Corrosion Behavior of Zinc-Nickel and Graphene Layered Structures on Steel Substrates

Polizos, Georgios; Stehle, Yijing Y.; Sharma, Jaswinder; Voylov, Dmitry N.; Vlassiouk, Ivan V.; Shin, Seungha; Meyer, III, Harry M.

doi:10.1002/adem.201800949

Title: Corrosion Behavior of Zinc-Nickel and Graphene Layered Structures on Steel Substrates

Journal Article · Wed Jan 02 00:00:00 EST 2019 · Advanced Engineering Materials

DOI:https://doi.org/10.1002/adem.201800949· OSTI ID:1496004

^[1]; Stehle, Yijing Y. ^[1];

^[1]; Voylov, Dmitry N. ^[2];

^[1]; Shin, Seungha ^[2];

^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Univ. of Tennessee, Knoxville, TN (United States)

Large‐area single layers of graphene are synthesized using chemical vapor deposition techniques and are assembled onto steel substrates that are finished with a thin layer of electrodeposited zinc–nickel (ZnNi). Atomic force microscopy combined with Raman spectroscopy is used to determine the number of the assembled graphene layers and to characterize the defects in their crystal structure. The graphene‐ZnNi‐steel layered specimens are exposed to a salt‐fog environment. The defects in the structure of the graphene single layers are found to accelerate corrosion and the formation of a resistive oxide layer. The chemical composition and element map of the reacted surfaces are studied by x‐ray photoelectron spectroscopy. The electrical properties of the samples before and after the salt‐fog testing are evaluated using sheet resistance measurements.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1496004

Alternate ID(s):: OSTI ID: 1489298

Journal Information:: Advanced Engineering Materials, Vol. 21, Issue 3; ISSN 1438-1656

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 2 works

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References (35)

