Crystal structure of ammonium trimolybdate monohydrate (NH{sub 4}){sub 2}Mo{sub 3}O{sub 10}{center_dot}H{sub 2}O by powder diffraction method
Journal Article
·
· Journal of Solid State Chemistry
- Jagiellonian Univ., Ingardena (Poland)
- Univ. of Amsterdam (Netherlands)
The structure of the fibrillar ammonium trimolybdate monohydrate (NH{sub 4}){sub 2}Mo{sub 3}O{sub 10}{center_dot}H{sub 2}O was solved by the Direct Method and Powder Diffraction package POWSIM, and refined by the Rietveld method to R{sub F} = 6.4 and R{sub wp} = 17.1%. Distorted edge-shared MoO{sub 6} octahedra (Mo-O = 1.71-2.62) form infinite chains, built up of Mo{sub 3}O{sub 10} units, parallel to the [010] axis. The space group is P2{sub 1}/m (11), with lattice parameters a = 9.638(1), b = 7.577(2), c = 8.537(1) {angstrom}, {beta} = 112.89(1){sup {degrees}}, V = 574.4(2) {angstrom}{sup 3}, Z = 2.
- OSTI ID:
- 149624
- Journal Information:
- Journal of Solid State Chemistry, Journal Name: Journal of Solid State Chemistry Journal Issue: 2 Vol. 116; ISSN 0022-4596; ISSN JSSCBI
- Country of Publication:
- United States
- Language:
- English
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