Thermal Conductivity of Single-Layer Graphene Balandin, Alexander A.; Ghosh, Suchismita; Bao, Wenzhong Nano Letters, Vol. 8, Issue 3, p. 902-907 https://doi.org/10.1021/nl0731872	journal	March 2008
Specific surface area of carbon nanotubes and bundles of carbon nanotubes Peigney, A.; Laurent, Ch.; Flahaut, E. Carbon, Vol. 39, Issue 4, p. 507-514 https://doi.org/10.1016/S0008-6223(00)00155-X	journal	April 2001
Capacity Fade Mechanisms and Side Reactions in Lithium-Ion Batteries Arora, Pankaj; White, Ralph E.; Doyle, Marc Journal of The Electrochemical Society, Vol. 145, Issue 10, p. 3647-3667 https://doi.org/10.1149/1.1838857	journal	January 1998
Advanced carbon aerogels for energy applications Biener, Juergen; Stadermann, Michael; Suss, Matthew Energy & Environmental Science, Vol. 4, Issue 3, p. 656-667 https://doi.org/10.1039/c0ee00627k	journal	January 2011
Functionalized graphene sheets for polymer nanocomposites Ramanathan, T.; Abdala, A. A.; Stankovich, S. Nature Nanotechnology, Vol. 3, Issue 6, p. 327-331 https://doi.org/10.1038/nnano.2008.96	journal	May 2008
Carbon 1s near-edge-absorption fine structure in graphite Batson, P. E. Physical Review B, Vol. 48, Issue 4, p. 2608-2610 https://doi.org/10.1103/PhysRevB.48.2608	journal	July 1993
Self-Assembled Graphene Hydrogel via a One-Step Hydrothermal Process Xu, Yuxi; Sheng, Kaixuan; Li, Chun ACS Nano, Vol. 4, Issue 7, p. 4324-4330 https://doi.org/10.1021/nn101187z	journal	July 2010
X-ray absorption spectroscopy of graphite oxide Jeong, H.-K.; Noh, H.-J.; Kim, J.-Y. EPL (Europhysics Letters), Vol. 82, Issue 6, Article No. 67004 https://doi.org/10.1209/0295-5075/82/67004	journal	June 2008
Nanostructured Reduced Graphene Oxide/Fe₂O₃ Composite As a High-Performance Anode Material for Lithium Ion Batteries Zhu, Xianjun; Zhu, Yanwu; Murali, Shanthi ACS Nano, Vol. 5, Issue 4, p. 3333-3338 https://doi.org/10.1021/nn200493r	journal	April 2011
On the Origin of the Extra Electrochemical Capacity Displayed by MO/Li Cells at Low Potential Laruelle, S.; Grugeon, S.; Poizot, P. Journal of The Electrochemical Society, Vol. 149, Issue 5, p. A627-A634 https://doi.org/10.1149/1.1467947	journal	January 2002
Graphene Aerogels Wang, Jian; Ellsworth, Mark https://doi.org/10.1149/1.3119548	conference	January 2009
Structure and electronic properties of a nongraphitic disordered carbon system and its heat-treatment effects Takai, Kazuyuki; Oga, Meigo; Sato, Hirohiko Physical Review B, Vol. 67, Issue 21, Article No. 214202 https://doi.org/10.1103/PhysRevB.67.214202	journal	June 2003
Aqueous Dispersion of Graphene Sheets Stabilized by Pluronic Copolymers: Formation of Supramolecular Hydrogel Zu, Sheng-Zhen; Han, Bao-Hang The Journal of Physical Chemistry C, Vol. 113, Issue 31, p. 13651-13657 https://doi.org/10.1021/jp9035887	journal	August 2009
Core excitons and vibronic coupling in diamond and graphite Ma, Y.; Skytt, P.; Wassdahl, N. Physical Review Letters, Vol. 71, Issue 22, p. 3725-3728 https://doi.org/10.1103/PhysRevLett.71.3725	journal	November 1993
Structural Studies of Lithium Intercalation in a Nanocrystalline α-Fe₂O₃Compound Jain, Gaurav; Balasubramanian, Mahalingam; Xu, Jun John Chemistry of Materials, Vol. 18, Issue 2, p. 423-434 https://doi.org/10.1021/cm052014f	journal	January 2006
Synthesis of Graphene Sheets with High Electrical Conductivity and Good Thermal Stability by Hydrogen Arc Discharge Exfoliation Wu, Zhong-Shuai; Ren, Wencai; Gao, Libo ACS Nano, Vol. 3, Issue 2, p. 411-417 https://doi.org/10.1021/nn900020u	journal	February 2009
Graphene-Wrapped Fe₃O₄ Anode Material with Improved Reversible Capacity and Cyclic Stability for Lithium Ion Batteries Zhou, Guangmin; Wang, Da-Wei; Li, Feng Chemistry of Materials, Vol. 22, Issue 18, p. 5306-5313 https://doi.org/10.1021/cm101532x	journal	September 2010
Synthesis of Graphene Aerogel with High Electrical Conductivity Worsley, Marcus A.; Pauzauskie, Peter J.; Olson, Tammy Y. Journal of the American Chemical Society, Vol. 132, Issue 40, p. 14067-14069 https://doi.org/10.1021/ja1072299	journal	October 2010
Graphene Anchored with Co₃O₄ Nanoparticles as Anode of Lithium Ion Batteries with Enhanced Reversible Capacity and Cyclic Performance Wu, Zhong-Shuai; Ren, Wencai; Wen, Lei ACS Nano, Vol. 4, Issue 6, p. 3187-3194 https://doi.org/10.1021/nn100740x	journal	June 2010
