SAPO-34 Membranes for Xenon Capture from Air

Wu, Ting; Lucero, Jolie; Crawford, James M.; Sinnwell, Michael A.; Thallapally, Praveen K.; Carreon, Moises A.

doi:10.1016/j.memsci.2018.12.021

SAPO-34 Membranes for Xenon Capture from Air

Journal Article · Fri Mar 01 04:00:00 EST 2019 · Journal of Membrane Science

DOI:https://doi.org/10.1016/j.memsci.2018.12.021· OSTI ID:1496822

Wu, Ting; Lucero, Jolie; Crawford, James M.; Sinnwell, Michael A.; Thallapally, Praveen K.; Carreon, Moises A.

Capturing Xe from gas mixtures represents one of the most challenging molecular gas separations. In this communication, we demonstrate the ability of a zeolite membrane, denoted as SAPO-34 to effectively capture Xe from air. Specifically, SAPO-34 membranes showed air permeances as high as 2.3 x 10^-7 mol/m² s Pa (690 GPU) and separation selectivities as high as 30.1 for a molar feed of 9:1 air/Xe. Molecular sieving, competitive adsorption, and diffusivity differences played a critical role in the overall separation performance. Membranes were air selective due to favorable molecular sieving and differences in diffusivity between gases present in mixture and Xe, which were identified as the dominant separation mechanisms. The high air permeances, and high separation selectivities, make these membranes highly appealing as a potentially less energy intensive alternative to cryogenic distillation the benchmark technology used to separate these gases. We (Pacific Northwest National Laboratory) acknowledge US Department of Energy (DOE), Office of Nuclear Energy for adsorption. P.K.T. would like to acknowledge Dr Terry Todd at Idaho National Laboratory, Dr Robert Jubin at Oakridge National Laboratory, Dr John Vienna at Pacific Northwest National Laboratory (PNNL), Kimberly Gray, Dr. Patricia Paviet and Jim Breese (DOE-NE HQ) for programmatic support. PNNL is a multi-program national laboratory operated for the US DOE by Battelle under Contract DE-AC05-76RL01830.

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1496822

Report Number(s):: PNNL-SA-136512

Journal Information:: Journal of Membrane Science, Journal Name: Journal of Membrane Science Journal Issue: C Vol. 573; ISSN 0376-7388

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

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Xenon Recovery by DD3R Zeolite Membranes: Application in Anaesthetics Wang, Xuerui; Zhang, Yuting; Wang, Xiaoyu Angewandte Chemie International Edition, Vol. 58, Issue 43 https://doi.org/10.1002/anie.201909544	journal	October 2019
Xenon Recovery by DD3R Zeolite Membranes: Application in Anaesthetics Wang, Xuerui; Zhang, Yuting; Wang, Xiaoyu Angewandte Chemie, Vol. 131, Issue 43 https://doi.org/10.1002/ange.201909544	journal	September 2019

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