Optimized poly(methyl methacrylate)-mediated graphene-transfer process for fabrication of high-quality graphene layer Park, Honghwi; Lim, Changhee; Lee, Chang-Ju Nanotechnology, Vol. 29, Issue 41 https://doi.org/10.1088/1361-6528/aad4d9	journal	August 2018
Enhancement of seawater corrosion resistance in copper using acetone-derived graphene coating Huh, Jae-Hoon; Kim, Seung Hyun; Chu, Jae Hwan Nanoscale, Vol. 6, Issue 8 https://doi.org/10.1039/C3NR05997A	journal	January 2014
Quantifying Defects in Graphene via Raman Spectroscopy at Different Excitation Energies Cançado, L. G.; Jorio, A.; Ferreira, E. H. Martins Nano Letters, Vol. 11, Issue 8, p. 3190-3196 https://doi.org/10.1021/nl201432g	journal	July 2011
Study on corrosion resistance of electroplating zinc-nickel alloy coatings Tian, W.; Xie, F. Q.; Wu, X. Q. Surface and Interface Analysis, Vol. 41, Issue 3 https://doi.org/10.1002/sia.3017	journal	March 2009
Simple, green, and clean removal of a poly(methyl methacrylate) film on chemical vapor deposited graphene Park, J. -H.; Jung, W.; Cho, D. Applied Physics Letters, Vol. 103, Issue 17 https://doi.org/10.1063/1.4824877	journal	October 2013
Scalable superhydrophobic coatings based on fluorinated diatomaceous earth: Abrasion resistance versus particle geometry Polizos, Georgios; Winter, Kyle; Lance, Michael J. Applied Surface Science, Vol. 292 https://doi.org/10.1016/j.apsusc.2013.12.009	journal	February 2014
Intrinsic and extrinsic performance limits of graphene devices on SiO₂ Chen, Jian-Hao; Jang, Chaun; Xiao, Shudong Nature Nanotechnology, Vol. 3, Issue 4, p. 206-209 https://doi.org/10.1038/nnano.2008.58	journal	March 2008
Graphene Oxide Membranes for Ionic and Molecular Sieving Mi, B. Science, Vol. 343, Issue 6172 https://doi.org/10.1126/science.1250247	journal	February 2014
A cautionary note on graphene anti-corrosion coatings Cui, Chenlong; Lim, Alane Tarianna O.; Huang, Jiaxing Nature Nanotechnology, Vol. 12, Issue 9 https://doi.org/10.1038/nnano.2017.187	journal	September 2017
Effect of polymer residues on the electrical properties of large-area graphene–hexagonal boron nitride planar heterostructures Stehle, Yijing Y.; Voylov, Dmitry; Vlassiouk, Ivan V. Nanotechnology, Vol. 28, Issue 28 https://doi.org/10.1088/1361-6528/aa7589	journal	June 2017
Evolution of the Raman spectra from single-, few-, and many-layer graphene with increasing disorder Martins Ferreira, E. H.; Moutinho, Marcus V. O.; Stavale, F. Physical Review B, Vol. 82, Issue 12 https://doi.org/10.1103/PhysRevB.82.125429	journal	September 2010
Greatly Enhanced Anticorrosion of Cu by Commensurate Graphene Coating Xu, Xiaozhi; Yi, Ding; Wang, Zhichang Advanced Materials, Vol. 30, Issue 6 https://doi.org/10.1002/adma.201702944	journal	December 2017
Corrosion mechanism and hydrogen evolution on Mg Thomas, S.; Medhekar, N. V.; Frankel, G. S. Current Opinion in Solid State and Materials Science, Vol. 19, Issue 2 https://doi.org/10.1016/j.cossms.2014.09.005	journal	April 2015
Inhibitor or promoter: Insights on the corrosion evolution in a graphene protected surface Lee, Jihyung; Berman, Diana Carbon, Vol. 126 https://doi.org/10.1016/j.carbon.2017.10.022	journal	January 2018
Determination of PMMA Residues on a Chemical-Vapor-Deposited Monolayer of Graphene by Neutron Reflection and Atomic Force Microscopy Li, Ruiheng; Li, Zongyi; Pambou, Elias Langmuir, Vol. 34, Issue 5 https://doi.org/10.1021/acs.langmuir.7b03117	journal	January 2018
Evolutionary selection growth of two-dimensional materials on polycrystalline substrates Vlassiouk, Ivan V.; Stehle, Yijing; Pudasaini, Pushpa Raj Nature Materials, Vol. 17, Issue 4 https://doi.org/10.1038/s41563-018-0019-3	journal	March 2018
Quantifying ion-induced defects and Raman relaxation length in graphene Lucchese, M. M.; Stavale, F.; Ferreira, E. H. Martins Carbon, Vol. 48, Issue 5 https://doi.org/10.1016/j.carbon.2009.12.057	journal	April 2010
Raman spectroscopy and imaging of graphene Ni, Zhenhua; Wang, Yingying; Yu, Ting Nano Research, Vol. 1, Issue 4 https://doi.org/10.1007/s12274-008-8036-1	journal	October 2008
Robust Superhydrophobic Graphene-Based Composite Coatings with Self-Cleaning and Corrosion Barrier Properties Nine, Md J.; Cole, Martin A.; Johnson, Lucas ACS Applied Materials & Interfaces, Vol. 7, Issue 51 https://doi.org/10.1021/acsami.5b09611	journal	December 2015
RNA World Benner, S. A.; Ellington, A. D. Science, Vol. 252, Issue 5010 https://doi.org/10.1126/science.252.5010.1232-a	journal	May 1991
Excellent tribological and anti-corrosion performance of polyurethane composite coatings reinforced with functionalized graphene and graphene oxide nanosheets Mo, Mengting; Zhao, Wenjie; Chen, Zifei RSC Advances, Vol. 5, Issue 70 https://doi.org/10.1039/C5RA10494G	journal	January 2015
Graphene on graphene formation from PMMA residues during annealing Karlsson, Linda H.; Birch, Jens; Mockute, Aurelija Vacuum, Vol. 137 https://doi.org/10.1016/j.vacuum.2017.01.004	journal	March 2017
Different graphene layers to enhance or prevent corrosion of polycrystalline copper Xu, Ying; Qu, Jingyi; Shen, Yongtao RSC Advances, Vol. 8, Issue 27 https://doi.org/10.1039/C8RA00412A	journal	January 2018
Scalable production of large quantities of defect-free few-layer graphene by shear exfoliation in liquids Paton, Keith R.; Varrla, Eswaraiah; Backes, Claudia Nature Materials, Vol. 13, Issue 6 https://doi.org/10.1038/nmat3944	journal	April 2014
Graphene as a Long-Term Metal Oxidation Barrier: Worse Than Nothing Schriver, Maria; Regan, William; Gannett, Will J. ACS Nano, Vol. 7, Issue 7 https://doi.org/10.1021/nn4014356	journal	June 2013
Laser-patterned functionalized CVD-graphene as highly transparent conductive electrodes for polymer solar cells La Notte, Luca; Villari, Enrica; Palma, Alessandro Lorenzo Nanoscale, Vol. 9, Issue 1 https://doi.org/10.1039/C6NR06156G	journal	January 2017
Designing Carbon Nanotube Membranes for Efficient Water Desalination Corry, Ben The Journal of Physical Chemistry B, Vol. 112, Issue 5 https://doi.org/10.1021/jp709845u	journal	February 2008
Impermeable barrier films and protective coatings based on reduced graphene oxide Su, Y.; Kravets, V. G.; Wong, S. L. Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5843	journal	September 2014
Heat transfer fluids for concentrating solar power systems – A review Vignarooban, K.; Xu, Xinhai; Arvay, A. Applied Energy, Vol. 146 https://doi.org/10.1016/j.apenergy.2015.01.125	journal	May 2015
Oxidation behavior of graphene-coated copper at intrinsic graphene defects of different origins Kwak, Jinsung; Jo, Yongsu; Park, Soon-Dong Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-01814-8	journal	November 2017
Functional and smart coatings for corrosion protection: A review of recent advances Montemor, M. F. Surface and Coatings Technology, Vol. 258 https://doi.org/10.1016/j.surfcoat.2014.06.031	journal	November 2014
Raman Studies of Monolayer Graphene: The Substrate Effect Wang, Ying ying; Ni, Zhen hua; Yu, Ting The Journal of Physical Chemistry C, Vol. 112, Issue 29 https://doi.org/10.1021/jp8008404	journal	June 2008
Direct Chemical-Vapor-Deposition-Fabricated, Large-Scale Graphene Glass with High Carrier Mobility and Uniformity for Touch Panel Applications Sun, Jingyu; Chen, Zhaolong; Yuan, Long ACS Nano, Vol. 10, Issue 12 https://doi.org/10.1021/acsnano.6b06066	journal	November 2016
Large scale atmospheric pressure chemical vapor deposition of graphene Vlassiouk, Ivan; Fulvio, Pasquale; Meyer, Harry Carbon, Vol. 54 https://doi.org/10.1016/j.carbon.2012.11.003	journal	April 2013
Raman characterization of defects and dopants in graphene Beams, Ryan; Gustavo Cançado, Luiz; Novotny, Lukas Journal of Physics: Condensed Matter, Vol. 27, Issue 8 https://doi.org/10.1088/0953-8984/27/8/083002	journal	January 2015

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36 MATERIALS SCIENCE
corrosion
graphene
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zinc–nickel

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