Mechanically robust and electrically conductive carbon nanotube foams Worsley, Marcus A.; Kucheyev, Sergei O.; Satcher, Joe H. Applied Physics Letters, Vol. 94, Issue 7, Article No. 073115 https://doi.org/10.1063/1.3086293	journal	February 2009
Giant Intrinsic Carrier Mobilities in Graphene and Its Bilayer Morozov, S. V.; Novoselov, K. S.; Katsnelson, M. I. Physical Review Letters, Vol. 100, Issue 1, Article No. 016602 https://doi.org/10.1103/PhysRevLett.100.016602	journal	January 2008
Mechanically robust 3D graphene macroassembly with high surface area Worsley, Marcus A.; Kucheyev, Sergei O.; Mason, Harris E. Chemical Communications, Vol. 48, Issue 67, p. 8428-8430 https://doi.org/10.1039/c2cc33979j	journal	January 2012
Large Reversible Li Storage of Graphene Nanosheet Families for Use in Rechargeable Lithium Ion Batteries Yoo, EunJoo; Kim, Jedeok; Hosono, Eiji Nano Letters, Vol. 8, Issue 8, p. 2277-2282 https://doi.org/10.1021/nl800957b	journal	August 2008
A Controllable Self-Assembly Method for Large-Scale Synthesis of Graphene Sponges and Free-Standing Graphene Films Liu, Fei; Seo, Tae Seok Advanced Functional Materials, Vol. 20, Issue 12, p. 1930-1936 https://doi.org/10.1002/adfm.201000287	journal	May 2010
Fabrication of Graphene-Polymer Nanocomposites With Higher-Order Three-Dimensional Architectures Vickery, Jemma L.; Patil, Avinash J.; Mann, Stephen Advanced Materials, Vol. 21, Issue 21, p. 2180-2184 https://doi.org/10.1002/adma.200803606	journal	June 2009
Synthesis and Characterization of Nanometric Iron and Iron-Titanium Oxides by Mechanical Milling: Electrochemical Properties as Anodic Materials in Lithium Cells Morales, Julian; Sanchez, Luis; Martin, Francisco Journal of The Electrochemical Society, Vol. 152, Issue 9, p. A1748-A1754 https://doi.org/10.1149/1.1972812	journal	January 2005
Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material Eda, Goki; Fanchini, Giovanni; Chhowalla, Manish Nature Nanotechnology, Vol. 3, Issue 5, p. 270-274 https://doi.org/10.1038/nnano.2008.83	journal	April 2008
Comment on “Near-Edge X-Ray Absorption Fine-Structure Investigation of Graphene” Jeong, H.-K.; Noh, H.-J.; Kim, J.-Y. Physical Review Letters, Vol. 102, Issue 9, Article No. 099701 https://doi.org/10.1103/PhysRevLett.102.099701	journal	March 2009
Flash Reduction and Patterning of Graphite Oxide and Its Polymer Composite Cote, Laura J.; Cruz-Silva, Rodolfo; Huang, Jiaxing Journal of the American Chemical Society, Vol. 131, Issue 31, p. 11027-11032 https://doi.org/10.1021/ja902348k	journal	August 2009
Strong Akaganeite Aerogel Monoliths Using Epoxides: Synthesis and Characterization Gash, Alexander E.; Satcher, Joe H.; Simpson, Randall L. Chemistry of Materials, Vol. 15, Issue 17, p. 3268-3275 https://doi.org/10.1021/cm034211p	journal	August 2003
Facile Synthesis of a Crystalline, High-Surface-Area SnO₂ Aerogel Baumann, T. F.; Kucheyev, S. O.; Gash, A. E. Advanced Materials, Vol. 17, Issue 12, p. 1546-1548 https://doi.org/10.1002/adma.200500074	journal	June 2005
In situ self-assembly of mild chemical reduction graphene for three-dimensional architectures Chen, Wufeng; Yan, Lifeng Nanoscale, Vol. 3, Issue 8, p. 3132-3137 https://doi.org/10.1039/c1nr10355e	journal	January 2011
Thermal and electrical conductivity of monolithic carbon aerogels Lu, Xianping; Nilsson, Ove; Fricke, Jochen Journal of Applied Physics, Vol. 73, Issue 2, p. 581-584 https://doi.org/10.1063/1.353367	journal	January 1993
Graphene Based Electrochemical Sensors and Biosensors: A Review Shao, Yuyan; Wang, Jun; Wu, Hong Electroanalysis, Vol. 22, Issue 10, p. 1027-1036 https://doi.org/10.1002/elan.200900571	journal	March 2010

Similar Records

Graphene aerogels

Patent · Tue Mar 31 00:00:00 EDT 2015 · OSTI ID:1177114

Highly crystalline 3D graphene

Patent · Tue Mar 19 00:00:00 EDT 2019 · OSTI ID:1568069

Nitrogen-doped carbon aerogels for electrical energy storage

Patent · Tue Oct 03 00:00:00 EDT 2017 · OSTI ID:1397269

Related Subjects

25 ENERGY STORAGE
36 MATERIALS SCIENCE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Graphene aerogels

Citation Formats

References (77)

Similar Records

Related Subjects